Subduction-related subcontinental lithospheric mantle metasomatism and crustal thickening: origin for superchondritic Nb/Ta in mafic dykes

2020 ◽  
Vol 178 (1) ◽  
pp. jgs2020-120
Author(s):  
Xiang Cui ◽  
Wenbin Zhu ◽  
F. Jourdan
Keyword(s):  
Trace Element ◽  
South China ◽  
Lithospheric Mantle ◽  
Incompatible Trace Element ◽  
Mantle Metasomatism ◽  
Crustal Thickening ◽  
Subcontinental Lithospheric Mantle ◽  
Content Type ◽  
Mafic Dykes ◽  
Supplementary Material

Superchondritic Nb/Ta is rarely reported in terrestrial reservoirs and is usually attributed to carbonatite metasomatism or accessory rutile in the residue phase. Previously documented high Nb/Ta in rocks derived from subcontinental lithospheric mantle indicated a predominance of carbonatite metasomatism. This study evaluates Nb/Ta in conjunction with other trace elements of Neoproterozoic mafic dykes exposed in the eastern segment of the Jiangnan Orogen, where early subduction existed before the amalgamation of South China. These mafic dykes show mostly superchondritic Nb/Ta ratios from 19.6 to 24.5. Partial melting modelling suggested low-degree melting of rutile-bearing subcontinental lithospheric mantle for these mafic dykes. A literature review of Neoproterozoic mafic–intermediate rocks throughout the Jiangnan Orogen shows sporadically but coincidently superchondritic Nb/Ta near or beneath the Shuangxiwu arc, indicating rutile stability in the relict sub-arc mantle. Rutile in the lherzolite was formed sometime after Neoproterozoic subduction initiation in South China but contemporaneous with crustal thickening at c. 860 Ma. This study brings direct evidence to bear on the mechanism of rutile formation in the mantle wedge, as well as the link between crustal thickening and superchondritic Nb/Ta of mafic products derived from the metasomatized mantle.Supplementary material: Major and trace element compositions, photomicrographs of samples, and figures illustrating geochemistry, REE and incompatible trace element patterns and loss on ignition versus Nb/Ta and La/Yb are available at https://doi.org/10.6084/m9.figshare.c.5093535

scholarly journals Major-trace element and Sr-Nd isotope compositions of mafic dykes of the Singhbhum Craton: Insights into evolution of the lithospheric mantle

Lithos ◽  
2021 ◽  
Vol 382-383 ◽  
pp. 105959
Author(s):  
Om Prakash Pandey ◽  
Klaus Mezger ◽  
Dewashish Upadhyay ◽  
Debajyoti Paul ◽  
Ajay Kumar Singh ◽  
...  
Keyword(s):  
Trace Element ◽  
Lithospheric Mantle ◽  
Nd Isotope ◽  
Mafic Dykes ◽  
Singhbhum Craton

Diamondiferous lamproites of Ingashi field, Siberian craton

2021 ◽  
pp. SP513-2020-274
Author(s):  
S. I. Kostrovitsky ◽  
D. A. Yakovlev ◽  
I. S. Sharygin ◽  
D. P. Gladkochub ◽  
T. V. Donskaya ◽  
...  
Keyword(s):  
Trace Element ◽  
Siberian Craton ◽  
Major Elements ◽  
Primary Sources ◽  
Content Type ◽  
Link Type ◽  
Ultramafic Lamprophyre ◽  
Dating Methods ◽  
Supplementary Material

