scholarly journals Triple oxygen isotope variations in magnetite from iron-oxide deposits, central Iran, record magmatic fluid interaction with evaporite and carbonate host rocks

Geology ◽  
2019 ◽  
Vol 48 (3) ◽  
pp. 211-215 ◽  
Author(s):  
Stefan T.M. Peters ◽  
Narges Alibabaie ◽  
Andreas Pack ◽  
Seann J. McKibbin ◽  
Davood Raeisi ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Oxygen Isotope ◽  
Carbonate Rocks ◽  
Isotope Composition ◽  
Central Iran ◽  
Magmatic Fluid ◽  
Isotope Data ◽  
O Isotopes ◽  
Magmatic Fluids ◽  
O Isotope

Abstract Oxygen isotope ratios in magnetite can be used to study the origin of iron-oxide ore deposits. In previous studies, only 18O/16O ratios of magnetite were determined. Here, we report triple O isotope data (17O/16O and 18O/16O ratios) of magnetite from the iron-oxide–apatite (IOA) deposits of the Yazd and Sirjan areas in central Iran. In contrast to previous interpretations of magnetite from similar deposits, the triple O isotope data show that only a few of the magnetite samples potentially record isotopic equilibrium with magma or with pristine magmatic water (H2O). Instead, the data can be explained if magnetite had exchanged O isotopes with fluids that had a mass-independently fractionated O isotope composition (i.e., MIF-O), and with fluids that had exchanged O isotopes with marine sedimentary carbonate rocks. The MIF-O signature of the fluids was likely obtained by isotope exchange with evaporite rocks of early Cambrian age that are associated with the IOA deposits in central Iran. In order to explain the triple O isotope composition of the magnetite samples in conjunction with available iron isotope data for magnetite from the deposits, we propose that magnetite formed from magmatic fluids that had interacted with evaporite and carbonate rocks at high temperatures and at variable water/rock ratios; e.g., magmatic fluids that had been released into the country rocks of a magma reservoir. Additionally, the magnetite could have formed from magmatic fluids that had exchanged O isotopes with SO2 and CO2 that, in turn, had been derived by the magmatic assimilation and/or metamorphic breakdown of evaporite and carbonate rocks.

scholarly journals Triple oxygen isotope variations in magnetite from iron-oxide deposits, central Iran, record magmatic fluid interaction with evaporite and carbonate host rocks: REPLY

Geology ◽  
2020 ◽  
Vol 48 (7) ◽  
pp. e504-e504 ◽  
Author(s):  
Stefan T.M. Peters ◽  
Narges Alibabaie ◽  
Andreas Pack ◽  
Seann J. McKibbin ◽  
Davood Raeisi ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Oxygen Isotope ◽  
Central Iran ◽  
Magmatic Fluid ◽  
Host Rocks ◽  
Fluid Interaction

scholarly journals Oxygen isotope composition of zircons from the Talnakh economic intrusion of the Noril’sk province: first data

2019 ◽  
Vol 489 (2) ◽  
pp. 170-173
Author(s):  
I. Yu. Badanina ◽  
E. A. Belousova ◽  
K. N. Malitch ◽  
S. F. Sluzhenikin
Keyword(s):  
Oxygen Isotope ◽  
Isotope Composition ◽  
Oxygen Isotope Composition ◽  
Primary Magma ◽  
Crustal Component ◽  
Layered Series ◽  
Isotope Data ◽  
Oxygen Isotope Data ◽  
First Results ◽  
Isotope Analyses

This study presents the first results of oxygen isotope analyses (18O) collected on zircons from the Talnakh economic intrusion within the Norilsk province. Zircons from gabbro-diorite, gabbroic rocks of the layered series and plagioclase-bearing wehrlite have similar mantle-like mean 18O values (5,39 0,49; 5,64 0,48 and of 5,28 0,34, respectively), which differ from 18O in zircons from sulfide-bearing melanocratic troctolite with a taxitic texture in the lower part of the intrusion (mean 18O = 6,50 0,98). These new oxygen isotope data support (i) the mantle-derived origin of the primary magma(s), parental to the Talnakh intrusion, and (ii) possible involvement of a crustal component during the formation of sulfide-bearing taxitic-textured rocks.

