Synthesis, characterization and catalytic oxidation performance of new planar binuclear phthalocyanines sharing the benzene ring

2010 ◽  
Vol 14 (10) ◽  
pp. 904-910 ◽  
Author(s):  
Guiguang Lu ◽  
Yulu Zhou ◽  
Yuzhi Xiang ◽  
Daohong Xia
Keyword(s):  
Sulfuric Acid ◽  
Ammonium Molybdate ◽  
Trimellitic Anhydride ◽  
H Nmr ◽  
Immobilized Catalyst ◽  
Crude Product ◽  
Oxidation Performance ◽  
Alkaline Conditions ◽  
Concentrated Sulfuric Acid ◽  
Better Than

The crude product of hexacarboxy biphtalocyanines cobalt ( CoBPcC6 ) was synthesized by fusing trimellitic anhydride, pyromellitic dianhydride, urea and CoCl2 · 6H2O with ammonium molybdate as catalyst and then hydrolyzed under alkaline conditions. The crude product was isolated by acidifying with hydrochloric acid followed by filtration, then purified by reprecipitation from concentrated sulfuric acid followed by chromatography on silica gel column. CoBPcC6 was characterized by IR, UV-vis, 1 H NMR, elemental analysis, etc. The activity of CoBPcC6 catalyst for extractive sweetening was evaluated by studying mercaptide oxidation. It was found that the performance of this immobilized catalyst was better than the commercial immobilized catalyst.

scholarly journals PICKLING EXPERIMENTAL STUDY ON PREPARATION OF DIESEL OIL WITH PYROLYSIS OIL FROM WASTE RUBBER

2017 ◽  
Vol 1 ◽  
pp. 169
Author(s):  
Wang Lei ◽  
Wang Yun ◽  
Jin Jie
Keyword(s):  
Experimental Study ◽  
Sulfuric Acid ◽  
Hydrochloric Acid ◽  
Diesel Oil ◽  
Pyrolysis Oil ◽  
Waste Rubber ◽  
Pickling Process ◽  
Concentrated Sulfuric Acid ◽  
Better Than

The research has been done for removing asphaltene by pickling process of diesel oil from pyrolysis oil self-made by waste rubber in this paper, and the study showed that pickling effect of concentrated sulfuric acid was better than concentrated hydrochloric acid. The best pickling effect was found when the concentration of sulfuric acid was 18.4mol/L, acid to oil ratio, namely, the amount of concentration of sulfuric acid to the amount of diesel oil ratio, was 25%. This experiment proved that removing asphaltene by pickling process using concentrated sulfuric acid was remarkable.

Preparation and Properties of Sulfonated β-Cyclodextrins Used as Water-Reducer

2012 ◽  
Vol 430-432 ◽  
pp. 729-732 ◽  
Author(s):  
Sheng Hua Lv ◽  
Rui Jun Gao ◽  
Di Li
Keyword(s):  
Molecular Structure ◽  
Sulfuric Acid ◽  
Characterization Methods ◽  
H Nmr ◽  
Zeta Potentials ◽  
Potential Value ◽  
Concentrated Sulfuric Acid ◽  
Adsorption Amount ◽  
Dispersing Ability ◽  
Value Changes

Sulfonated β-cyclodextrin was synthesized with β–cyclodextrins (β-CD) and concentrated sulfuric acid. The molecular structure of sulfonated β-cyclodextrin was characterized by FTIR and 1H-NMR. The dispersing ability of sulfonated β-cyclodextrin was investigated using various characterization methods like paste fluidity, adsorption amount and zeta potentials measurements. The results show that compared with sulphonated naphthalene based superplasticizer (NPS), the fluidity of cement paste dosage with sulfonated β-cyclodextrin is 248 mm, the zeta potential value changes from 11.5 mV to-19.6 mV with the concentration of sulfonated β-cyclodextrin increasing from 0 to 15 g/L and the maximum adsorption amount is 20 mg/g. Meanwhile, FTIR and 1H-NMR results indicate that the sulfonic groups were grafted successfully on the molecular chain of the β-CD.

