Early Carbonate Petrology: Carbonate Rocks . Limestones and Dolomites. Lucien Cayeux. Translated from the French edition (Paris, 1935) and updated by Albert V. Carozzi. Hafner, Darien, Conn., 1970. xviii, 506 pp., illus. $37.50. Sedimentary Rocks of France.

Science ◽  
1971 ◽  
Vol 172 (3979) ◽  
pp. 151-151
Author(s):  
Gerald M. Friedman
Author(s):  
L. V. Kuleshevich ◽  
М. М. Filippov ◽  
N. А. Goltsin ◽  
R. Sh. Krymsky ◽  
K. I. Lokhov

The Maksovo metasapropelite deposit, which contains shungite matter and is called maksovite, is located in the eastern Onega structure. The deposit is a diapiric fold which formed ca. 2070±10 Ma ago. It is underlain by carbonate rocks and overlain by tuff siltstones and is cross-cut by 1956±5 Ma gabbro-dolerites. Unaltered maksovites are pelitomorphic rocks with a massive to mildly layered texture and moderate concentrations of all petrogenic components and Сorg of about 30%. Fe-Mg rich and alkaline metasomatic rocks evolve after maksovites and mafic and carbonate tuff siltstones in the northwestern part of the deposit within a multiple ridge-like fold after brecciation zones. They differ from unaltered sedimentary rocks in heterogeneous (brecciated, streaky) textures, mineral and chemical composition and are saturated with numerous sulphide, carbonate, quartz and albite veinlets. They are identified by intense biotitization, chloritization and the presence of calcite, microcline metacrystals, albite-carbonate metacrystals with apatite and carbonate-quartz metacrystals with sulphides and rutile, veinlets and disseminated mineralization. Na concentration rises to 5.67% and K concentration to 7.57%. P and Ti concentrations, accompanying alkaline metasomatism, as well as Mg-Fe and ore-bearing components (often incompatible), increase locally. Metasomatic rocks evolve heterogeneously and are represented by breccia zones. Their slightly elevated radioactivity disturbs the qualitative characteristics of primary maksovite as a useful mineral. Maksovites were dated at 1558±61 Ma by the Re-Os method from sulphides.


1966 ◽  
Vol S7-VIII (4) ◽  
pp. 585-591
Author(s):  
Jean Boulin ◽  
Patrick Dimpault Darcy ◽  
Henry Leroy

Abstract The Sierra de Lujar is composed of Triassic sedimentary rocks, mostly limestones and dolomites, in a reversed series. This unit seems to be the inverted flank of a recumbent fold of which the Lanjaron nappe is the normal flank, the fold being inclined toward the inner zones of the range. A lead deposit is associated with the carbonate rocks. It is of the stratiform type and appears to be related to a shoal zone that existed during the sedimentation of the ore host rock, and perhaps also to reworking and concentration of the latter, in which case it would be synsedimentary. These Triassic shoals, which have probably shifted somewhat, lie parallel to the northeast-southwest direction of the minor alpine (Cenozoic) folds that make up the Sierra. These minor folds are themselves parallel to the general alignment of the range.


2021 ◽  
Vol 21 (1) ◽  
pp. 599-607
Author(s):  
Qiyan Li ◽  
Songtao Wu ◽  
Xiufen Zhai ◽  
Songqi Pan ◽  
Senhu Lin

