scholarly journals High energy storage density with ultra-high efficiency and fast charging–discharging capability of sodium bismuth niobate lead-free ceramics

2021 ◽  
pp. 2150018
Author(s):  
Abdul Manan ◽  
Maqbool Ur Rehman ◽  
Atta Ullah ◽  
Arbab Safeer Ahmad ◽  
Yaseen Iqbal ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Efficiency ◽  
Perovskite Phase ◽  
Discharge Rate ◽  
High Energy ◽  
Low Dielectric ◽  
Dense Microstructure ◽  
Average Grain Size ◽  
Fast Charging ◽  
High Dielectric

Ceramics-based capacitors with excellent energy storage characteristics, fast charging/discharge rate, and high efficiency have received significant attention. In this work, Na[Formula: see text]Bi[Formula: see text]NbO3(NBN) ceramics were processed through solid-state sintering route. The investigated ceramics were crystallized in a single perovskite phase. Dense microstructure, with small average grain size ([Formula: see text]0.92 [Formula: see text]m) is obtained for the investigated ceramics. A high dielectric constant >1000 accompanied by a low dielectric loss was achieved for these ceramics at ambient temperature. A recoverable energy density [Formula: see text]0.92 J/cm3and ultra-high efficiency of 96.33% at 138 kV/cm were obtained at room temperature. Furthermore, a lower discharging time of 0.14 [Formula: see text]s was also achieved. This material is a suitable candidate for power pulsed applications.

Study of Dielectric Characteristics and Energy Storage Properties of Sr0.7Bi0.2TiO3 Doped with CaTiO3

2020 ◽  
Vol 842 ◽  
pp. 168-173
Author(s):  
Peng Zhao ◽  
Bin Tang ◽  
Feng Si ◽  
Cheng Tao Yang ◽  
Shu Ren Zhang
Keyword(s):  
Energy Storage ◽  
Dielectric Breakdown ◽  
Breakdown Strength ◽  
High Energy ◽  
Low Dielectric ◽  
Average Grain Size ◽  
Energy Storage Properties ◽  
Energy Storage Efficiency ◽  
Storage Properties ◽  
High Energy Storage

Sr0.7Bi0.2TiO3 (SBT), a kind of lead-free relaxor ferroelectric, is attracting more and more attention for pulse energy storage applications due to the low remnant polarization and high energy storage efficiency (h). However, relatively low dielectric breakdown strength (DBS) limited the recoverable energy storage density (Wrec). Herein, CaTiO3 with high intrinsic DBS was introduced in SBT. The novel solid solutions (1-x)SBT-xCT with x = 0 - 0.15 shows pure pseudo-cubic perovskite structure. When x = 0.05, the maxium polarization are improved, and the CT doping decreases the average grain size, leading to an enhanced DBS. A high energy storage properties of 1.59 J/cm3 with the h of 87.4% at 220 kV/cm is achieved in 0.95SBT-0.05CT, which demonstrates that this 0.95SBT-0.05CT is prospective materials for energy storage application.

Composition-Microstructure-Property Relationships in BaTiO3 with Mg Addition

2015 ◽  
Vol 659 ◽  
pp. 58-63
Author(s):  
Oratai Jongprateep ◽  
Tunchanoke Khongnakhon ◽  
Jednupong Palomas
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
Barium Titanate ◽  
High Efficiency ◽  
High Dielectric Constant ◽  
Dielectric Materials ◽  
High Energy ◽  
High Energy Density ◽  
Low Dielectric ◽  
High Dielectric

Rising worldwide demands for energy encourages development of high-efficiency energy storage and capacitor components. Main requirements for dielectric materials employed in fabrication of high energy density capacitors include high dielectric constant, high dielectric breakdown strength, and low dielectric loss. Owing to its high dielectric constant and low dielectric loss [1], barium titanate is among common capacitor materials. Tailoring of dielectric properties of barium titanate can be achieved through controlled chemical composition, microstructure, and crystal structure. Synthesis and processing techniques, as well as doping of barium titanate, can be key factors to control the composition and structure, which consequently contribute to enhancement of dielectric constant in the material.

Enhancement of Energy Storage Properties in PLZST Cramics with Different Zr/Sn Ratios

2014 ◽  
Vol 602-603 ◽  
pp. 916-920
Author(s):  
Qian Zhang ◽  
Yong Zhang ◽  
Xiao Lin Liu ◽  
Xiao Zhen Song ◽  
Jia Zhu
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Perovskite Phase ◽  
Hysteresis Loops ◽  
Lead Zirconate ◽  
High Energy ◽  
Average Grain Size ◽  
Energy Storage Properties ◽  
Higher Temperature ◽  
Storage Properties

The effect of Zr/Sn ratio on the dielectric and energy storage properties of lanthanum modified lead zirconate stannate titanate (PLZST) ceramics with compositions located near the boundary between antiferroelectric and ferroelectric phases was studied. Microstructural observation indicated that all the samples had a uniform morphology with pure perovskite phase and the average grain size reduced obviously with increasing Zr/Sn ratio. As the Zr/Sn ratio increased, the dielectric constant increased and the transition temperature Tm shifted to higher temperature. All the PLZST ceramics exhibited double hysteresis loops. The maximum polarization increased, while the switching field decreased when the Zr/Sn ratio increased. The variations of Zr/Sn ratio had little impact on remanent polarization. As a result, both charged energy density and discharged energy density increased with increasing Zr/Sn ratio. A high energy storage density of 1.75 J/cm3 was achieved in the PLZST ceramics with the Zr/Sn ratio of 82.5/7.5 at 9 kV/mm.

