Neoproterozoic Blaini Formation of Lesser Himalaya, India: Fiction and Fact

2020 ◽  
Vol 132 (11-12) ◽  
pp. 2267-2281
Author(s):  
Sumit Dey ◽  
Prabir Dasgupta ◽  
Kaushik Das ◽  
Abdul Matin

Abstract The long-conceived idea of the glacial origin of Blaini diamictite of Lesser Himalayan Neoproterozoic succession reached its maxima when the diamictites and capping pink limestone were attributed to the Neoproterozoic Snowball Earth event and its aftermath, respectively. Occurrences of diamictite-limestone association in two different levels have also been correlated with the Sturtian and Marinoan glaciations. Critical review, however, reveals that the interpretations of the glacial origin of diamictites are not well founded. The diamictite-limestone association, which occurs at the lower part of a thick, light brown shale unit and laterally grades into light brown shale, primarily indicates episodic surge events in an otherwise tranquil condition favorable for hemipelagic sedimentation. The lithology, bed geometry, internal organization, and disposition of the diamictite bodies suggest deposition of debris flow fan lobes along fault scarps in a rift setting. Emplacement of subaqueous debris flows is indicated by the associated deposits of entrained turbidity currents. The limestone also bears the signature of claciturbidites. The appearance of diamictite bodies and associated limestone in two distinct levels is not a stratigraphic disposition; on the contrary, the deposits were dislocated and repeated by two successive regional thrust faults. The Chemical Index of Alteration (CIA) values of the light brown shale and the matrix of the diamictites indicate that these sediments formed through prolonged subaerial weathering. The events leading up to development of the rift system and evidence of prolonged weathering within the basin-fill sediments are consistent with supercontinental break up, the prologue of Snowball Earth.

2021 ◽  
Vol 7 (1) ◽  
pp. 1-11
Author(s):  
Raj Kumar Priya ◽  
Vinod Chandra Tewari ◽  
Rakesh Kumar Ranjan

The Rangit Gondwana Basin of Sikkim in the lesser Himalaya witnessed a wide span of climate change during the Permo-Carboniferous period. The principal objective of the present study is to document this Permo-Carboniferous climate change in the form of a geochemical signature preserved in the siliciclastic facies of the Rangit Pebble Slate Formation. The stratigraphic sequences of the Rangit Gondwana Basin are categorically well defined and subdivided into upper and lower sequences on the basis of their depositional environment. The lower sequences of the Rangit Gondwana basin are comprised of massive diamictite with large stromatolitic dolomite boulders and dropstone embedded in the coarser sandstone which indicate the cold glaciomarine environment of deposition, whereas upper sequences consist of repeated alternate beds of sandstone, black shale and coal seam with a regular interval depicting the fluvial and deltaic environment of deposition. The enrichment of SiO2, Al2O3, TiO2, MnO, MgO, and K2O indicates that these sediments were mostly derived from felsic rock source areas. Chemical Index of Alteration (CIA) and Index of Compositional Variability (ICV) CaO + Na2O + K2O/Al2O3, and SiO2 vs. (Al2O3 + K2O + Na2O) values suggest that the sediments maturity and paleoclimatic environment deposition of the sediments of lower sequences was cold and semi-humid whereas the deposition of sediments of upper sequences was warm and humid. The A-CN-K ternary plot and CIA vs ICV binary plot also indicate and verify that the source areas were subjected to prolonged intense chemical weathering from low to high grade due to shifting of cold to warm humid paleo-climatic condition.


2018 ◽  
Author(s):  
Chad Wittkop ◽  
◽  
Christian Piper ◽  
Julie K. Bartley ◽  
Russell Krueger ◽  
...  

