scholarly journals PICKLING EXPERIMENTAL STUDY ON PREPARATION OF DIESEL OIL WITH PYROLYSIS OIL FROM WASTE RUBBER

2017 ◽  
Vol 1 ◽  
pp. 169
Author(s):  
Wang Lei ◽  
Wang Yun ◽  
Jin Jie
Keyword(s):  
Experimental Study ◽  
Sulfuric Acid ◽  
Hydrochloric Acid ◽  
Diesel Oil ◽  
Pyrolysis Oil ◽  
Waste Rubber ◽  
Pickling Process ◽  
Concentrated Sulfuric Acid ◽  
Better Than

The research has been done for removing asphaltene by pickling process of diesel oil from pyrolysis oil self-made by waste rubber in this paper, and the study showed that pickling effect of concentrated sulfuric acid was better than concentrated hydrochloric acid. The best pickling effect was found when the concentration of sulfuric acid was 18.4mol/L, acid to oil ratio, namely, the amount of concentration of sulfuric acid to the amount of diesel oil ratio, was 25%. This experiment proved that removing asphaltene by pickling process using concentrated sulfuric acid was remarkable.

The Preparation of 1,2-Bis(2,2′:6′,2′′-Terpyridin-4′yl)Ethanone: The First Example of 4′-Terpyridyls Unsymmetrically Linked by a Functionalized Two-Carbon Chain

2004 ◽  
Vol 57 (7) ◽  
pp. 689 ◽  
Author(s):  
Zhi-Long Chen ◽  
Ronald N. Warrener ◽  
Douglas N. Butler
Keyword(s):  
Sulfuric Acid ◽  
Hydrochloric Acid ◽  
Single Crystal ◽  
Coupling Reaction ◽  
Carbon Chain ◽  
Sodium Cyanide ◽  
Starting Material ◽  
X Ray ◽  
Concentrated Sulfuric Acid ◽  
Single Crystal Analysis

1,2-Bis(2,2′:6′,2′′-terpyridin-4′yl)ethanone 7, an unsymmetrically linked bis-tridentatate ligand, was prepared by treatment of 4′-cyanomethylterpyridine 10 (RT, overnight) or 4′-(methoxycarbonylmethyl)terpyridine 11 (60°C, 7 h) with concentrated hydrochloric acid. These conversions, which involved an unprecedented homo-coupling reaction, are discussed with the structure of 7 being confirmed by X-ray single crystal analysis. The nitrile starting material 10 was prepared by reaction of the mesylate 9, derived from the known 4′-hydroxymethylterpyridine 8 with sodium cyanide, while ester 11 was prepared by reaction of 10 with methanol in the presence of concentrated sulfuric acid.

The Electrical Conductivity Stability of Polyaniline Doped with Three Different Acids

2013 ◽  
Vol 774-776 ◽  
pp. 803-806
Author(s):  
Ren Chun Fu ◽  
Jun Du ◽  
Hui Huang ◽  
Zhong Cheng Guo
Keyword(s):  
Electrical Conductivity ◽  
Sulfuric Acid ◽  
Hydrochloric Acid ◽  
Temperature Dependence ◽  
Methanesulfonic Acid ◽  
Variable Range Hopping ◽  
As Doping ◽  
The Stability ◽  
Better Than

The doping acid will obviously effect on the properties of polyaniline. In order to investigate the industrial acids influence the electrical conductivity stability of polyaniline, the hydrochloric acid (HCl), sulfuric acid (SA) and methanesulfonic acid (MSA) in industrial degree were chosen as doping acids to synthesize polyaniline. The stability of electrical conductivity was measured by in situ temperature. The mechanism of temperature dependence of electrical conductivity was discussed. The results revealed that the stability of polyaniline doped by hydrochloric acid (HCl) was better than that of polyaniline doped by other acids. The variable-range hopping (VRH) model could explain the temperature dependence of electrical conductivity of polyaniline.

