Structural and magnetic study of metallo-organic YIG powder using 2-ethylhexanoate carboxylate-based precursors

The crystallization and magnetic behavior of yttrium iron garnet (YIG) prepared by metallo-organic decomposition (MOD) method are discussed. The chemistry and physics related to synthesis of iron and yttrium carboxylates based on 2-ethylhexanoic acid (2EHA) are studied, since no literature was found which elucidates synthesis of metallo-organic precursor of YIG in spite of the literatures of doped YIG samples such as Bi-YIG. Typically, the metal carboxylates used in preparation of ceramic oxide materials are 2-ethylhexanoate (2EH) solvents. Herein, the synthesis, thermal behavior and solubility of yttrium and iron 2EH used in synthesis of YIG powder by MOD are reported. The crystallization and magnetic parameters, including saturation magnetization and coercivity of these samples, smoothly change as a function of the annealing temperature. It is observed that high sintering temperature of [Formula: see text] to [Formula: see text] promotes the diffraction peaks of YIG, therefore, we can conclude that the formation of YIG in MOD method increases the crystallization temperature. The maximum value of saturation magnetization and minimum value of coercivity and remanence are observed for the sample sintered at [Formula: see text] which are 13.7 emu/g, 10.38 Oe and 1.5 emu/g, respectively. This study cites the drawbacks in chemical synthesis of metallo-organic-based YIG production.

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Preparation and Magnetic Properties of Low Temperature Sintering Bi-Substituted Yttrium Iron Garnet

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.280-283.481 ◽

2007 ◽

Vol 280-283 ◽

pp. 481-484 ◽

Cited By ~ 3

Author(s):

Hong Jie Zhao ◽

Ji Zhou ◽

Zhi Lun Gui ◽

Long Tu Li

Keyword(s):

Magnetic Properties ◽

Low Temperature ◽

Saturation Magnetization ◽

Yttrium Iron Garnet ◽

Sintering Temperature ◽

Initial Permeability ◽

Yttrium Iron ◽

Garnet Phase ◽

Iron Garnet ◽

Ferromagnetic Resonance Linewidth

The low temperature sinterability and magnetic properties of Bi-substituted yttrium iron garnet (YIG) polycrystalline samples were studied in this paper. The results showed that Bi-substitution can lower garnet phase formation temperature from about 1200oC to 900oC and ceramic sintering temperature from over 1300oC to about 1050oC respectively. The Bi-substitution leads to a decrease in initial permeability and an increase in ferromagnetic resonance linewidth (ΔH) of sintered specimens. Saturation magnetization decreases and coercive force increases a few with an increase of Bi content. The mechanism of Bi-substitution on initial permeability and ΔH is discussed. The change in initial permeability of Bi-substituted specimens relative to unsubstituted YIG results from Bismuth volatilization and weakening of superexchange interaction. The lattice dilatation in Bi-substituted YIG gives cause for a decrease of saturation magnetization and an increase of coactivity force.

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Morphology-dependent spin Seebeck effect in yttrium iron garnet thin films prepared by metal-organic decomposition

Ceramics International ◽

10.1016/j.ceramint.2021.02.249 ◽

2021 ◽

Author(s):

Trinh Nguyen Thi ◽

Phuoc Cao Van ◽

Duc Duong Viet ◽

Viet Dong Quoc ◽

Hayeong Ahn ◽

...

Keyword(s):

Thin Films ◽

Yttrium Iron Garnet ◽

Seebeck Effect ◽

Yttrium Iron ◽

Spin Seebeck Effect ◽

Metal Organic ◽

Iron Garnet ◽

Organic Decomposition

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Magnetic behavior and characterization of La, Pr, and Bi substituted yttrium iron garnet

Materials Chemistry and Physics ◽

10.1016/j.matchemphys.2020.124067 ◽

2021 ◽

Vol 259 ◽

pp. 124067

Author(s):

O. Dehghani Dastjerdi ◽

H. Shokrollahi ◽

N. Asakereh Raad

Keyword(s):

Yttrium Iron Garnet ◽

Magnetic Behavior ◽

Yttrium Iron ◽

Iron Garnet

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Magneto-optic property measurement of bismuth substituted yttrium iron garnet films prepared by metal-organic-decomposition method at the 1310-nm and 1550-nm wavelengths

Journal of Magnetism and Magnetic Materials ◽

10.1016/j.jmmm.2019.165673 ◽

2019 ◽

Vol 492 ◽

pp. 165673 ◽

Cited By ~ 1

Author(s):

Yudeuk Kim ◽

David Juseong Bang ◽

Yonghwan Kim ◽

Jinyong Jung ◽

Namjung Hur ◽

...