2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Mayla A. Ramos-Vázquez ◽  
John S. Armstrong-Altrin

AbstractThe mineralogy, bulk sediment geochemical composition, and U–Pb ages of detrital zircons retrieved from the Barra del Tordo (Tordo) and Tesoro beach sediments in the northwestern Gulf of Mexico were analyzed to determine their provenance. The beach sediments are mainly composed of quartz, ilmenite, magnetite, titanite, zircon, and anorthite. The weathering proxies such as the Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), and Plagioclase Index of Alteration (PIA), reveal a moderate-to-high intensity of weathering in the source area. The chondrite-normalized rare earth element (REE) patterns are similar to felsic igneous rocks, with large negative europium anomaly (Eu/Eu* = ~ 0.47–0.80 and ~ 0.57–0.67 in the Tordo and Tesoro beach sediments, respectively).Three major zircon U–Pb age groups are identified in the Tordo and Tesoro beach sediments, i.e., Proterozoic (~ 2039–595 Ma), Mesozoic (~ 244–70.3 Ma), and Cenozoic (~ 65.9–1.2 Ma). The differences of the zircon age spectrum between the Tordo and Tesoro beach sediments are not significant. The comparison of zircon U–Pb ages in this study with ages of potential source terranes suggests that the Mesozoic and Cenozoic zircons of the studied Tordo and Tesoro beach sediments were derived from the Eastern Alkaline Province (EAP) and Mesa Central Province (MCP). Similarly, the likely sources for the Proterozoic zircons were the Sierra Madre Oriental (SMOr) and Oaxaquia in the northwestern Gulf of Mexico. The results of this study further indicate that the sediments delivered to the beaches by rivers and redistributed by longshore currents were crucial in determining the sediment provenance.


2020 ◽  
Vol 10 ◽  
pp. 102
Author(s):  
Phillips Reuben Ikhane ◽  
Olalekan Olayiwola Oyebolu ◽  
Afolabi Omotayo Alaka

Integration of X-ray fluor escence and stable isotope spectrometric techniques for quality assessment and provenance study of exposed marble deposit at Fakunle Quarry, Ikpeshi, South Western Nigeria constitute the fundamental aims of this research. Fourteen fresh (14) marble samples obtained at different localities within the quarry were subjected to geochemical and isotopic analyses to ascertain the quantitative abundance of major oxides and stable isotopes using X-Ray Fluorescence and Thermo Fisher mass spectrometer respectively. The major oxides revealed by XRF analysis of the marble samples are CaO, MgO, SiO2, Al2O3, Fe2O3 and Na2O with percentage composition ranging between 11.66 – 13.25, 7.75 – 9.65, 41.36 – 47.55, 12.36 – 15.23, 7.79 – 10.55 and 1.44 – 1.75respectively. Na2O + K2O value ranges between 1.48 and 1.78.The classification of marble in relation to percentage of calcite-dolomite indicate a percentage range of -5 to 4% and 93-103% for Calcite and Dolomite respectively. Chemical Index of Alteration (CIA) ranges from 45.16 to 51.59 % and Chemical Index of Weathering (CIW) ranges from 46.19 to 52.30 %. Stable isotope ( ? –180) of marble ranges from -10.50 to -7.00 with a corresponding value from 25.50 to 55.33.Interpretation of the overall results indicates an impure quartz-rich dolomitic marble; metamorphosed from a low carbonate sedimentary/meta sedimentary protolith which shallowly precipitated within a passive marginal marine environment under humid condition. The high silica impurity can however be attributed to the inordinate influx of terrigenous sediments during the precipitation process. Weathering effect is minimal on the marble deposit. Conclusively, strong correlation is apparent between the obtained geochemical result and the basement geology of the study area.


2020 ◽  
Vol 347 ◽  
pp. 105829
Author(s):  
Can Chen ◽  
Jiasheng Wang ◽  
Zhou Wang ◽  
Yongbo Peng ◽  
Xiaohong Chen ◽  
...  