Paleoenvironmental Traces of Carbon and Oxygen Isotopes in Carbonate Rocks: An Example From Dengying Formation in Xichuan Area, Henan Province

2020 ◽  
Author(s):  
Lan Zhang ◽  
Hong Xie ◽  
Qingguang Li ◽  
Zhenghao Lu ◽  
Yang Bai ◽  
...  
Keyword(s):  
Oxygen Isotope ◽  
Carbonate Rocks ◽  
Isotope Composition ◽  
Salinity Range ◽  
Carbon And Oxygen Isotopes ◽  
Accurate Analysis ◽  
Average Value ◽  
Dengying Formation ◽  
Three Samples ◽  
Carbon And Oxygen Isotope

Abstract The carbon and oxygen isotope composition of carbonate rocks is an important index for accurate analysis of the paleo-sea environment, which depends on Mn/Sr, δ 18 O > -10‰, correlativity of δ 13 C and δ 18 O and “age effect” of δ 18 O. This study reports carbon and oxygen isotope data of carbonate rocks from the Dengying Formation in the Xichuan area. δ 13 C values range -1.58‰ to 3.76‰, with an average value of 1.55‰, and δ 18 O values are -14.91‰ to -1.88‰, with an average value of -6.95‰. The δ 18 O values of three samples are less than -10‰, so they are excluded and taken to be correlative with the cracking of the Rodinia supercontinent during the Neoproterozoic. The paleotemperature range 7.40°C to 35.05°C, with an average value of 21.09°C. Paleo-salinity range 8.38‰ to 19.30‰, with an average value of 13.89‰. Z values range 127.80 to 135.03 and thus all exceeded 120, with an average value of 131.25. These calculations indicate that the Xichuan area had deposited marine carbonate rocks, with the hot and dry tropical monsoon climate, and a transgressive process overall during the Dengying age.

The geologic history of seawater oxygen isotopes from marine iron oxides

Science ◽  
2019 ◽  
Vol 365 (6452) ◽  
pp. 469-473 ◽  
Author(s):  
Nir Galili ◽  
Aldo Shemesh ◽  
Ruth Yam ◽  
Irena Brailovsky ◽  
Michal Sela-Adler ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Oxygen Isotope ◽  
Iron Oxides ◽  
Isotope Composition ◽  
Geologic History ◽  
Temperature Dependent ◽  
Oxygen Isotope Fractionation ◽  
History Of ◽  
Sediment Cover

The oxygen isotope composition (δ18O) of marine sedimentary rocks has increased by 10 to 15 per mil since Archean time. Interpretation of this trend is hindered by the dual control of temperature and fluid δ18O on the rocks’ isotopic composition. A new δ18O record in marine iron oxides covering the past ~2000 million years shows a similar secular rise. Iron oxide precipitation experiments reveal a weakly temperature-dependent iron oxide–water oxygen isotope fractionation, suggesting that increasing seawater δ18O over time was the primary cause of the long-term rise in δ18O values of marine precipitates. The18O enrichment may have been driven by an increase in terrestrial sediment cover, a change in the proportion of high- and low-temperature crustal alteration, or a combination of these and other factors.

Apatite Texture, Composition, and O-Sr-Nd Isotope Signatures Record Magmatic and Hydrothermal Fluid Characteristics at the Black Mountain Porphyry Deposit, Philippines

2021 ◽  
Author(s):  
Ming Jian Cao ◽  
Noreen J. Evans ◽  
Pete Hollings ◽  
David R. Cooke ◽  
Brent I.A. McInnes ◽  
...  
Keyword(s):  
Phase Separation ◽  
High Temperature ◽  
Oxygen Isotope ◽  
Hydrothermal Alteration ◽  
Hydrothermal Fluid ◽  
Isotope Composition ◽  
Hydrothermal Fluids ◽  
Nd Isotope ◽  
O Isotope ◽  
Black Mountain