A nanoscale pore throat system develops extensively in rocks of unconventional reservoirs serving as both source and reservoir rock. The nanoscale pores provide the main storage spaces, accounting for 70% to 80% of the total unconventional tight reservoirs in China. As one of most important unconventional petroleum accumulations, tight oil has accumulated in more than 20 lacustrine strata since the Permian in China. Three types of tight oil reservoirs were identified based on the lithology and provenance in the lacustrine basins, including terrigenous sandstone, endogenous carbonate rocks and mixed sedimentary rocks. The micro/nanopore structures of these tight rocks were investigated with the application of optical microscopy, scanning electron microscopy (SEM), mercury injection capillary pressure (MICP), gas adsorption (GA) and nuclear magnetic resonance (NMR). The results indicated that the pore systems were connected by nanoscale throats dominated the storage spaces of the lacustrine tight oil reservoirs, while there were obvious differences among these three tight rocks, including pore types, pore size and movable fluid distribution. (i) The terrigenous sandstones, which were represented by the Triassic Chang 7 tight sandstones in the Ordos Basin and Cretaceous Quantou tight sandstones in the Songliao Basin, were mainly arkoses, and their storage space was mainly composed of dissolution pores and intraclay mineral pores. Feldspar, rock fragments and carbonate cements were the majority of the dissolved components, and the diameter of dissolution pores ranged from 1 micron to 50 microns. Abundant intrakaolinite and illite/smectite mixed layers pores were developed, and the pore size was 10 nm to 500 nm. The MICP and GA data suggested that storage spaces were connected by throats with diameters of 10 nm˜300 nm. (ii) The endogenous carbonate rocks, which were represented by the Jurassic Da’anzhai limestones in the Sichuan Basin, were the tightest rocks with porosities of less than 5% and permeabilities of less than 0.01×10−3 μm2. The calcite dissolution pores and fractures with diameters of 10 nm˜500 nm were the most important storage spaces. The majority of pore systems were connected by throats with diameters of 6 nm˜100 nm based on the MICP and GA data. (iii) The tight mixed sedimentary rocks, which were represented by the Permian Lucaogou Formation in the Junggar Basin, were complex in lithologic composition, and dolostones and dolomite sandstones were the most important exploration targets. The interdolomite pores were the dominant storage spaces, in which abundant illite/smectite mixed layers were filled, and the pore size ranged from 50 nm to 50 microns. The MICP and GA data showed that the storage space was dominated by throats with diameters of 10 nm˜200 nm, and their volumetric contributions could reach over 70%. These results could provide a reference for future tight oil research and exploration in China.


2018 ◽  
Vol 25 (1-2) ◽  
Author(s):  
Jiří Zimák

This paper deals with natural radioactivity of Palaeozoic sedimentary rocks in the map sheets 25-11 Hlubočky and 25-12 Hranice. All studied rocks belong to the Moravo-Silesian Palaeozoic, namely to three flysch formations (Horní Benešov, Moravice and Hradec-Kyjovice fms.) and two carbonate formations (Macocha and Líšeň fms.). Contents of potassium, uranium and thorium were measured using a laboratory gamma–ray spectrometer in 1 337 rock samples, values of mass activity of 226Ra equivalent (am) were calculated. The data are tabled and discussed. The average am of analysed flysch sediments is 160 Bq.kg-1. This value is very close to the value of am calculated for the average continental crust. Natural radioactivity of flysch sedimentary rocks grows from psefites (conglomerates) through psammites (graywackes dominate) to the group of aleurites and pelites (siltstones, silty shales, clay shales). Natural radioactivity of the studied carbonate rocks is very low. In dark biodetritic limestones of the Líšeň Fm. there were found slightly increased uranium contents (typically up to 6 ppm). Uranium in the rock is probably bound to graphitic matter.


Author(s):  
S. W. Wise ◽  
F. M. Weaver ◽  
N. Guven

Although silica is a primary component of flints, cherts, volcanic glasses, and siliceous deep sea oozes, mobilization pathways and modes of reprecipitation of this element during early diagenesis of volcanic and sedimentary rocks remains an elusive geologic problem. As a result, the source and mode of deposition of vast Tertiary silica deposits of the Atlantic and Gulf Coastal Plain and offshore deep sea deposits is currently a topic of sharp debate. Both volcanic and biogenous sources of silica have been variously postulated as ultimate or immediate silica sources for a broad range of fine-grained silica-rich rocks including claystones, “opal claystones,” “buhrstones,” “pseudobuhrstones,” cristobalitic cherts, and silicified chalks and limestones. Current scanning electron microscope/electron microprobe investigations of incipient stages of diagenesis in geologically young biogenous sediments, volcanic glasses, and silica-replaced carbonate rocks, however, do allow silica pathways to be traced and silica sources to be ascertained.


