Rotational structure of triplet–singlet transitions in orthorhombic molecules in intermediate and high magnetic fields
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The Zeeman band profiles are calculated for near-case (b) triplet–singlet transitions in asymmetric rotors, making allowance for the intensity perturbations induced by an external magnetic field. It is shown that new bands correlating with zero-field forbidden lines can be observed under the effect of sufficiently high fields. Band profiles and the patterns of the magnetic sublevels of the triplet state split by the external field are discussed in detail for the Paschen–Back limit.
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2002 ◽
Vol 16
(20n22)
◽
pp. 3355-3359
2015 ◽
Vol 15
(1)
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pp. 41-48
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1971 ◽
Vol 49
(21)
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pp. 3577-3578
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