Oxidations involving silver. V. The oxidation of primary aliphatic amines
1969 ◽
Vol 47
(20)
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pp. 3729-3736
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Keyword(s):
Primary aliphatic amines are rapidly oxidized using a silver electrode at potentials more positive than 0.6 V normal hydrogen electrode (n.h.e.) in aqueous alkali. Primary aliphatic amines with a mono-substituted α-carbon atom give the corresponding nitrile and aldehyde, α,α-disubstituted ones give the corresponding ketone, and α,α,α-trisubstituted ones give the corresponding alcohol, nitro-compound, and unsaturated hydrocarbons. Some evidence for the reaction pathway is presented. The effect of amine on the kinetic parameters for Ag2O formation is reported.
2007 ◽
Vol 111
(2)
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pp. 408-422
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2011 ◽
Vol 134
(24)
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pp. 244508
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1969 ◽
Vol 21
(02)
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pp. 325-331
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2019 ◽
Vol 116
(52)
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pp. 26353-26358
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2015 ◽
Vol 17
(40)
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pp. 27103-27108
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2015 ◽
Vol 81
(16)
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pp. 5387-5394
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1933 ◽
Vol 16
(6)
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pp. 859-873
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2013 ◽
Vol 25
(18)
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pp. 184008
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