scholarly journals Ground Level Integrated Diverse Energy Storage (GLIDES) Cost Analysis

2018 ◽  
Author(s):  
Saiid Kassaee ◽  
Adewale Odukomaiya ◽  
Ahmad Abu-Heiba ◽  
Xiaobing Liu ◽  
Matthew M. Mench ◽  
...  
Keyword(s):  
Energy Storage ◽  
Economic Model ◽  
High Efficiency ◽  
Ground Level ◽  
High Energy ◽  
Capital Cost ◽  
High Energy Density ◽  
Oak Ridge ◽  
Storage Technology ◽  
Energy Storage Technology

With the increasing penetration of renewable energy, the need for advanced flexible/scalable energy storage technologies with high round-trip efficiency (RTE) and high energy density has become critical. In this paper, a techno-economic model of a novel energy storage technology developed by the Oak Ridge National Laboratory (ORNL) is presented and used to estimate the technology’s capital cost. Ground-Level Integrated Diverse Energy Storage (GLIDES) is an energy storage technology with high efficiency which can store energy via input of electricity and heat and supply dispatchable electricity. GLIDES stores energy by compressing and expanding a gas using a liquid piston. GLIDES performance has been extensively studied analytically and experimentally. This study aims to develop a comprehensive combined performance and cost modeling environment. With the desired system storage capacity kilowattage, storage time (hours), and an initial RTE guess as inputs, the model optimizes the selection of system components to minimize the capital cost. The techno-economic model described in this paper can provide preliminary cost estimates and corresponding performance for various system sizes and storage times.

scholarly journals Effect of sintering temperature on the dielectric, ferroelectric and energy storage properties of SnO2-doped Bi0.5(Na0.8K0.2)0.5TiO3 lead-free ceramics

2020 ◽  
Vol 10 (04) ◽  
pp. 2050011
Author(s):  
Nguyen Truong-Tho ◽  
Le Dai Vuong
Keyword(s):  
Dielectric Constant ◽  
Energy Storage ◽  
Sintering Temperature ◽  
High Energy ◽  
Lead Free ◽  
Energy Storage Properties ◽  
Energy Storage Efficiency ◽  
High Dielectric ◽  
Storage Properties ◽  
High Energy Storage

Sintered lead-free [Formula: see text]([Formula: see text][Formula: see text]([Formula: see text][Formula: see text]O3 ceramics (BNKTS) have been fabricated via a solid-state reaction. The effect of sintering temperature on the structural, morphological, dielectric, ferroelectric and energy storage properties of BNKTS ceramics was investigated, and it was found that the electrical properties of the synthesized ceramics increased with the increase in the sintering temperature, and the highest values were achieved at [Formula: see text]C. The ceramics sintered at the optimized temperature of [Formula: see text]C exhibited the best physical, dielectric, ferroelectric and energy storage properties, namely, high density (the relative density, [Formula: see text][Formula: see text]g.cm[Formula: see text], approximate to 96.7% of the theoretical value), high densification factor ([Formula: see text]), high dielectric constant ([Formula: see text]), low dielectric loss (tan[Formula: see text]), highest dielectric constant ([Formula: see text]), high remanent polarization ([Formula: see text]C.cm[Formula: see text], high coercive field ([Formula: see text][Formula: see text]kV/cm), high energy storage density (0.12[Formula: see text]J/cm[Formula: see text], and high energy storage efficiency (41.7% at 46.3[Formula: see text]kV/cm).

scholarly journals Colossal dielectric constant of NaNbO3 doped BaTiO3 ceramics

2016 ◽  
Vol 34 (2) ◽  
pp. 322-329 ◽  
Author(s):  
Wan Q. Cao ◽  
Ling F. Xu ◽  
Mukhlis M. Ismail ◽  
Li L. Huang
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
Traditional Approach ◽  
Temperature Stability ◽  
Bound State ◽  
High Energy ◽  
Low Dielectric ◽  
Giant Dielectric ◽  
Giant Dielectric Constant ◽  
High Dielectric

AbstractBaTiO3 ceramics doped with 0.40 mol% NaNbO3 were prepared using a traditional approach by sintering at temperature of 1250 °C to 1290 °C. The prepared ceramics was characterized by very good dielectric properties, such as high dielectric constant (1.5 × 105), low dielectric loss (0.1), and good dielectric temperature stability in the −40 °C to 100 °C range for the sample sintered below 1270 °C. The dielectric characteristics obtained with XPS confirmed that Ti4+ ions remain in the state without any change. The huge increase in dielectric constant in NaNbO3 doped BaTiO3 samples occurs when large amount of Ba2+ ions are excited to a high energy bound state of Ba2+ − e or Ba+ to create electron hopping conduction. For samples with the content of NaNbO3 higher than 0.40 mol%, or sintering temperature higher than 1280 °C, compensation effect is dominated by cation vacancies with sharply decreasing dielectric constant and increased dielectric loss. The polaron effect is used to explain the relevant mechanism of giant dielectric constant appearing in the ferroelectric phase.

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