AbstractIngashi lamproite dykes are the only known primary sources of diamond in the Irkutsk district (Russia) and the only non-kimberlitic one in the Siberian craton. Ingashi lamproite field placed in Urik-Iya graben within Prisayan uplift of Siberian craton. Phlogopite-olivine lamproites contain olivine, talc, phlogopite, serpentine, chlorite, olivine, garnet, chromite, orthopyroxene, clinopyroxene as well as Sr-F-apatite, monazite, zircon, armolcolite, priderite, potassium Mg-arfvedsonite, Mn-ilmenite, Nb-rutile, and diamond. The only one ultramafic lamprophyre dyke is composed mainly of serpentinized olivine and phlogopite in the talc-carbonate groundmass and similar (to Ingashi lamproites) accessory assemblage with the same major elements compositions. Trace element and Sr-Nd isotopic relationships of the Ingashi lamproites are similar to classic lamproites. Different dating methods have provided the ages of lamproites: 1481 Ma (Ar-Ar phlogopite), 1268 Ma (Rb-Sr whole rock) and 300 Ma (U-Pb zircon). Ingashi lamproite ages are controversial and require additional study. Calculated pressure of 3.5 GPamax for clinopyroxenes indicating that lamproite magma originated deeper than 100 km. Cr-in-garnet barometer (Grutter et al., 2006) shows a 3.7-4.3 GPamin and derivation of Ingashi lamproites deeper than 120 km depth. Based on the range of typical cratonic geotherms and presence of diamonds, the Ingashi lamproite magma originated at a depth greater than 155 km.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5493128

Isotopic analyses of clinopyroxene in mantle xenoliths demonstrate the effects of kimberlite melt metasomatism upon the lithospheric mantle

2020 ◽  
Author(s):  
Angus Fitzpayne ◽  
Andrea Giuliani ◽  
Janet Hergt ◽  
Jon Woodhead ◽  
Roland Maas
Keyword(s):  
Trace Element ◽  
Lithospheric Mantle ◽  
Mantle Metasomatism ◽  
Mantle Xenoliths ◽  
Isotopic Compositions ◽  
Isotopic Analyses ◽  
Cretaceous Magmatism

<p>As clinopyroxene is the main host of most lithophile elements in the lithospheric mantle, the trace element and radiogenic isotope systematics of this mineral have frequently been used to characterise mantle metasomatic processes. To further our understanding of mantle metasomatism, both solution-mode Sr-Nd-Hf-Pb and in situ trace element and Sr isotopic data have been acquired for clinopyroxene grains from a suite of peridotite (lherzolites and wehrlites), MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside), and PIC (Phlogopite-Ilmenite-Clinopyroxene) rocks from the Kimberley kimberlites (South Africa). The studied mantle samples can be divided into two groups on the basis of their clinopyroxene trace element compositions, and this subdivision is reinforced by their isotopic ratios. Type 1 clinopyroxene, which comprises PIC, wehrlite, and some sheared lherzolite samples, is characterised by low Sr (~100–200 ppm) and LREE concentrations, moderate HFSE contents (e.g., ~40–75 ppm Zr; La/Zr < 0.04), and restricted isotopic compositions (e.g., <sup>87</sup>Sr/<sup>86</sup>Sr<sub>i</sub> = 0.70369–0.70383; εNd<sub>i</sub> = +3.1 to +3.6) resembling those of their host kimberlite magmas. Available trace element partition coefficients can be used to show that Type 1 clinopyroxenes are close to equilibrium with kimberlite melt compositions, supporting a genetic link between kimberlites and these metasomatised lithologies. Thermobarometric estimates for Type 1 samples indicate equilibration depths of 135–155 km within the lithosphere, thus showing that kimberlite melt metasomatism is prevalent in the deeper part of the lithosphere beneath Kimberley. In contrast, Type 2 clinopyroxenes occur in MARID rocks and coarse granular lherzolites, which derive from shallower depths (<130 km), and have higher Sr (~350–1000 ppm) and LREE contents, corresponding to higher La/Zr of >~0.05. The isotopic compositions of Type 2 clinopyroxenes are more variable and extend from compositions resembling the “enriched mantle” towards those of Type 1 rocks (e.g., εNd<sub>i</sub> = -12.7 to -4.4). To constrain the source of these variations, in situ Sr isotope analyses of clinopyroxene were undertaken, including zoned grains in Type 2 samples. MARID and lherzolite clinopyroxene cores display generally radiogenic but variable <sup>87</sup>Sr/<sup>86</sup>Sr<sub>i</sub> values (0.70526–0.71177), which might be explained by the interaction between peridotite and melts from different enriched sources with the lithospheric mantle. In contrast, the rims of these Type 2 clinopyroxenes trend towards compositions similar to those of the host kimberlite and Type 1 clinopyroxene from PIC and wehrlites. These results are interpreted to represent clinopyroxene overgrowth during late-stage (shortly before/during entrainment) metasomatism by kimberlite magmas. Our study shows that an early, pervasive, alkaline metasomatic event caused MARID and lherzolite genesis in the lithospheric mantle beneath the Kimberley area, which was followed by kimberlite metasomatism during Cretaceous magmatism. This latter event is the time at which discrete PIC, wehrlite, and sheared lherzolite lithologies were formed, and MARID and granular lherzolites were partly modified.</p>

