DIAGENETIC HISTORY OF CAMBRIAN SANDSTONE UNITS IN WESTERN WISCONSIN

2016 ◽  
Author(s):  
Rachel Fliflet ◽  
◽  
Justin M. Poirier ◽  
Brian J. Mahoney ◽  
Kent M. Syverson
Keyword(s):  
History Of ◽  
Diagenetic History

DIAGENETIC HISTORY OF CAMBRIAN SANDSTONE UNITS IN WESTERN WISCONSIN: IMPLICATIONS FOR RESOURCE EXTRACTION

2016 ◽  
Author(s):  
Rachel Fliflet ◽  
◽  
Justin M. Poirier ◽  
J. Brian Mahoney ◽  
Kent M. Syverson
Keyword(s):  
Resource Extraction ◽  
History Of ◽  
Diagenetic History

scholarly journals Experimental degradation of helicoidal photonic nanostructures in scarab beetles (Coleoptera: Scarabaeidae): implications for the identification of circularly polarizing cuticle in the fossil record

2018 ◽  
Vol 15 (148) ◽  
pp. 20180560 ◽  
Author(s):  
Giliane P. Odin ◽  
Maria E. McNamara ◽  
Hans Arwin ◽  
Kenneth Järrendahl
Keyword(s):  
Uric Acid ◽  
Fossil Record ◽  
Evolutionary History ◽  
Polarized Light ◽  
Circularly Polarized Light ◽  
Circularly Polarized ◽  
Alkaline Conditions ◽  
History Of ◽  
Diagenetic History ◽  
Scarab Beetles

Scarab beetles (Coleoptera: Scarabaeidae) can exhibit striking colours produced by pigments and/or nanostructures. The latter include helicoidal (Bouligand) structures that can generate circularly polarized light. These have a cryptic evolutionary history in part because fossil examples are unknown. This suggests either a real biological signal, i.e. that Bouligand structures did not evolve until recently, or a taphonomic signal, i.e. that conditions during the fossilization process were not conducive to their preservation. We address this issue by experimentally degrading circularly polarizing cuticle of modern scarab beetles to test the relative roles of decay, maturation and taxonomy in controlling preservation. The results reveal that Bouligand structures have the potential to survive fossilization, but preservation is controlled by taxonomy and the diagenetic history of specimens. Further, cuticle of specific genus ( Chrysina ) is particularly decay-prone in alkaline conditions; this may relate to the presence of certain compounds, e.g. uric acid, in the cuticle of these taxa.

scholarly journals Ultrastructure, dissolution and "pyritization" of Late Quaternary and Recent echinoderms

1987 ◽  
Vol 36 ◽  
pp. 275-287
Author(s):  
Margit Jensen ◽  
Elsebeth Thomsen
Keyword(s):  
Late Pleistocene ◽  
Sea Water ◽  
Late Quaternary ◽  
Pore Space ◽  
Water Interface ◽  
Sea Stars ◽  
Northern Norway ◽  
History Of ◽  
Organic Tissue ◽  
Diagenetic History

The diagenetic history of the skeletal elements of Late Pleistocene-Holocene Ophiura sarsi from the shelf off northern Norway (Andfjorden, Malangsdjupet) is elucidated by comparison with natural and induced degradation of the skeletal elements of Recent ophiuroids (brittle stars) and asteroids (sea stars) from Danish waters. Dissolution features ("core-and-rind") in the trabeculae of fossil and Recent echinoderm stereom are initiated during death and early decay of organic tissue in the animals. The trabeculae have a polycrystal­line lamellar ultrastructure and lose their older central part during later stages of dissolution, which are dependant on undersaturation of the sea-water with regard to CaC03• The presence of undersaturated sea-water is supported by palaeoecological studies (Thomsen & Vorren 1984, 1986) implying oxygen deficient periods in the Late Pleistocene and an increased biogenic production in the Holocene. Pyrite framboids are situated in the secondary voids within the trabeculae and in the pore space of the stereom of the Late Pleistocene elements. No pyrite is observed within the polycrystalline lamellar ultrastructure of the trabeculae. The Late Pleistocene "pyritization" took place during oxygen deficient periods at the sediment-water interface or within the reduced zone of the topmost sediment.

scholarly journals FTIR-Based Crystallinity Assessment of Aragonite–Calcite Mixtures in Archaeological Lime Binders Altered by Diagenesis