2017 ◽  
Vol 60 (1) ◽  
pp. 159-165 ◽  
Author(s):  
Catarina Leandro ◽  
Lurdes Ávila-Carvalho ◽  
Elena Sierra-Palmeiro ◽  
Marta Bobo-Arce

Abstract This study aimed to analyse the quality of difficulty judging in rhythmic gymnastics, at different levels of performance. The sample consisted of 1152 difficulty scores concerning 288 individual routines, performed in the World Championships in 2013. The data were analysed using the mean absolute judge deviation from the final difficulty score, a Cronbach’s alpha coefficient and intra-class correlations, for consistency and reliability assessment. For validity assessment, mean deviations of judges’ difficulty scores, the Kendall’s coefficient of concordance W and ANOVA eta-squared values were calculated. Overall, the results in terms of consistency (Cronbach’s alpha mostly above 0.90) and reliability (intra-class correlations for single and average measures above 0.70 and 0.90, respectively) were satisfactory, in the first and third parts of the ranking on all apparatus. The medium level gymnasts, those in the second part of the ranking, had inferior reliability indices and highest score dispersion. In this part, the minimum of corrected item-total correlation of individual judges was 0.55, with most values well below, and the matrix for between-judge correlations identified remarkable inferior correlations. These findings suggest that the quality of difficulty judging in rhythmic gymnastics may be compromised at certain levels of performance. In future, special attention should be paid to the judging analysis of the medium level gymnasts, as well as the Code of Points applicability at this level.


Molecules ◽  
2019 ◽  
Vol 24 (18) ◽  
pp. 3245 ◽  
Author(s):  
Iwona Kosendiak ◽  
Jussi M.E. Ahokas ◽  
Justyna Krupa ◽  
Jan Lundell ◽  
Maria Wierzejewska

Structural changes of glycolic acid (GA) complex with nitrogen induced by selective overtone excitation of the νOH mode were followed in argon matrices using FTIR spectroscopy. For the most stable SSC1 complex present in different trapping sites directly upon deposition site, selective changes in the νOH region were achieved upon near-infrared irradiation. Simultaneously, new conformers of the GA…N2 complex were formed, giving rise to several sets of bands in the νOH and νC=O regions of the spectra. Both position and intensity of new absorptions appeared to be highly sensitive on the wavelength of radiation used, as well as on the annealing of the matrix. Based on theoretical calculations at different levels of theory, an assignment of the observed bands is proposed and discussed.


Clay Minerals ◽  
2009 ◽  
Vol 44 (1) ◽  
pp. 51-66 ◽  
Author(s):  
Hanlie Hong ◽  
Zhaohui Li ◽  
Muzhuang Yang ◽  
Ping Xiao ◽  
Huijuan Xue

AbstractThe clay mineralogy and chemical composition of the white veins, red matrix and both Fe- and Mn-bearing nodules occurring in a laterite profile in Hubei, south China were investigated using X-ray diffraction, scanning electron microscopy equipped with an energy-dispersive spectrometer, and high-resolution transmission electron microscopy. The results show that the mineral components of the red matrix are mainly quartz, kaolinite, halloysite, goethite and minor illite, whereas the white net-like veins contain mostly quartz, kaolinite, halloysite, and illite. In the net-like horizon, the chemical index of alteration (CIA, the ratio of Al2O3/(Al2O3+CaO+K2O+Na2O)) and the TiO2/Al2O3 ratio are 89.8% and 0.021 for the white vein and 90.7% and 0.025 for the red matrix, respectively. Both white-vein and red-matrix components have similar TiO2/Al2O3 ratios, and are similar to the ratio 0.027 of the unaltered bedrock. The similarity in TiO2/Al2O3 values indicates that all three portions of the laterite soil share the same origin. Also, although the white-vein and red-matrix components differ in Fe2O3 abundance, the similar CIA values do imply similar degrees of alteration. The Fe-bearing and Mn-bearing nodules were produced by the local accumulation of Fe2O3 and MnO, respectively. Halloysite in the weathering profile occurs in two different morphologies, tubular and platy crystals. Tubular halloysite occurs both in the red matrix and the Fe-bearing nodule whereas platy halloysite occurs only in the white vein and Mn-bearing nodule assemblages. Crystallization of small tubular halloysite from Si and Al concretions in the red matrix is observed, indicating that the morphology of these crystals in the weathering environment is mainly controlled by Fe3+ cations, whereas platy halloysite may be derived from the hydration of kaolinite.


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