2021 ◽  
pp. 82-91
Author(s):  
Petr Ignatov ◽  
Nail Zaripov ◽  
Konstantin Novikov ◽  
Alexander Tolstov

Drag folds were revealed in Lower Paleozoic sedimentary strata of Mirny, Nakyn and Syuldyukar diamondiferous fields, West Yakutia. They consist of minor anticlinal forms (3-5 to 15-20 cm thick) and cut marl, clayey limestone and dolomite bands located between monolith seams of carbonate rocks. Some folds as monocline, flexures and S- or Z-shaped folds reflect the degree of shearrelated interlayer offset. Drag folds are among shear zone occurrences including microfaults, slickensides with slip groove horizontal planes, and schistosity zones. Drag folds reflect local extension points while schistosity zones indicate compression points. For Syuldyukar field, detailed mapping results for drag folds and schistosity zones are provided at 3 scales: across 20 × 20 m observation grid within a local 2 km2 site; across 200 × 200 m grid within 20 km2 area; across 500 × 500 m grid within ~100 km2 territory. For all scales, drag fold halos are restricted to schistosity zones. Within a local site adjacent to kimberlites, drag folds mark ore-hosting fault controlling long axes of kimberlite areal projections. Within large areas, drag fold halos are 1,2-2 km, which compares with kimberlite group areal parameters. Drag fold halos reflect shear junctions, with some of them hosting kimberlites. Local occurrences of drag folds mark a major shear hosting a kimberlite body. Drag fold analysis combined with other evidence should be used as an indirect prospecting indicator of concealed shears and local extension areas controlling kimberlites.


2019 ◽  
Vol 485 (3) ◽  
pp. 356-360
Author(s):  
A. V. Chugaev ◽  
I. V. Chernyshev ◽  
B. G. Pokrovsky ◽  
G. V. Mandzhieva ◽  
B. I. Gareev ◽  
...  

This article is devoted to a study of variations in the U isotopic composition (238U/235U) in the section of clas- tic-carbonate Ediacaran sediments exposed along the Chaya River in the southern part of Central Siberia (Russia). Measurements of 238U/235U in the rocks were performed using a high-precision (±0.07%o, 2SD) MC-ICP- MS with a 233U-236U double isotope spike. The total variation range of S238U in the studied carbonate rocks was -0.91 to -0.01%. Extremely low values of S238U (-0.91%, -0.9%, and -0.84%), which were found in a number of samples from the lower part of the section, are interpreted as the result of postsedimentation processes affecting the rocks. In the overlying sediments, the range of S238U variations is smaller from -0.49 to -0.01%. Here, regular “weighting” of the U isotopic composition observed upwards through the section indicates an increase in the reduction conditions at this time (about 550 Ma) in the paleobasin. This conclusion is consistent with the elevated concentrations of U, Mo, and V in the Late Ediacaran sedimentary rocks of the region studied.


1970 ◽  
Vol 7 (6) ◽  
pp. 1539-1551 ◽  
Author(s):  
Harold H. Williams ◽  
Robert C. Harriss

The acid soluble chloride/bromide ratios of 66 limestones and 74 dolomites and the water soluble chloride/bromide ratios of 65 limestones and 42 dolomites were determined for samples from Recent to Precambrian age (2 b.y.). A progressive increase occurs in the chloride/bromide ratio from the Precambrian to Recent and is interpreted as representing an increase in the chloride/bromide ratio of sea water over the past 2 × 109 years. It is postulated that removal of bromine from sea water by sedimentation of bromine-enriched organic matter and crustal recycling of sedimentary rocks is responsible for the increase in the chloride/bromide ratio of sea water.


Author(s):  
Diogo Rosa ◽  
John F. Slack ◽  
Hendrik Falck

During the 2013 field season, siliciclastic and carbonate rocks of the lower Palaeozoic sedimentary succession of the Franklinian Basin in Amundsen Land, central North Greenland, were collected for whole-rock geochemical analysis. These data are evaluated here in an attempt to identify possible hydrothermal signatures related to sediment-hosted Zn-Pb mineralisation, similar to that found in correlative strata at the large Citronen Fjord deposit located c. 100 km to the eastnorth-east. In this paper, we use the term Sedex in a broad sense to describe stratiform, sediment-hosted deposits that formed either by syngenetic (exhalative) processes or by subsea-floor replacement coeval with sedimentation (e.g. Emsbo et al. 2016); the term Mississippi Valley-type (MVT) is used for non-stratiform Zn-Pb deposits that formed epigenetically during late diagenesis or tectonism (e.g. Leach et al. 2010).


Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).


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