scholarly journals TERAHERTZ BLOCH OSCILLATOR WITH SUPPRESSED ELECTRIC DOMAINS: EFFECT OF ELASTIC SCATTERING

2009 ◽  
Vol 23 (20n21) ◽  
pp. 4459-4472 ◽  
Author(s):  
TIMO HYART ◽  
KIRILL N. ALEKSEEV ◽  
AHTI LEPPÄNEN ◽  
ERKKI V. THUNEBERG

We theoretically consider the amplification of THz radiation in a superlattice Bloch oscillator. The main dilemma in the realization of THz Bloch oscillator is finding operational conditions which allow simultaneously to achieve gain at THz frequencies and to avoid destructive space-charge instabilities. A possible solution to this dilemma is the extended Limited Space-Charge Accumulation scheme of Kroemer (H. Kroemer, cond-mat/0009311). Within the semiclassical miniband transport approach we extend its range of applicability by considering a difference in the relaxation times for electron velocity and electron energy. The kinetics of electrons and fields establishing a stationary signal in the oscillator is also discussed.

2020 ◽  
Vol 140 (5) ◽  
pp. 276-284
Author(s):  
Maimi Mima ◽  
Tokihiro Narita ◽  
Hiroaki Miyake ◽  
Yasuhiro Tanaka ◽  
Masahiro Kozako ◽  
...  

2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>


1994 ◽  
Vol 30 (11) ◽  
pp. 143-146
Author(s):  
Ronald D. Neufeld ◽  
Christopher A. Badali ◽  
Dennis Powers ◽  
Christopher Carson

A two step operation is proposed for the biodegradation of low concentrations (&lt; 10 mg/L) of BETX substances in an up flow submerged biotower configuration. Step 1 involves growth of a lush biofilm using benzoic acid in a batch mode. Step 2 involves a longer term biological transformation of BETX. Kinetics of biotransformations are modeled using first order assumptions, with rate constants being a function of benzoic acid dosages used in Step 1. A calibrated computer model is developed and presented to predict the degree of transformation and biomass level throughout the tower under a variety of inlet and design operational conditions.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1003
Author(s):  
Michiaki Matsumoto ◽  
Tadashi Hano

The non-enzymatic synthesis of N-benzyloxycarbonyl-L-phenylalanyl-L-leucine (Cbz-Phe-Leu) from lipophilic N-benzyloxycarbonyl-L-phenylalanine (Cbz-Phe) and hydrophilic L-leucine (Leu), by N, N’-dicyclohexylcarbodiimide (DCC) as a condensing agent, was carried out using a reversed micellar system composed of bis(2-ethylhexyl) sodium sulfosuccinate (AOT) as a surfactant and isooctane. We successfully synthesized Cbz-Phe-Leu in a short time and investigated the effects of its operational conditions, the DCC concentration, w0, and the pH on the kinetic parameters and the maximum yields. For dipeptide synthesis, we had to add an excess of DCC with the substrates because of the side reactions of Cbz-Phe. From the pH dependency of the reactivity, a partially cationic form of Leu was better for a synthesis reaction because of the enrichment of Leu at the interface by anionic AOT. The optimum water content on the dipeptide synthesis was w0 = 28 due to the competition of the peptide synthesis and the side reactions. The maximum yield of Cbz-Phe-Leu was 0.565 at 80 h under optimum experimental conditions.


2008 ◽  
Vol 24 (1) ◽  
pp. 14-24 ◽  
Author(s):  
S. Delpino ◽  
D. Fabiani ◽  
G.C. Montanari ◽  
C. Laurent ◽  
G. Teyssedre ◽  
...  

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