Abstract The trace elemental and isotopic signatures in apatite can be modified during hydrothermal alteration. This study investigates the suitability of apatite as an indicator of the source, chemistry, and evolution of magma and hydrothermal fluids. In situ textural, elemental, and O-Sr-Nd isotope analyses were performed on apatite in thin sections, from fresh and propylitically altered pre- and synmineralized dioritic porphyries from the Black Mountain porphyry Cu deposit in the Philippines. All studied apatite crystals have similar subhedral to euhedral shapes and are homogeneous in the grayscale in backscattered electron images. In cathodoluminescence images, the apatite in fresh and altered rocks displays yellow to yellow-green and green to brown luminescence, respectively. Apatite in fresh rocks has a higher Cl and Mn content, and lower Fe, Mg, Sr, Pb, and calculated XOH-apatite, compared to apatite in altered rocks. The content of F, rare earth elements (REEs), Y, U, Th, and Zr, and the Sr-Nd isotope signatures of apatite from fresh and altered rocks are similar in all apatite grains (87Sr/86Sr = 0.7034–0.7042 vs. 0.7032–0.7043, εNd(t) = 5.3–8.0 vs. 5.1–8.4). The X-ray maps and elemental and oxygen isotope signatures across individual apatite crystals are typically homogeneous in apatite from both fresh and altered rocks. The distinct luminescence colors, coupled with distinct mobile element compositions (Cl, OH, Mn, Mg, Fe, Sr, Pb), indicate modification of primary magmatic apatite during interaction with hydrothermal fluids. The similarities in Sr isotope ratios (87Sr/86Sr = 0.7032–0.7043) but slight differences in O isotope signatures (δ18O = 6.0 ± 0.3‰ vs. 6.6 ± 0.3‰) in apatite from fresh and altered rocks are consistent with the magma and hydrothermal fluids having the same source and suggest significant phase separation in the hydrothermal fluids given that 18O preferentially fractionates into the residual liquid relative to 16O during phase separation. The similarity of immobile element (REE, Y, U, Th, and Zr) contents in both populations of apatite, consistency of textures and Nd isotope compositions, and absence of obvious dissolution-reprecipitation features all suggest that altered apatite retains some magmatic characteristics. The apatite in fresh rocks has oxygen isotope compositions similar to that of zircons from the same sample (δ18O = 5.9 ± 0.3‰), indicating little to no oxygen isotope fractionation between zircon and apatite and that apatite can be a good proxy for the oxygen isotope composition of the magma. Based on the Cl contents of the magmatic and replacement apatite, and assuming their equilibrium with high-temperature magma fluid and replacement hydrothermal fluid, respectively, the calculated Cl content of the early magmatic fluid and the later replacement fluid can be estimated to be 6.4 to 15.1 wt % and ~0.25 ± 0.03 wt %, respectively. This indicates a depletion of Cl from the early high-temperature fluid to the replacement fluid, consistent with phase separation. This study demonstrates that cathodoluminescence, elemental compositions (such as Cl, Mn, Mg, Fe, Sr, Pb) and Sr-O isotope signatures in apatite can be modified during hydrothermal alteration, whereas other components (REE, Y, U, Th, and Zr) and the Nd isotope composition are preserved. These features can be used to constrain the origin, chemistry, and evolution of the primary magma and ore-forming hydrothermal fluids.

Hydrotermal mineralization hosted by Cambrian sedimentary rocks asevidence of kimberlite-hosting structure, Syuldyukarskoye field, Yakutia

2021 ◽  
pp. 93-105
Author(s):  
Petr Ignatov ◽  
Nail Zaripov ◽  
Alexander Tolstov ◽  
Kolesnik Alexander ◽  
Mikhail Maltsev
Keyword(s):  
Carbonate Rocks ◽  
Isotope Composition ◽  
Manganese Concentration ◽  
Tectonic Structures ◽  
Southeastern Part ◽  
Medium Temperature ◽  
Sedimentary Carbonate ◽  
O Isotope ◽  
Diamond Potential ◽  
Diamondiferous Kimberlite

