Anodic voltammetry of pyrazolone derivatives with the help of the self-cleaning rotating electrode

1987 ◽  
Vol 52 (1) ◽  
pp. 66-71 ◽  
Author(s):  
Vesselin C. Noninski ◽  
Emanuel B. Sobowale

Nine pyrazolone derivatives have been studied by anodic voltammetry using gold self-cleaning rotating electrode (SRE). Voltamograms of good reproducibility are presented. On the basis of voltammetric data a mechanism is proposed for the electrochemical oxidation of sodium 1-phenyl-2,3-dimethyl-4-(N-methylamino)pyrazol-5-one-N-methansulphonate and 1-phenyl-2,3-dimethyl-4-(dimethylamino)pyrazol-5-one in protic medium.

2021 ◽  
Author(s):  
Maulida Rahayu ◽  
Sujito ◽  
Edy Wibowo ◽  
S. Sutisna
Keyword(s):  
The Self ◽  

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 387
Author(s):  
Euigyung Jeong ◽  
Heeju Woo ◽  
Yejin Moon ◽  
Dong Yun Lee ◽  
Minjung Jung ◽  
...  

In this study, self-cleaning polyester (PET) fabrics were prepared using TiOF2 and hexadecyltrimethoxysilane(HDS) treatment. TiOF2 was synthesized via direct fluorination of a precursor TiO2 at various reaction temperatures. The prepared PET fabrics had superior photocatalytic self-cleaning properties compared with anatase TiO2/HDS-treated PET fabrics under UV and sunlight with 98% decomposition of methylene blue. TiOF2/HDS-treated PET fabrics also had superior superhydrophobic self-cleaning properties compared with anatase TiO2/HDS-treated PET fabrics with a 161° water contact angle and 6° roll-off angle. After the self-cleaning tests of the non-dyed TiOF2/HDS-treated PET fabrics, we prepared dyed TiOF2/HDS-treated PET fabrics to test practical aspects of the treatment method. These PET fabrics were barely stained by tomato ketchup; even when stained, they could be self-cleaned within 4 h. These results suggest that practical self-cleaning PET fabrics with superhydrophobicity and photocatalytic degradation could be prepared using TiOF2/HDS-treatment.


2009 ◽  
Vol 17 (2) ◽  
pp. 383-391 ◽  
Author(s):  
Huda Mahmoud ◽  
Redha Al-Hasan ◽  
Majida Khanafer ◽  
Samir Radwan

Author(s):  
Yu Li ◽  
Shengke Yang ◽  
Yangyang Chen ◽  
Dan Zhang

The hydrophobicity and anti-fouling properties of materials have important application value in industrial and agricultural production and people’s daily life. To study the relationship between the unit width L0 of the parabolic hydrophobic material and the hydrophobicity and anti-fouling properties, the rough surface structure of the parabolic with different widths was prepared by grinding with different SiC sandpapers, and further, to obtain hydrophobic materials through chemical oxidation and chemical etching, and modification with stearic acid (SA). The morphology, surface wetting and anti-fouling properties of the modified materials were characterized by SEM and contact angle measurement. The oil–water separation performance and self-cleaning performance of the materials were explored. The surface of the modified copper sheet forms a rough structure similar to a paraboloid. When ground with 1500 grit SiC sandpaper, it is more conducive to increase the hydrophobicity of the copper sheet surface and increase the contact angle of water droplets on the copper surface. Additionally, the self-cleaning and anti-fouling experiments showed that as L0 decreases, copper sheets were less able to stick to foreign things such as soil, and the better the self-cleaning and anti-fouling performance was. Based on the oil–water separation experiment of copper mesh, the lower L0 has a higher oil–water separation efficiency. The results showed that material with parabolic morphology has great self-cleaning, anti-fouling, and oil–water separation performance. The smaller the L0 was, the larger the contact angle and the better hydrophobic performance and self-cleaning performance were.


Soft Matter ◽  
2020 ◽  
Vol 16 (36) ◽  
pp. 8473-8481 ◽  
Author(s):  
Yuxing Shan ◽  
Zhi Zhou ◽  
Haoming Bai ◽  
Ting Wang ◽  
Lili Liu ◽  
...  

Stretchable elastomers with superhydrophobic surfaces and self-cleaning abilities are fabricated for use in wearable electronics.


Author(s):  
Honghui Zhang ◽  
Zejun Tao ◽  
Yunheng Xiao

In this article, magnetorheological colloid was adopted to coat a stainless steel substrate, which was cured under magnetic field to form magnetic roughness surface. Superhydrophobicity had been verified in the experiments, and the influential factors on the hydrophobic performance had been explored. A regular sawtooth structure model was proposed to relate the hydrophobicity with the formed surface microstructure. With the self-cleaning and bonding strength testing, the magnetic roughness surface is promising to keep sustainable superhydrophobicity in the self-cleaning or drag reduction applications.


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