Small Polymeric Toys Placed in Child-Dedicated Chocolate Food Products—Do They Contain Harmful Chemicals? Examination of Quality by Example of Selected VOCs and SVOCs

This study was focused on child-dedicated chocolate food products that contain a plastic package with a small toy inside (also known as chocolate eggs). Three types of these products that are commercially available on the Polish market, with different prices, chocolate composition, and main types of polymers used in the toy manufacturing process, were investigated. The polymers were identified using Fourier-transform infrared (FT-IR) analysis and emissions of selected toxic volatile organic compounds of toy and packaging samples were identified using stationary emission micro-chamber. Total volatile organic compounds emissions were also estimated. Moreover, the content of polybrominated diphenyl ethers (PBDEs) as bioaccumulative semi-volatile organic compounds was checked in all parts of the cheapest product. The highest PBDE concentrations, which ranged from 5.32 ± 0.79 to 1768 ± 289 ng/g, were recorded in chocolate samples. This demonstrates the need for consumer knowledge on the safety of such products available on the Polish market to be broadened. This is one of the many examples of studies showing that products sold on the European market do not always comply with the Conformité Européenne (CE) declaration of conformity. Furthermore, the presence of phased-out PBDEs in toys may provide evidence of wrong recycling practices. Forward-looking considerations showed that, based on assessments of the hazard quotient (HQ) and cancer risk of BDE-209 and assuming each child has contact with one toy and eats one of the studied chocolate products per day, there is no high risk associated with the exposure of children to PBDEs.

Simulation of Thermal and Electric Field Distribution in Packaged Sausages Heated in a Stationary Versus a Rotating Microwave Oven

The microwave oven has become a standard appliance to reheat or cook meals in households and convenience stores. However, the main problem of microwave heating is the non-uniform temperature distribution, which may affect food quality and health safety. A three-dimensional mathematical model was developed to simulate the temperature distribution of four ready-to-eat sausages in a plastic package in a stationary versus a rotating microwave oven, and the model was validated experimentally. COMSOL software was applied to predict sausage temperatures at different orientations for the stationary microwave model, whereas COMSOL and COMSOL in combination with MATLAB software were used for a rotating microwave model. A sausage orientation at 135° with the waveguide was similar to that using the rotating microwave model regarding uniform thermal and electric field distributions. Both rotating models provided good agreement between the predicted and actual values and had greater precision than the stationary model. In addition, the computational time using COMSOL in combination with MATLAB was reduced by 60% compared to COMSOL alone. Consequently, the models could assist food producers and associations in designing packaging materials to prevent leakage of the packaging compound, developing new products and applications to improve product heating uniformity, and reducing the cost and time of the research and development stage.

Small polymeric toys placed in child-dedicated chocolate food products - do they contain harmful chemicals? Examination of quality by example of selected VOCs and SVOCs

This study was focused on child-dedicated chocolate food products that contain a plastic package with a small toy inside (also known as chocolate eggs). Three types of these products that are commercially available on the Polish market, with different prices, chocolate composition, and main types of polymers used in the toy manufacturing process, were investigated. First, to fully characterise the studied polymer samples, the main types of material in the studied toys and their packaging were identified using Fourier-transform infrared (FT-IR) analysis. Next, the emissions of selected toxic volatile organic compounds (VOCs) of toy and packaging samples were identified using stationary emission micro-chamber. Total volatile organic compounds (TVOC) emissions were also estimated. Moreover, the content of polybrominated diphenyl ethers (PBDEs) as bioaccumulative semi-volatile organic compounds (SVOCs) was checked in all parts of the cheapest product. The highest PBDE concentrations, which ranged from 5.32±0.79 to 1768±289 ng/g, were recorded in chocolate samples. This demonstrates the need for consumer knowledge on the safety of such products available on the Polish market to be broadened. This is one of the many examples of studies showing that products sold on the European market do not always comply with the CE declaration of conformity. Furthermore, the presence of phased-out PBDEs in toys may provide evidence of wrong recycling practices. Forward-looking considerations showed that, based on assessments of the hazard quotient (HQ) and cancer risk of BDE-209 (CRBDE-209) and assuming each child has contact with one toy and eats one of the studied chocolate products per day, there is no high risk associated with the exposure of children to PBDEs.

Shelf life extension of peach palm heart packed in different plastic packages

ABSTRACT Peach palm heart (Bactris gasipaes) is a highly perishable product and, therefore, studies on extending its shelf life are quite necessary. Considering the high demand of this vegetable, this study aimed to evaluate the influence of using different plastic packages in order to extend the shelf life of the peach palm heart in natura. Stipes were collected from plants grown on family farms located in the municipality of Seropédica-RJ. Stipes were peeled, sanitized and packed at the Post-harvest Laboratory in Universidade Federal Rural do Rio de Janeiro (UFRRJ). In this experiment, the following treatments were applied: a control without package (C), unperforated polyethylene bag (UPB), perforated polyethylene bag (PPB), microperforated polyethylene bag (MPPB), and styrofoam tray + plastic film (STPF). The material was stored in a cold chamber under controlled temperature (5±2oC) for 24 days and then at room temperature (28±2oC) on the 25th day. Physical, chemical and visual evaluations were carried out for 25 days, with samples submitted to evaluations at 0 (initial characterization), 4, 8, 12, 16, 20, 24 and 25 days of storage. Microbiological evaluations were performed for 18 days, with samples submitted to evaluations at 0, 8, and 16 days of storage. The results indicate that using plastic package combined with refrigeration was efficient in extending the shelf life of in natura peach palm hearts, by reducing fresh mass loss, maintaining visual quality and reducing sample contamination. The PPB, UPB and MPPB packages showed good performance considering the shelf life extension of the packed vegetable. Thus, we recommend the acquisition of cheaper packages, so that smallholder farmers could obtain higher profitability.

K1986BE92QI and STM32F103C8 microcontrollers as signal processing devices: comparative analysis

The subject of the research is to compare domestic microcontroller versus foreign microcontroller while used as signal processing devices in general applications. The purpose of the research was to conduct a comparative analysis of the popular foreign microcontroller STM32F103C8T6 and its domestic analogue K1986BE92QI in plastic package through solving a typical problem in the form of a 64-point FFT computation and calculating the value of π number by the geometrical method. The obtained results are in line with those expected in terms of program execution time and stability of the debug mode in the MDKARM v5 development environment. In the course of research, the key features of working with the examined microcontrollers were identified. Practical relevance of the research consists in its practical applicability: the findings can be used as a supportive material in the creation of programmable radio engineering systems based on the microcontrollers under consideration.