Heavy Metal Ions and the Development of Rancidity in Blended Fish Muscle

1968 ◽  
Vol 25 (4) ◽  
pp. 639-656 ◽  
Author(s):  
C. H. Castell ◽  
D. M. Spears

From 1 to 50 ppm of 10 different heavy metal ions were added to blended muscle taken from freshly killed cod, haddock, flounders, redfish, herring, mackerel, scallops, and lobster, and stored for 24 hr at 0 C. The resulting rancidities were determined by thiobarbituric acid (TBA) values and odours. With some exceptions, Fe++, V++, and Cu++ were the most active catalysts. Fe++ was always more effective than Fe+++. Cd++, Co++, and Zn+ produced randicity with the fatty species but not with any of the other species that were tested. Ni++, Cr++, Ce++, and Mn++ did not accelerate rancidity in any of the muscles. There was considerable difference in the relative susceptibility of muscle from different species to rancidity induced by specific metals. During frozen storage, changes in fish muscle took place that rendered it less susceptible to subsequent metal-induced rancidities.

2014 ◽  
Vol 893 ◽  
pp. 457-460
Author(s):  
Xing Zou ◽  
Xiao Dan Qiu

Separation of trace heavy metal ions with BaS from solutions of five kinds of systems was studied. One was prepared with the solution (called as original solution here) leached from pyrolusite with pyrite and H2SO4, and the other four kinds of systems were prepared in the laboratory according to the composition of the original solution. They are respectively: a ternary system of NiSO4CoSO4ZnSO4; two quaternary systems of (NH4)2SO4NiSO4CoSO4ZnSO4 and MnSO4NiSO4CoSO4ZnSO4; a quintuple system of MnSO4(NH4)2SO4NiSO4CoSO4ZnSO4. The experiments have researched the effect of reaction time and dosage of BaS on the separation of heavy metal ions. According to the results, it took the five systems 10minutes to reach the equilibrium state and re-dissolution was found in the results. As the increasing of BaS dosage, the residual heavy metal ions would reduce, but the results of five systems were different when the same BaS was used.


Author(s):  
Krisfian Tata Aneka Priyangga ◽  
Yehezkiel Steven Kurniawan ◽  
Keisuke Ohto ◽  
Jumina Jumina

Calixarenes are well-known supramolecular host molecules with versatile applications. Over the past decades, hundreds of selective and sensitive detections of several analytes have been reported by employing calixarenes as the chemosensor agent. The detection and quantification of metal ions and anions are crucial as heavy metal ions are harmful to living organisms, while monitoring anions is pivotal in the environmental samples. On the other hand, detecting and quantifying biomolecules and neutral molecules are critical due to their irreplaceable role in human health. In this review, we summarized the application of calixarenes as the supramolecular chemosensor agent for detecting metal ions, anions, biomolecules, and neutral molecules through fluorescent spectroscopy to give brief information on the design and development of the chemosensor field. This review updates the world with the application of calixarene derivatives as fluorescent chemosensors and challenges researchers to design and develop better chemosensor agents in the future.


2017 ◽  
Vol 14 (1) ◽  
pp. 15
Author(s):  
M.B. Nicodemus Ujih ◽  
Mohammad Isa Mohamadin ◽  
Milla-Armila Asli ◽  
Bebe Norlita Mohammed

Heavy metal ions contamination has become more serious which is caused by the releasing of toxic water from industrial area and landfill that are very harmful to all living organism especially human and can even cause death if contaminated in small amount of heavy metal concentration. Currently, peoples are using classic method namely electrochemical treatment, chemical oxidation/reduction, chemical precipitation and reverse osmosis to eliminate the metal ions from toxic water. Unfortunately, these methods are costly and not environmentally friendly as compared to bioadsorption method, where agricultural waste is used as biosorbent to remove heavy metals. Two types of agricultural waste used in this research namely oil palm mesocarp fiber (Elaesis guineensis sp.) (OPMF) and mangrove bark (Rhizophora apiculate sp.) (MB) biomass. Through chemical treatment, the removal efficiency was found to improve. The removal efficiency is examined based on four specification namely dosage, of biosorbent to adsorb four types of metals ion explicitly nickel, lead, copper, and chromium. The research has found that the removal efficiency of MB was lower than OPMF; whereas, the multiple metals ions removal efficiency decreased in the order of Pb2+ > Cu2+ > Ni2+ > Cr2+.


2019 ◽  
Vol 70 (5) ◽  
pp. 1507-1512
Author(s):  
Baker M. Abod ◽  
Ramy Mohamed Jebir Al-Alawy ◽  
Firas Hashim Kamar ◽  
Gheorghe Nechifor

The aim of this study is to use the dry fibers of date palm as low-cost biosorbent for the removal of Cd(II), and Ni(II) ions from aqueous solution by fluidized bed column. The effects of many operating conditions such as superficial velocity, static bed height, and initial concentration on the removal efficiency of metal ions were investigated. FTIR analyses clarified that hydroxyl, amine and carboxyl groups could be very effective for bio-sorption of these heavy metal ions. SEM images showed that dry fibers of date palm have a high porosity and that metal ions can be trapped and sorbed into pores. The results show that a bed height of 6 cm, velocity of 1.1Umf and initial concentration for each heavy metal ions of 50 mg/L are most feasible and give high removal efficiency. The fluidized bed reactor was modeled using ideal plug flow and this model was solved numerically by utilizing the MATLAB software for fitting the measured breakthrough results. The breakthrough curves for metal ions gave the order of bio-sorption capacity as follow: Cd(II)]Ni(II).


2020 ◽  
Vol 13 ◽  
Author(s):  
Rishabha Malviya ◽  
Pramod Sharma ◽  
Akanksha Sharma

: Manuscript discussed about the role of polysaccharides and their derivatives in the removal of metal ions from industrial waste water. Quick modernization and industrialization increases the amount of various heavy metal ions in the environment. They can possess various disease in humans and also causes drastic environmental hazards. In this review the recent advancement for the adsorption of heavy metal ions from waste water by using different methods has been studied. Various natural polymers and their derivatives are act as effective adsorbents for the removal of heavy metal ions from the waste water released from the industries and the treated water released into the environment can decreases the chances of diseases in humans and environmental hazards. From the literature surveys it was concluded that the removal of heavy metal ions from the industrial waste water was important to decrease the environmental pollution and also diseases caused by the heavy metal ions. Graft copolymers were acts as most efficient adsorbent for the removal of heavy metal ions and most of these followed the pseudo first order and pseudo second order model of kinetics.


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