The paper describes diamondiferous kimberlite area within a new Yakutian Syuldyukarskoye fi ld and presents detailed mapping results of ore-hosting shear evidence, veinlet bleaching of redbeds, outcrops of metagrained pyrite, pyrite-calcite and calcite veinlets hosted by Cambrian terrigenous-carbonate rocks where kimberlites occur. Kimberlite localization is shown at fault junction as well as kimberlite long axis combination with west-northwest orehosting shear. These tectonic structures combine with veinlet bleaching halos, those of pyrite-calcite and calcite veinlets, and calcite druses characterized by red photoluminescence and phosphorescence. Red, blue and partially white photoluminescence is caused by manganese concentration in calcites (> 0,1%). Hydrothermal calcite nature is supported by C and O isotope composition variations, which reflect the input of medium temperature formational and meteoric waters, carbon of sedimentary carbonate rocks and deep hydrocarbons. Anomalous Ba, Cr, Ni and La content is recognized in hydrothermal calcites from near-kimberlite environment. Kimberlite position in the southeastern part of endogenous mineralization halos and greater diamond potential of the western kimberlite body, which is larger compared to the eastern one, allow forecasting of new productive bodies.

scholarly journals Badzhal tin magmatic-fluid system (Far east, Russia): the transition from the granite crystallization to the hydrothermal ore deposition

2019 ◽  
Vol 61 (3) ◽  
pp. 3-30
Author(s):  
N. S. Bortnikov ◽  
L. Ya. Aranovich ◽  
S. G. Kryazhev ◽  
S. Z. Smirnov ◽  
V. G. Gonevchuk ◽  
...  
Keyword(s):  
Oxygen Isotope ◽  
Melt Inclusions ◽  
Isotope Composition ◽  
Far East ◽  
Oxygen Isotope Composition ◽  
Magmatic Fluid ◽  
Fluid System ◽  
Melt And Fluid Inclusions ◽  
Isotope System ◽  
Ore Deposition

With a view to reveal special characteristics of the transition stage from granite crystallization to rare-metal ore deposition it is studied Badzhal tin-bearing magmatic-fluid system of eponymously-named volcano-plutonic zone of the Middle Priamyrie. For that end the detail research of melt, fluid-melt and fluid inclusions and oxygen isotopes from minerals of granitoids from Verkne-Urmi massif from Badzhal volcano-plutonic zone and also minerals of Sn-W deposits Pravo-Urmi and Blizhnee have been carried out. The formation of greisens and hydrothermal veins were caused by the development of the integrated system associating with establishing of Verkne-Urmi granite massif which is one of a dome fold of Badzhal cryptobatholith. For the first time for tin deposits it has been followed up the transition from the magmatic phase of granite crystallization to the hydrothermal ore formation stage and the evolution of magmatic fluid from its separation from magmatic melt to Sn-W ore deposition. The direct evidence of tin-bearing fluid separation under melt crystallization is combined fluid-melt inclusions. Glass composition in inclusions shows that granites and granite-porphyry were crystallizing from acid and from limited to high-aluminous melts, that is value ASI changes from 0.95 to 1.33 and a content of alkalies varies from 6.02 up to 9.02 mass.%. Cl and F concentrations in glasses are according 0.03–0.14 and 0.14–0.44 mass.% and turned out to be higher of same in the total composition of rocks (0.02 and 0.05–0.13 mass.% in accordance). These differences indicate that Cl and F could be separated from granite melt under its crystallization and degasation. H2O content made from total deficiency electron microprobe analysis is 8–11 mass.%. This evaluation was made inclusive of a probable effect of “Na loss” (Nielsen, Sigurdson, 1981) under aqueous glass crystallization. Considering a high error of a such estimation (Devine et al., 1995), it should take to obtained values as a very approximate evaluation and consider that examined melts contained about 9,5–10,0 mass.% of H2O. The results of melt inclusion examination show that at any rate a part of melt forming magmatic rocks of Badzhal Ore Magmatic System are crystallizing at about T = 650 °C. These melts were acid, limited fluoride and meta- and high aluminous. The reason of low temperatures of its crystallization are likely a high pressure of aqua and also a increased content of F. Most likely that examined inclusions characterize the final stage of establishing of the massif, herewith at the system crystals, residual liquor and magmatic fluid phase coexist. The fluid from which greisens of Pravo-Urmi deposit formed is similar in properties to the supercritical fluid absorbing by magmatic minerals. The salinity of this fluid varying from ~9 to 12 mass.% equiv. NaCl, maximal T = 550 °C (with consideration for the temperature correction of T gom on a pressure ~1 кbar) are similar to such of magmatic fluid, which permit to connect its origin with pluton cooling. The formation of greisens and quartz-topaz veins of Pravo-Urmi deposit is related to fall of temperature of magmatic fluid from 550–450 up to 480–380 °C. The evolution of fluid deposited quartz-cassiterite veins of Blizhnee deposit, which based upon oxygen isotope composition (d18ОН2О ≈ 8.5‰) also separated from magma, was going at more subsurface conditions under much lesser pressure. That led to the gas separation of a fluid with salinity ~13 mass.% equa. NaCl under T = 420–340 °C on thin low salinity vapour and brine with concentration 33.5–37.4 mass.% equiv. NaCl. The research of oxygen isotope system testifies that oxygen isotope composition of ore-forming fluid controlled by equilibrium with granites at wide interval tempera­tures (from ~700 °С up to the beginning of greisen crystallization). Correspondence of measured and calculation data of the offered model indicates that the considerable volume of external fluid with other isotope characteristics which did not reach the isotope equilibrium with Verkhne-Urmi massif did not come into the magmatic isotope system. The discovered differences of physico-chemical conditions for two studied deposits are not “critical” and support an idea about their formation as the single magmatic-fluid system.