scholarly journals The petrogenesis of tholeiitic diabases in eastern Parnaíba Basin: evidence for geochemical heterogeneities in the subcontinental lithospheric mantle in NE Brazil

2017 ◽  
Vol 47 (1) ◽  
pp. 109-126 ◽  
Author(s):  
Adriano Guilherme da Silva ◽  
Cícera Neysi de Almeida ◽  
Sérgio de Castro Valente ◽  
Leonardo Fonseca Borghi de Almeida
Keyword(s):  
Trace Element ◽  
Fractional Crystallization ◽  
Lithospheric Mantle ◽  
Sedimentary Basin ◽  
Sedimentary Rocks ◽  
Geochemical Modelling ◽  
Subcontinental Lithospheric Mantle ◽  
Tectonic Events ◽  
Tholeiitic Magmatism ◽  
Parnaíba Basin

ABSTRACT: The sedimentary rocks within the Paleozoic Parnaiba basin in NE Brazil were intruded by voluminous tholeiitic diabase sills and covered by coeval basaltic flows. This paper presents lithogeochemical data of borehole samples obtained from wells located in the eastern portion of the Parnaiba basin. The diabases are subalkaline tholeiitc rocks comprising three high-TiO2 and three low-TiO2 suites that are unrelated by differentiation processes. Fractional crystallization of olivine and augite was the predominantly evolutionary processes within individual high- and low-TiO2 suites as depicted by trace element geochemical modelling, exception being made for one low-TiO2 suite that evolved by AFC. Parental compositions for both low- and high-TiO2 suites are related with variably enriched, spinel harzburgitic sources likely to represent the heterogeneous subcontinental lithospheric mantle underneath the sedimentary basin. The geochemical provinciality of the Parnaiba tholeiitic magmatism seems unrelated with the Transbrasiliano Lineament but may be due to lithospheric mantle amalgamation and remobilization occurred during previous tectonic events.

Metasomatic Processes in the Lithospheric Mantle Beneath the No. 30 Kimberlite (Wafangdian Region, North China Craton)

2019 ◽  
Vol 57 (4) ◽  
pp. 499-517 ◽  
Author(s):  
Ren Z. Zhu ◽  
Pei Ni ◽  
Jun Y. Ding ◽  
Guo G. Wang ◽  
Ming S. Fan ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
North China Craton ◽  
Lithospheric Mantle ◽  
North China ◽  
Compositional Data ◽  
Early Stage ◽  
Mantle Metasomatism ◽  
Element Data

AbstractThis paper presents the first major and trace element compositions of mantle-derived garnet xenocrysts from the diamondiferous No. 30 kimberlite pipe in the Wafangdian region, and these are used to constrain the nature and evolution of mantle metasomatism beneath the North China Craton (NCC). The major element data were acquired using an electron probe micro-analyzer and the trace element data were obtained using laser ablation inductively coupled plasma-mass spectrometry. Based on Ni-in-garnet thermometry, equilibrium temperatures of 1107–1365 °C were estimated for peridotitic garnets xenocrysts from the No. 30 kimberlite, with an average temperature of 1258 °C, and pressures calculated to be between 5.0 and 7.4 GPa. In a CaO versus Cr2O3 diagram, 52% of the garnets fall in the lherzolite field and 28% in the harzburgite field; a few of the garnets are eclogitic. Based on rare earth element patterns, the lherzolitic garnets are further divided into three groups. The compositional variations in garnet xenocrysts reflect two stages of metasomatism: early carbonatite melt/fluid metasomatism and late kimberlite metasomatism. The carbonatite melt/fluids are effective at introducing Sr and the light rare earth elements, but ineffective at transporting much Zr, Ti, Y, or heavy rare earth elements. The kimberlite metasomatic agent is highly effective at element transport, introducing, e.g., Ti, Zr, Y, and the rare earth elements. Combined with compositional data for garnet inclusions in diamonds and megacrysts from the Mengyin and Wafangdian kimberlites, we suggest that these signatures reflect a two-stage evolution of the sub-continental lithospheric mantle (SCLM) beneath the NCC: (1) early-stage carbonatite melt/fluid metasomatism resulting in metasomatic modification of the SCLM and likely associated with diamond crystallization; (2) late-stage kimberlite metasomatism related to the eruption of the 465 Ma kimberlite.

