Block Copolymers Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(6-hexanelactam). Preparation and Composition
1993 ◽
Vol 58
(11)
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pp. 2574-2582
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Keyword(s):
Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(6-hexanelactam) diblock copolymers were prepared from low-molecular weight poly(2,6-dimethyl-1,4-phenylene oxide) by transforming its phenolic end groups via the reaction with 2,4-tolylene diisocyanate and 6-hexanelactam to polymeric initiators and the subsequent anionic polymerization of 6-hexanelactam. The polymerization of 6-hexanelactam was carried out in bulk or toluene solution. The content of the 6-hexanelactam homopolymer was estimated by TLC showing that the pure diblock copolymer can be prepared in toluene. The reason for relatively low yields is discussed.
2013 ◽
Vol 54
(11)
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pp. 2595-2604
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Keyword(s):
1997 ◽
Vol 70
(5)
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pp. 707-713
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Keyword(s):
1983 ◽
Vol 23
(12)
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pp. 650-657
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