Modified Synthesis of 2-Ethoxycarbonyl-3,4-Diethyl-Pyrrole and the Corresponding Octaethylporphyrin

2014 ◽  
Vol 884-885 ◽  
pp. 465-470
Author(s):  
Qi Feng Liu
Keyword(s):  
Sulfuric Acid ◽  
Low Temperature ◽  
Acetic Anhydride ◽  
Acetyl Chloride ◽  
Toluene Solution ◽  
Organic Base ◽  
Crude Product ◽  
Concentrated Sulfuric Acid ◽  
Boiling Toluene

In the synthesis of 2-ethoxycarbonyl-3, 4-diethyl-pyrrole (1) by the Barton-Zard reaction of 4-acetoxy-3-nitrohexane (1b) with ethyl isocyanoacetate, the organic base 1, 8-diazabicyclo [5.4.0] undec-7-ene (DBU) and the solvent tetrahydrofuran (THF) were replaced with K2CO3 and ethanol, respectively. Moreover, the preparation of the intermediate 1b from 1a by acetylation reaction was carried out by employing acetyl chloride in boiling toluene solution instead of acetic anhydride and the catalyst concentrated sulfuric acid. After treatment of 1 with excess LiAlH4 at low temperature, the crude product 1c (α-hydroxymethyl-3, 4-diethyl-pyrrole) was immediately reacted via a tetramerization in the presence of the catalyst BF3.OEt2 in crude CHCl3,followed by oxidation of 2, 3-dichloro-5, 6-dicyano-1, 4-benzoquinone (DDQ) to provide the corresponding octaethylporphyrin 2. The results indicate that using BF3.OEt2 as catalyst instead of p-toluenesulphonic acid (p-TsOH)in the synthesis of 2 from 1c can obviously increase the yield of product 2 up to 80% from 69%.

scholarly journals SYNTHESIS OF POLYPROPYLCALIX[6]ARENE FROM p-t-BUTYLPHENOL AS ADSORBENT FOR Cr(III) METAL ION

2011 ◽  
Vol 11 (1) ◽  
pp. 37-42 ◽  
Author(s):  
Susy Yunita Prabawati ◽  
Jumina Jumina ◽  
Sri Juari Santosa ◽  
Mustofa Mustofa
Keyword(s):  
Heavy Metal ◽  
Sulfuric Acid ◽  
Contact Time ◽  
Metal Ion ◽  
Nmr Spectra ◽  
Allyl Bromide ◽  
Starting Material ◽  
Heavy Metal Cation ◽  
Alkaline Conditions ◽  
Concentrated Sulfuric Acid

A study has been conducted to synthesize a novel polypropylcalix[6]arene polymer using p-t-butylphenol as a starting material. It was of interest to investigate the capability of the polymer with a tunnel-like structure, as adsorbent to trap the heavy metal cation such as Cr3+. The synthesis was carried out in several steps i.e (1) formation of p-t-butylcalix[6]arene from p-t-butylphenol as a starting material, (2) treatment of p-t-butylcalix[6]arene with 4.95 equivalents of allyl bromide under  alkaline conditions to yield p-t-butyl-37,40-diallyloxy-38,39,41,42-tetra-hydroxy-calix[6]arene, and (3) polymerization of p-t-butyl-37,40-diallyloxy-38,39,41,42-tetrahydroxycalix[6]arene by treatment with concentrated sulfuric acid to yield polypropyl-calix[6]arene. The application of polypropylcalix[6]arene for trapping Cr(III) was investigated by stirring the suspension of calixarene under variation of pH, time, and adsorbent mass. IR and 1H NMR spectra, showed that two allyl groups had been incorporated to the lower rim of the p-t-butylcalix[6]arene and the polymer was obtained as brownish green crystals with the melting point of 108-110 °C. The study also showed that the polypropylcalix[6]arene was able to trap Cr(III) cation. The optimum adsorption conditions were achieved at pH 5, contact time 60 min and concentration 12 mg/l for every 0,008 g of polymer.