Spatial and temporal influence of Pacific subduction on South China: geochemical migration of Cretaceous mafic–intermediate rocks

2020 ◽  
Vol 177 (5) ◽  
pp. 1013-1024
Author(s):  
Chengshi Gan ◽  
Yuejun Wang ◽  
Tiffany L. Barry ◽  
Yuzhi Zhang ◽  
Xin Qian
Keyword(s):  
South China ◽  
Igneous Rocks ◽  
Geochemical Data ◽  
Content Type ◽  
The Pacific ◽  
Group A ◽  
Temporal Influence ◽  
Pacific Slab ◽  
Supplementary Material ◽  
Group B

The Cretaceous igneous rocks in the South China Block (SCB) were associated with the slab subduction and roll-back of the Pacific Plate. Thus, they provide excellent opportunities to examine the spatial–temporal geochemical migration of magmatism in the retreating subduction margins. The Cretaceous mafic–intermediate igneous rocks from the southeastern SCB were aged between 142 and 71 Ma, and can geochemically be subdivided into three groups: Group A (126–129 Ma and 83–93 Ma), Group B (126–142 Ma and 71–108 Ma) and Group C (116–142 Ma and 70–110 Ma). Group A and B were mainly distributed in the SCB interior and derived from asthenosphere and asthenosphere–lithosphere interaction sources, respectively. Group C occurred to the east of the Ganjiang Fault and originated from slab–lithosphere interaction. From the coastal provinces to the interior, these mafic–intermediate igneous rocks show increasing incompatible element ratios and Nd isotopic compositions, reflective of a westerly decreasing involvement of slab-derived components. They show two similar age-pulses at c. 125 Ma and c. 90 Ma as well as the Cretaceous A-type granites, indicating two episodes of subduction retreat of the Pacific slab during the Cretaceous. This spatial–temporal pattern of the Cretaceous mafic–intermediate igneous rocks suggests that the Cretaceous slab metasomatism of Pacific subduction retreat was limited to the east of the Ganjiang Fault.Supplementary material: Tables of geochemical data and additional figures are available at https://doi.org/10.6084/m9.figshare.c.4938576

Terreneuvian bio- and chemostratigraphy of the South Sichuan Region (South China)

2021 ◽  
pp. jgs2020-167
Author(s):  
Ben Yang ◽  
Michael Steiner
Keyword(s):  
Carbon Isotope ◽  
South China ◽  
Cambrian Explosion ◽  
The South ◽  
Yangtze Craton ◽  
Content Type ◽  
Link Type ◽  
Small Shelly Fossils ◽  
Assemblage Zone ◽  
Supplementary Material

Classical sections, such as the Maidiping and Daqiao Mine sections of South Sichuan (China), expose early Cambrian deposits that are crucial for understanding the biological and environmental evolution of Yangtze Craton. These sequences are rich in Terreneuvian small shelly fossils, which can be assigned to assemblages I and III from South China. The Anabarites trisulcatus– Protohertzina anabarica Assemblage Zone (Assemblage I) is recognized at the lower Maidiping Formation. The second assemblage (Paragloborilus subglobosus – Purella squamulosa Assemblage Zone) cannot be verified in South Sichuan, although previous reports claimed its existence based on the occurrence of Paragloborilus subglobosus. The third assemblage (Watsonella crosbyi Assemblage Zone) is confirmed in the upper Maidiping Formation. The abundant bioclasts in this interval indicate abrasions and bioerosions by winnowing or starved sedimentation. Carbon isotope values from the Maidiping section present no negative excursion at the presumed Ediacaran–Cambrian transition. A positive carbon isotope excursion is observed in the upper Maidiping Formation (Assemblage III) which is correlated to the ZHUCE excursion in the Dahai Member of eastern Yunnan. The shallow water deposits of South Sichuan can be correlated with the South China, western Mongolia and Siberia successions based on biozonations and carbon isotope trends.Thematic collection: This article is part of the Advances in the Cambrian Explosion collection available at: https://www.lyellcollection.org/cc/advances-cambrian-explosionSupplementary material:https://doi.org/10.6084/m9.figshare.c.5326834

