The halide elements are environmentally important and share some common attributes. The heaviest, I, and the lighest, F, are quite toxic and are important industrial pollutants. They are also effectively retained in soils. The others, Cl and Br, can be accumulated to high concentrations in plants, are used in agriculture and are highly mobile in soils. This study investigated the behaviour of the halides in plots, outdoor lysimeters, and laboratory sorption and excised-root experiments. Sorption on soil was ordered as F > I > Br > Cl. Concentrations in plants were generally ordered as CI ≥ Br > > F ≥ I, the inverse of the sorption ordering, as expected. Older tissues, which were also closest to the soil surface, had higher concentrations, and sequestered tissues, such as corn kernels and cabbage heads, had lower concentrations. There was evidence of competitive interaction among the halides and with soil anions such as phosphate and sulfate. This competition reduced the toxicity of I and modified tissue concentrations of the halides, P and S. Another interesting interaction was an increase in Cl and I sorption on soil solids when there were elevated levels or the other halides. Overall, the study of the halides in combination enhanced our understanding of their individual behaviours. Key words: Fluoride, chloride, bromide, iodide, vegetable
Lipidomics of children and adolescents exposed to multiple industrial pollutants