Synthesis, characterization and catalytic oxidation performance of new planar binuclear phthalocyanines sharing the benzene ring

2010 ◽  
Vol 14 (10) ◽  
pp. 904-910 ◽  
Author(s):  
Guiguang Lu ◽  
Yulu Zhou ◽  
Yuzhi Xiang ◽  
Daohong Xia
Keyword(s):  
Sulfuric Acid ◽  
Ammonium Molybdate ◽  
Trimellitic Anhydride ◽  
H Nmr ◽  
Immobilized Catalyst ◽  
Crude Product ◽  
Oxidation Performance ◽  
Alkaline Conditions ◽  
Concentrated Sulfuric Acid ◽  
Better Than

The crude product of hexacarboxy biphtalocyanines cobalt ( CoBPcC6 ) was synthesized by fusing trimellitic anhydride, pyromellitic dianhydride, urea and CoCl2 · 6H2O with ammonium molybdate as catalyst and then hydrolyzed under alkaline conditions. The crude product was isolated by acidifying with hydrochloric acid followed by filtration, then purified by reprecipitation from concentrated sulfuric acid followed by chromatography on silica gel column. CoBPcC6 was characterized by IR, UV-vis, 1 H NMR, elemental analysis, etc. The activity of CoBPcC6 catalyst for extractive sweetening was evaluated by studying mercaptide oxidation. It was found that the performance of this immobilized catalyst was better than the commercial immobilized catalyst.

scholarly journals Oxidative desulfurization of tire pyrolysis oil

2016 ◽  
Vol 22 (3) ◽  
pp. 249-254 ◽  
Author(s):  
Shahzad Ahmad ◽  
Muhammad Ahmad ◽  
Khawar Naeem ◽  
Muhammad Humayun ◽  
S Sebt-E-Zaeem ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Low Cost ◽  
Oxidative Desulfurization ◽  
High Price ◽  
Acid Mixture ◽  
Small Scale ◽  
Pyrolysis Oil ◽  
Experimental Conditions ◽  
Concentrated Sulfuric Acid ◽  
Pyrolysis Oils

This paper presents a low cost method for the purification of oils obtained from the pyrolysis of used tires. Oxidative desulfurization is a promising route for purification of tire pyrolysis oils as hydro-desulfurization may not be affordable for small scale industries. Different additives and acids have been employed for the enhancement of properties of pyrolytic oils. The experimental conditions were kept identical throughout, i.e. atmospheric pressure and 50?C temperature for comparison of performance of various additives. The use of hydrogen peroxide-acetic acid mixture (10 wt.%) was found more economical and effective in desulfurization and improvement of fuel properties of sample oils. The contribution of sulfuric acid in desulfurization and decreasing viscosity was also satisfactory but due to high price of concentrated sulfuric acid its use may not be economical. Calcium oxide and Fuller?s earth was not found to be effective in desulfurization. Results indicate that oxidative desulfurization could render tire pyrolysis oils suitable for blending as heating fuel.

DESAIN PEMBELAJARAN BAHASA INDONESIA BERBASIS PEMAHAMAN NILAI SIKAP GOTONG ROYONG

2020 ◽  
Vol 13 (2) ◽  
pp. 01-10
Author(s):  
Alpansyah Alpansyah ◽  
Abdul Talib Hasim
Keyword(s):  
Experimental Study ◽  
Language Learning ◽  
Reader Response ◽  
Female Students ◽  
Male Students ◽  
Mutual Cooperation ◽  
Male And Female ◽  
Quasi Experimental ◽  
Bahasa Indonesia ◽  
Better Than

The aims of this study were: (1) to identify an increase in students' understanding of the value of mutual cooperation through the use of reader response rules in Indonesian Language Learning (KRPDPBI); (2) identifying the use of the reader response principle in Indonesian Language learning (KRPDPBI) there are differences between male and female students. The design of this study used a quasi-experimental study with two different methods. The results showed that (1) the achievement of the score of understanding the value of mutual cooperation for students taught by KRPDPBI was better than for students taught by regular learning according to the curriculum; (2) the achievement of the understanding of the value of male students' mutual cooperation is no better than that of female students.