Gallium Arsenide Integrated Circuits Decapsulation Technique Using Mixed Acid Chemistry For Die-Level Failure Analysis

2018 ◽  
Author(s):  
Harold Jeffrey M. Consigo ◽  
Ricardo S. Calanog ◽  
Melissa O. Caseria
Keyword(s):  
Gallium Arsenide ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Integrated Circuits ◽  
Failure Analysis ◽  
Mixed Acid ◽  
Optimum Parameters ◽  
Plastic Package ◽  
Fuming Nitric Acid ◽  
Concentrated Sulfuric Acid

Abstract Gallium Arsenide (GaAs) integrated circuits have become popular these days with superior speed/power products that permit the development of systems that otherwise would have made it impossible or impractical to construct using silicon semiconductors. However, failure analysis remains to be very challenging as GaAs material is easily dissolved when it is reacted with fuming nitric acid used during standard decapsulation process. By utilizing enhanced chemical decapsulation technique with mixture of fuming nitric acid and concentrated sulfuric acid at a low temperature backed with statistical analysis, successful plastic package decapsulation happens to be reproducible mainly for die level failure analysis purposes. The paper aims to develop a chemical decapsulation process with optimum parameters needed to successfully decapsulate plastic molded GaAs integrated circuits for die level failure analysis.

PRODUCTION OF SULFOCATIONITE BY MODIFICATION OF NATURAL COAL WITH CONCENTRATED SULFURIC ACID

2020 ◽  
Vol 3 (441) ◽  
pp. 104-109
Author(s):  
N.A. Bektenov ◽  
◽  
N.C. Murzakassymova ◽  
M.A. Gavrilenko ◽  
А.N. Nurlybayeva ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Concentrated Sulfuric Acid ◽  
Natural Coal

Addition of primary alcohols to 3-chlorononafluoro-1,5-hexadiene and perfluoro-1,3,5-hexatriene

1985 ◽  
Vol 50 (8) ◽  
pp. 1714-1726 ◽  
Author(s):  
Václav Dědek ◽  
Igor Linhart ◽  
Milan Kováč
Keyword(s):  
Sulfuric Acid ◽  
Primary Alcohols ◽  
Principal Product ◽  
Allyl Rearrangement ◽  
Concentrated Sulfuric Acid ◽  
Sodium Alkoxide

Sodium alkoxide-catalyzed addition of methanol, ethanol and propanol to 3-chlorononafluoro-1,5-hexadiene (I) proceeds at temperatures -35 °C to 8 °C with allyl rearrangement, affording 1,6-dialkoxy-1,1,2,3,4,4,5,6,6-octafluoro-2,4-hexadiene (V) as the principal product, along with 1,6-dialkoxy-1,2,3,3,4,5,6,6-octafluoro-1,5-diene (VI) and trans-1,6-dialkoxy-1,1,2,3,4,4,5,6,6-nonafluoro-2-hexene (VII). The ethers Va-Vc consist of the cis,trans- and trans,trans-isomers in about 3 : 1 ratio, whereas the ethers VIa-VIc have trans,trans-configuration. Ethers Vc and VIc react with concentrated sulfuric acid to give dipropyl 2,3,4,5-tetrafluoro-2,4-hexadienedioate (IX) and dipropyl 2,3,4,4,5-pentafluoro-2-hexenedioate (X), respectively, whereas the ether VIIc affords a mixture of propyl 6-propyloxy-2,3,4,4,5,6-heptafluoro-2-hexenoate (XI) and ester X. Addition of methanol to perfluoro-1,3,5-hexatriene (II) affords 1,1,2,3,4,5,6,6-octafluoro-1,6-dimethoxy-3-hexene (XIII) as the principal product.

scholarly journals 4,5,6-Trichloropyrimidine-2-carboxamide

Molbank ◽  
10.3390/m1190 ◽  
2021 ◽  
Vol 2021 (1) ◽  
pp. M1190
Author(s):  
Andreas S. Kalogirou ◽  
Panayiotis A. Koutentis
Keyword(s):  
Sulfuric Acid ◽  
Elemental Analysis ◽  
Maldi Tof ◽  
Concentrated Sulfuric Acid

Reaction of 4,5,6-trichloropyrimidine-2-carbonitrile (1) with concentrated sulfuric acid at ca. 20 °C gave 4,5,6-trichloropyrimidine-2-carboxamide (5) in 91% yield. The new compound was fully characterized by IR, MALDI-TOF, NMR and elemental analysis.

Sign in / Sign up

Export Citation Format

Share Document