Keyword(s):

Yttrium Iron Garnet ◽

Decomposition Method ◽

Yttrium Iron ◽

Garnet Films ◽

Optic Property ◽

Metal Organic ◽

Property Measurement ◽

Iron Garnet ◽

Organic Decomposition ◽

Magneto Optic

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Effect of annealing temperature on surface morphology and ultralow ferromagnetic resonance linewidth of yttrium iron garnet thin film grown by rf sputtering

Applied Surface Science ◽

10.1016/j.apsusc.2017.11.129 ◽

2018 ◽

Vol 435 ◽

pp. 377-383 ◽

Cited By ~ 12

Author(s):

Phuoc Cao Van ◽

Srivathsava Surabhi ◽

Viet Dongquoc ◽

Rambabu Kuchi ◽

Soon-Gil Yoon ◽

...

Keyword(s):

Thin Film ◽

Surface Morphology ◽

Ferromagnetic Resonance ◽

Yttrium Iron Garnet ◽

Annealing Temperature ◽

Rf Sputtering ◽

Yttrium Iron ◽

Resonance Linewidth ◽

Iron Garnet ◽

Ferromagnetic Resonance Linewidth

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A comparison of converse magnetoelectric coupling effect of YIG film on FE and AFE ceramic substrates

Ferroelectrics ◽

10.1080/00150193.2020.1713349 ◽

2020 ◽

Vol 557 (1) ◽

pp. 1-8

Author(s):

Han Liuyang ◽

Ponchel Freddy ◽

Rémiens Denis ◽

Lasri Tuami ◽

Tiercelin Nicolas ◽

...

Keyword(s):

Coupling Effect ◽

Switching Field ◽

Bias Magnetic Field ◽

Yttrium Iron ◽

Ceramic Substrates ◽

Pzt Ceramics ◽

Advantages And Disadvantages ◽

Maximum Value ◽

Iron Garnet ◽

Magnetoelectric Coupling Effect

The magnetoelectric properties of laminated heterostructures consisting of ferromagnetic yttrium iron garnet (YIG) films deposited on antiferroelectric (AFE) (Pb0.97La0.02)(Zr0.6Sn0.3Ti0.1)O3 (PLZST) and on ferroelectric (FE) 0.75Pb(Mg1/3Nb2/3)O3-0.25Pb(Zr0.48Ti0.52)O3 (PMN-PZT) ceramics are compared in this work. In particular, the Converse Magneto Electric (CME) coefficient is evaluated for these two types of structures. When the electric field is applied on an AFE ceramic, the CME coefficient peaks at the switching field and, without bias magnetic field, the maximum value is 11.6 × 10−8 s/m. In case of a FE ceramic, at the electric coercive field, the CME coefficient can reach 17 × 10−8 s/m at 0 Oe. Each structure has advantages and disadvantages depending on the applications.

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Saturation magnetization of gallium‐substituted yttrium iron garnet

Journal of Applied Physics ◽

10.1063/1.1663657 ◽

1974 ◽

Vol 45 (6) ◽

pp. 2728-2732 ◽

Cited By ~ 101

Author(s):

P. Hansen ◽

P. Röschmann ◽

W. Tolksdorf

Keyword(s):

Saturation Magnetization ◽

Yttrium Iron Garnet ◽

Yttrium Iron ◽

Iron Garnet

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Local order and magnetic behavior of amorphous and nanocrystalline yttrium iron garnet produced by swift heavy ion irradiations

Journal of Applied Physics ◽

10.1063/1.372110 ◽

2000 ◽

Vol 87 (4) ◽

pp. 1899-1907 ◽

Cited By ~ 14

Author(s):

J. M. Costantini ◽

J. M. Desvignes ◽

A. Pérez ◽

F. Studer

Keyword(s):

Yttrium Iron Garnet ◽

Magnetic Behavior ◽

Heavy Ion ◽

Local Order ◽

Yttrium Iron ◽

Swift Heavy Ion ◽

Iron Garnet

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Effect of pH and annealing temperature on the structural and magnetic properties of cerium-substituted yttrium iron garnet powders produced by the sol-gel method

Materials Science-Poland ◽

10.1515/msp-2016-0036 ◽

2016 ◽

Vol 34 (2) ◽

pp. 362-367 ◽

Cited By ~ 5

Author(s):

I. Yarici ◽

M. Erol ◽

E. Celik ◽

Y. Ozturk

Keyword(s):

Magnetic Properties ◽

Yttrium Iron Garnet ◽

Annealing Temperature ◽

Ph Value ◽

Sol Gel ◽

Chelating Agent ◽

Yttrium Iron ◽

Gel Method ◽

Sol Gel Method ◽

Iron Garnet

AbstractCerium substituted yttrium iron garnet (Ce0.2Y2.8Fe5O12; Ce-YIG) nanoparticles were produced via the sol-gel method from solutions of Ce-, Y- and Fe-based precursors, a solvent and a chelating agent. The solutions were dried at 200°C and heat treated at temperatures between 800 °C and 1400°C for 3 h in air. The effects of pH and annealing temperature on the structure, phase formation, magnetic properties and crystallite size were investigated. A cubic YIG phase was obtained for the sample annealed at 1400 °C. The presented results showed that the pH value of the starting solution affects the crystal size and consequently, the saturation magnetization.

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