scholarly journals Absence of hydrothermal oxygen isotope variations in host rocks supports magmatic origin of the giant Grängesberg iron oxide–apatite (IOA) deposit, Central Sweden

2021 ◽  
Author(s):  
Franz Weis ◽  
Valentin R. Troll ◽  
Erik Jonsson ◽  
Karin Högdahl ◽  
Chris Harris ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Oxygen Isotope ◽  
Large Scale ◽  
Country Rock ◽  
Isotope Composition ◽  
Northwestern Part ◽  
Magmatic Origin ◽  
Ore Body ◽  
Two Samples ◽  
Host Rocks

AbstractThe origin of Kiruna-type iron oxide–apatite ores is controversial, and debate presently centres on a ‘magmatic’ versus a ‘hydrothermal’ mode of formation. To complement recent investigations on the Grängesberg iron oxide–apatite ore deposit in the northwestern part of the Palaeoproterozoic Bergslagen ore province in central Sweden, we investigated the oxygen isotope composition of the host rocks of this large iron oxide–apatite ore body. As the metavolcanic and metagranitoid country rocks around the Grängesberg ore body either pre-date or are coeval with ore formation, they would be expected to record an extensive isotopic imprint if the ore body had formed by large-scale hydrothermal processes involving an externally sourced fluid. A direct magmatic formation process, in turn, would have produced localized alteration only, concentrated on the immediate vicinity of the ore body. Here, we test these two hypotheses by assessing the oxygen isotope variations in the host rocks around the main Grängesberg iron oxide–apatite ore body. We analysed oxygen isotopes in quartz from metavolcanic (n = 17) and metagranitoid host rocks (n = 14) from the vicinity of the ore body, and up to 2 km distance along and across the strike of the ore body. Remarkably, we find no significant variation in δ18O values with distance from the ore body, or any deviations in country rock δ18O from common magmatic and/or regional values. Only two samples show shifts to values more negative than the common magmatic range, indicating highly localized hydrothermal overprint only. As a large-scale, low-temperature hydrothermal origin of the ore body through voluminous fluid percolation would be expected to have left a distinct imprint on the oxygen isotope values of the country rocks, our results are more consistent with an ortho-magmatic origin for the Grängesberg iron oxide–apatite ore.

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