Synthesis and Activity of Nanodispersed SnO2–CeO2 Catalyst in the Oxidation Reactions of Carbon Monoxide and Methane

2021 ◽  
Vol 62 (1) ◽  
pp. 155-159
Author(s):  
E. Yu. Liberman ◽  
E. A. Simakina ◽  
I. A. Moiseev ◽  
A. O. Izotova ◽  
T. V. Kon’kova ◽  
...  
2011 ◽  
Vol 89 (7) ◽  
pp. 845-853 ◽  
Author(s):  
Sadok Letaief ◽  
Wendy Pell ◽  
Christian Detellier

The clay mineral kaolinite was used as support of gold nanoparticles for heterogeneous catalysis of oxidation reactions, particularly of carbon monoxide oxidation. The application of clay minerals in the preparation of new functional materials provides an alternative approach for the use of these abundant raw materials. To improve the physicochemical properties of kaolinite, as well as to ensure a strong immobilization of the adsorbed species, kaolinite was functionalized by grafting 2-amino-2-methyl-1,3-propanediol on the internal and external surfaces of the octahedral sheets by reaction with the aluminol groups. Gold nanoparticles were then deposited on the external surfaces of the fine particles of the functionalized kaolinite. The resulting gold kaolinite nanohybrid material was characterized by various physicochemical techniques. X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and energy-dispersive X-ray spectrometry confirmed that gold was effectively reduced to the metallic state during adsorption onto the external surfaces of the modified kaolinite. The gold nanoparticles have a narrow size distribution: more than 88% are less than 4 nm in diameter. Gold nanoparticles deposited on kaolinite catalyze the electro-oxidation of carbon monoxide in alkaline solution at room temperature.


2021 ◽  
Vol 62 (1) ◽  
pp. 146-154
Author(s):  
L. A. Isupova ◽  
E. Yu. Gerasimov ◽  
I. P. Prosvirin

Author(s):  
Tomotaka Abe ◽  
Ken’ichi Hiratsuka ◽  
Czesław Kajdas

Oxidation reaction of methane is one of the most fundamental reactions in organic chemistry. This reaction is enhanced by silver catalyst [1]. In this study, we confirmed that the catalytic activity of silver is enhanced more by the friction. This effect is called tribocatalysis. In previous studies about tribocatalysis, we have shown that the oxidation reactions of hydrogen [2], carbon monoxide [3] and ethylene were promoted by the friction. According to NIRAM (negative-ion-radical action mechanism) approach, exo-electron emission triggers the promotion of chemical reactions [4]. Insulator such as aluminum oxide, when it is worn, emits larger number of negative particles including electrons compared with metals [5]. Therefore we expected that the friction of aluminum oxide promotes tribochemical reactions more than metals.


Author(s):  
G. R. Kosmambetova ◽  
O. I. Yanushevska ◽  
N. V. Vlasenko ◽  
O. Z. Didenko ◽  
V. I. Grytsenko ◽  
...  

2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
Yingji Song ◽  
Xuefeng Chu ◽  
Yingzi Lin ◽  
Xiaotian Yang

Enhancing the catalytic activity of supported metal nanoparticle is a great demand but extremely challenging to make. We reported a simple strategy for enhancing the activities by employing the polyvinylpyrrolidone (PVP) additive, where a series of supported Au nanoparticle catalysts including Au/C, Au/BN, Au/TiO2, and Au/SBA-15 exhibited significantly higher activities in the oxidation of various alcohols and carbon monoxide by molecular oxygen after adding PVP to the reaction system. The XPS study indicates that PVP could electronically interact with Au to form high active Au sites for molecular oxygen, thus causing improved activities for the various oxidation reactions.


2018 ◽  
Vol 243 ◽  
pp. 00007
Author(s):  
Leonid Minkov ◽  
Kseniya Moiseeva

Numerical modeling of the combustion of a lean methane-air mixture containing fine coal particles entering the “Swiss-roll” type recuperative burner is considered. The mathematical model is constructed under the following assumptions: the flow field is two-dimensional; the gas mixture is an ideal incompressible gas consisting of oxygen, methane, coal volatile substances, carbon monoxide, carbon dioxide, water vapor, hydrogen and nitrogen. In the gas phase four oxidation reactions, in which methane, volatile matter of coal, carbon monoxide, hydrogen participate and the reaction of carbon dioxide decomposition take place. On the surface of the coal particle, there are three oxidation reactions involving oxygen, carbon dioxide and water vapor, resulting in the formation of carbon monoxide. It is assumed that coal contains 8% of ash, 12.9% of volatile substances and 79.1% of carbon. It is shown that for a two percent methane-air mixture the reaction zone shifts toward the center of the burner as the feed rate of the mixture increases. An increase in the content of coal particles leads to a shift of the reaction zone into the inlet part of the burner, and the heat release in the burner increases.


Sign in / Sign up

Export Citation Format

Share Document