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 121 ◽  
Author(s):  
Michael Toffolo ◽  
Lior Regev ◽  
Stéphan Dubernet ◽  
Yannick Lefrais ◽  
Elisabetta Boaretto
Keyword(s):  
Unknown Origin ◽  
Infrared Light ◽  
Infrared Spectrometry ◽  
Atomic Order ◽  
Range Atomic Order ◽  
Mechanisms Of Formation ◽  
History Of ◽  
Lime Plaster ◽  
Archaeological Sediments ◽  
Diagenetic History

Lime plaster and mortar are pyrotechnological materials that have been employed in constructions since prehistoric times. They may nucleate as calcite and/or aragonite under different environmental settings. In nature, aragonite and calcite form through biogenic and geogenic processes that lead to different degrees of atomic order. The latter is a result of defects in the crystal lattice, which affect the properties of crystals, including their interaction with infrared light. Using Fourier transform infrared spectrometry (FTIR) with the KBr pellet method, it is possible to exploit these differences and assess the degree of atomic order of aragonite and calcite crystals and thus their mechanisms of formation. Here we use FTIR to characterize the degree of short-range atomic order of a pyrogenic form of aragonite recently observed in experimental and archaeological lime binders. We show that pyrogenic aragonite has a unique signature that allows its identification in archaeological sediments and lime binders of unknown origin. Based on these results, we developed a new FTIR-based method to assess the integrity and degree of preservation of aragonite and calcite when they occur together in the same material. This method allowed a better assessment of the diagenetic history of an archaeological plaster and finds application in the characterization of present-day conservation materials, such as lime plaster and mortar, where different polymorphs may nucleate and undergo recrystallization processes that can alter the mechanical properties of binders.

Diagenetic history of a submerged Pleistocene Jamaican fringing reef

1992 ◽  
Vol 7 (1) ◽  
pp. 2-10 ◽  
Author(s):  
M. L. McCullough ◽  
L. S. Land
Keyword(s):  
Fringing Reef ◽  
History Of ◽  
Diagenetic History

Climatic and oceanographic isotopic signals from the carbonate rock record and their preservation

1992 ◽  
Vol 129 (2) ◽  
pp. 143-160 ◽  
Author(s):  
James D. Marshall
Keyword(s):  
Ocean Circulation ◽  
Global Climate ◽  
Burial History ◽  
Vegetative Cover ◽  
Isotopic Data ◽  
Rock Interaction ◽  
Diagenetic Alteration ◽  
Wide Range ◽  
History Of ◽  
Diagenetic History

AbstractStable isotopic data from marine limestones and their constituent fossils and marine cements can provide quantitative evidence for changes in global climate and ocean circulation. Oxygen isotopic data can indicate changes in temperature and ocean composition whereas stratigraphic variation in carbon isotope ratios may reflect changes in the carbon cycle that can be linked to changes in oceanic productivity and atmospheric greenhouse gases. Terrestrial carbonates–meteoric cements, calcretes and speleothems–similarly offer significant potential for understanding the evolution of terrestrial climates by providing evidence for the composition of rainwater and the nature of vegetative cover.Primary environmental isotopic signals may be obscured by the effects of post-depositional diagenetic alteration. Cementation and replacement reactions can take place in a wide range of diagenetic environments; the diagenetic history of an individual limestone is determined by a combination of its mineralogical diagenetic potential and depositional setting, together with subsequent changes in relative sea-level and burial history. Carbon isotopic values are less prone to alteration during diagenesis than oxygen values but shifts can be significant where organogenic carbon is incorporated. Linear covariation of carbon and oxygen values is not a reliable indicator of diagenetic alteration: water-rock interaction and fluid mixing may produce non-linear distributions.Attempts to determine long-term changes in climatic and oceanographie conditions through isotope stratigraphy of shallow-water limestones must include an assessment of the diagenetic history of the materials analysed. Pétrographic examination using conventional microscopy backed up, where appropriate, by cathodoluminescence and scanning electron microscopy together with elemental and strontium isotopic analysis can help to identify the effects of diagenetic alteration. Where material with a range of different degrees of alteration is preserved in the same sediment it may be possible to compare patterns of isotopic and elemental variation and to attempt to unravel the effects of diagenesis in order to determine primary, environmental, isotopic signals. Recent research has shown that these techniques can be successfully employed in both Phanerozoic and Precambrian sediments.

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