scholarly journals Volcanic spherules condensed from supercritical fluids in the Payenia volcanic province, Argentina

2020 ◽  
Vol 178 (1) ◽  
pp. jgs2020-026
Author(s):  
Linda A. Kirstein ◽  
Silvestar Kanev ◽  
J. Godfrey Fitton ◽  
Stephen J. Turner ◽  
Keyword(s):  
Trace Element ◽  
Secondary Ion Mass Spectrometry ◽  
Trace Element Content ◽  
Volcanic Eruptions ◽  
Content Type ◽  
Lightning Strikes ◽  
Meteorite Impacts ◽  
High Temperature Processes ◽  
Supplementary Material ◽  
Sedimentary Carbonates

Spherules can be formed by high-temperature processes during volcanic eruptions, lightning strikes and meteorite impacts. Here we report four different types of spherules and spheroidal particles associated with tephra deposits from two separate volcanic fields in the southern Payenia province of Argentina. These silicate and carbonate spherules represent <0.01% of the sampled material, with individual spherules <200 µm in size. Thirty particles were imaged. Only the transparent spherules are smooth, perfect spheres; other morphologies include ellipsoids and aggregated dumbbells. The spheroids are either hollow or solid. Major element analyses show that the spherules and spheroids have silica-rich, Fe-rich, carbonate and basaltic compositions. Chemical analysis of the carbonate spheroids shows some variability in the trace element content between the cores and rims, suggesting element mobility and loss towards the margins. All the analysed carbonate spheroids have elevated Sr/Y, La/Y and La/Ce ratios outside the range for sedimentary carbonates. All four spherule types are considered to be volcanic in origin, with the excess CO2 required for the formation of the carbonate spherules potentially sourced from the basement lithologies. Based on the major and trace element analyses, we conclude that the silica-rich and carbonate spherules formed by instantaneous condensation from supercritical CO2-rich hydrous fluids saturated with dissolved silicates.Supplementary material: Appendix A, containing the full analytical dataset collected by electron probe microanalysis and secondary ion mass spectrometry, is available at https://doi.org/10.6084/m9.figshare.c.5108689

Kimberlites as Geochemical Probes of Earth’s Mantle

Elements ◽  
2019 ◽  
Vol 15 (6) ◽  
pp. 387-392 ◽  
Author(s):  
D. Graham Pearson ◽  
Jon Woodhead ◽  
Philip E. Janney
Keyword(s):  
Trace Element ◽  
Transition Zone ◽  
Lithospheric Mantle ◽  
Crustal Contamination ◽  
Incompatible Trace Element ◽  
Magma Source ◽  
Core Mantle Boundary ◽  
The Core ◽  
Earth’S Mantle ◽  
Source Regions

Kimberlites are ultrabasic, Si-undersaturated, low Al, low Na rocks rich in CO2 and H2O. The distinctive geochemical character of kimberlite is strongly influenced by the nature of the local underlying lithospheric mantle. Despite this, incompatible trace element ratios and radiogenic isotope characteristics of kimberlites, filtered for the effects of crustal contamination and alteration, closely resemble rocks derived from the deeper, more primitive, convecting mantle. This suggests that the ultimate magma source is sub-lithospheric. Although the composition of primitive kimberlite melt remains unresolved, kimberlites are likely derived from the convecting mantle, with possible source regions ranging from just below the lithosphere, through the transition zone, to the core–mantle boundary.

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