scholarly journals Electrochemical Behaviors of Iron-Based Electrode Materials in Li2SO4 Aqueous Electrolyte

2017 ◽  
Vol 4 (10) ◽  
pp. 1642-1648 ◽  
Author(s):  
Wei Jiang ◽  
Fang Hu ◽  
Qingyu Yan ◽  
Xiang Wu

The electrochemical performance of the as-synthesized mesoporous NiCo2O4 flower-like products as electrode materials for battery-type supercapacitors is systematically investigated in detail.


2018 ◽  
Vol 34 (6) ◽  
pp. 3058-3063 ◽  
Author(s):  
R. Suresh ◽  
K. Tamilarasan ◽  
D. Senthil Vadivu

Progress in material science has unearthed a number of options that offer great advantages for nanostructured electrode materials which enable supercapacitors to operate efficiently. Present work involves fabrication of symmetric and asymmetric type supercapacitor devices utilizing Mn-CuO nanostructures and activated carbon (AC) as electrode materials and subsequent investigation on their supercapacitive performance in 2M KOH aqueous electrolyte. The asymmetric supercapacitor device (Mn-CuO // 2M KOH// AC) demonstrate a specific capacitance of 72 Fg-1 at a current density of 0.5 Ag-1. The cyclic stability test of this device performed at a current density of 10 Ag-1 reveals a capacitance retention of 71% of its initial value over 300 charge-discharge cycles. In addition, this device exhibits an energy density of 7.4 Whkg-1 and a power density of 127 Wkg-1.


2012 ◽  
Vol 27 (2) ◽  
pp. 481-485 ◽  
Author(s):  
Britta Andres ◽  
Sven Forsberg ◽  
Ana Paola Vilches ◽  
Renyun Zhang ◽  
Magnus Hummelgård ◽  
...  

Abstract Paper based supercapacitors are prepared by stacking a paper between two graphene electrodes and soaking these in an aqueous electrolyte. We demonstrate that supercapacitors can easily be manufactured by using proven paper technologies. Several different electrode materials were compared and two types of contacting material, silver and graphite foil were tested. The influence of the paper used as separator was also investigated. The supercapacitors with a graphene-gold nanoparticle composite as electrodes showed a specific capacitance of up to 100 F/g and an energy density of 1.27 Wh/kg. The energy density can further be increased by using other electrolytes. The silver contacts showed a pseudo capacitance, which the graphite contacts did not. The papers tested had a minor effect on the capacitance, but they have an influence on the weight and the volume of the supercapacitor.


RSC Advances ◽  
2015 ◽  
Vol 5 (86) ◽  
pp. 70297-70301 ◽  
Author(s):  
Yong Zhang ◽  
Youfu Wang ◽  
Aiguo Hu

Hierarchically porous carbon nanofoams were prepared via the formation of core–shell organosilica nanoparticles and subsequent Friedel–Crafts chemistry. The specific capacitance of them as electrode materials reached 170 F g−1 in an aqueous electrolyte.


2020 ◽  
Vol 20 (6) ◽  
pp. 3785-3794 ◽  
Author(s):  
Manohar D. Mehare ◽  
Abhay D. Deshmukh ◽  
S. J. Dhoble

A sucrose derived carbon quantum dots/polyaniline (S-CQD/PANI) nanocomposite was synthesized as electrode materials by electrodeposition method to achieve excellent electrocapacitive performance for supercapacitor application. The morphology reveals that CQD were distributed uniformly over the surface of PANI. The highest specific capacitance obtained to be 1512.4 Fg−1 at current density 1 Ag−1 for S-CQD/PANI-25 composite in three electrode system with 1 M H2SO4 aqueous electrolyte within the potential range of −0.2 to 0.8 V. In addition asymmetric supercapacitor device was fabricated reveals highest specific capacitance of 295 Fg−1 at 1 Ag−1 with excellent stability over 1000 cycle at 3 Ag−1. Remarkably, the device delivers energy density of 40.86 Whkg−1 at power density 2000 Wkg−1.


2016 ◽  
Vol 4 (12) ◽  
pp. 4497-4505 ◽  
Author(s):  
Xiao-Xiao Lin ◽  
Bin Tan ◽  
Lu Peng ◽  
Zhao-Feng Wu ◽  
Zai-Lai Xie

In the present work, a series of hierarchical porous carbon monoliths were prepared from fructoseviaa one-step ionothermal carbonization approach using an iron-based ionic liquid as solvent, and a porogenic agent.


2011 ◽  
Vol 239-242 ◽  
pp. 2573-2577
Author(s):  
Guan Gui Yi ◽  
Ying Liang Liu ◽  
Yong Xiao ◽  
Wen Qi He ◽  
Shuai Zhao

Nitrogen-doped mesoporous carbons (NMC) were prepared through a facile procedure using surfactants (polyvinylpyrrolidone) as a nitrogen-containing carbon source. The NMC samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and nitrogen sorption at 77 K. Cyclic voltammetry and galvanostatic charge/discharge experiments were adopted to investigate their electrochemical behaviors. The NMC-5 sample contain abundant mesopores shows the large specific capacitance up to 276 F g−1at the current of density of 0.1 A g-1. We suggest that the nitrogen-doped mesoporous carbon has potential application as electrochemical capacitor electrode materials.


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