Gallium Arsenide Integrated Circuits Decapsulation Technique Using Mixed Acid Chemistry For Die-Level Failure Analysis

2018 ◽  
Author(s):  
Harold Jeffrey M. Consigo ◽  
Ricardo S. Calanog ◽  
Melissa O. Caseria
Keyword(s):  
Gallium Arsenide ◽  
Sulfuric Acid ◽  
Nitric Acid ◽  
Integrated Circuits ◽  
Failure Analysis ◽  
Mixed Acid ◽  
Optimum Parameters ◽  
Plastic Package ◽  
Fuming Nitric Acid ◽  
Concentrated Sulfuric Acid

Abstract Gallium Arsenide (GaAs) integrated circuits have become popular these days with superior speed/power products that permit the development of systems that otherwise would have made it impossible or impractical to construct using silicon semiconductors. However, failure analysis remains to be very challenging as GaAs material is easily dissolved when it is reacted with fuming nitric acid used during standard decapsulation process. By utilizing enhanced chemical decapsulation technique with mixture of fuming nitric acid and concentrated sulfuric acid at a low temperature backed with statistical analysis, successful plastic package decapsulation happens to be reproducible mainly for die level failure analysis purposes. The paper aims to develop a chemical decapsulation process with optimum parameters needed to successfully decapsulate plastic molded GaAs integrated circuits for die level failure analysis.

PRODUCTION OF SULFOCATIONITE BY MODIFICATION OF NATURAL COAL WITH CONCENTRATED SULFURIC ACID

2020 ◽  
Vol 3 (441) ◽  
pp. 104-109
Author(s):  
N.A. Bektenov ◽  
◽  
N.C. Murzakassymova ◽  
M.A. Gavrilenko ◽  
А.N. Nurlybayeva ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Concentrated Sulfuric Acid ◽  
Natural Coal

Addition of primary alcohols to 3-chlorononafluoro-1,5-hexadiene and perfluoro-1,3,5-hexatriene

1985 ◽  
Vol 50 (8) ◽  
pp. 1714-1726 ◽  
Author(s):  
Václav Dědek ◽  
Igor Linhart ◽  
Milan Kováč
Keyword(s):  
Sulfuric Acid ◽  
Primary Alcohols ◽  
Principal Product ◽  
Allyl Rearrangement ◽  
Concentrated Sulfuric Acid ◽  
Sodium Alkoxide

Sodium alkoxide-catalyzed addition of methanol, ethanol and propanol to 3-chlorononafluoro-1,5-hexadiene (I) proceeds at temperatures -35 °C to 8 °C with allyl rearrangement, affording 1,6-dialkoxy-1,1,2,3,4,4,5,6,6-octafluoro-2,4-hexadiene (V) as the principal product, along with 1,6-dialkoxy-1,2,3,3,4,5,6,6-octafluoro-1,5-diene (VI) and trans-1,6-dialkoxy-1,1,2,3,4,4,5,6,6-nonafluoro-2-hexene (VII). The ethers Va-Vc consist of the cis,trans- and trans,trans-isomers in about 3 : 1 ratio, whereas the ethers VIa-VIc have trans,trans-configuration. Ethers Vc and VIc react with concentrated sulfuric acid to give dipropyl 2,3,4,5-tetrafluoro-2,4-hexadienedioate (IX) and dipropyl 2,3,4,4,5-pentafluoro-2-hexenedioate (X), respectively, whereas the ether VIIc affords a mixture of propyl 6-propyloxy-2,3,4,4,5,6-heptafluoro-2-hexenoate (XI) and ester X. Addition of methanol to perfluoro-1,3,5-hexatriene (II) affords 1,1,2,3,4,5,6,6-octafluoro-1,6-dimethoxy-3-hexene (XIII) as the principal product.

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