A High Capacity, Room Temperature Hybrid Flow Battery Consisted of Liquid Na-Cs Anode and Aqueous NaI Catholyte

Batteries ◽  
2018 ◽  
Vol 4 (4) ◽  
pp. 60 ◽  
Author(s):  
Caihong Liu ◽  
Leon Shaw

In this study, we have proposed a novel concept of hybrid flow batteries consisting of a molten Na-Cs anode and an aqueous NaI catholyte separated by a NaSICON membrane. A number of carbonaceous electrodes are studied using cyclic voltammetry (CV) for their potentials as the positive electrode of the aqueous NaI catholyte. The charge transfer impedance, interfacial impedance and NaSICON membrane impedance of the Na-Cs ‖ NaI hybrid flow battery are analyzed using electrochemical impedance spectroscopy. The performance of the Na-Cs ‖ NaI hybrid flow battery is evaluated through galvanostatic charge/discharge cycles. This study demonstrates, for the first time, the feasibility of the Na-Cs ‖ NaI hybrid flow battery and shows that the Na-Cs ‖ NaI hybrid flow battery has the potential to achieve the following properties simultaneously: (i) An aqueous NaI catholyte with good cycle stability, (ii) a durable and low impedance NaSICON membrane for a large number of cycles, (iii) stable interfaces at both anode/membrane and cathode/membrane interfaces, (iv) a molten Na-Cs anode capable of repeated Na plating and stripping, and (v) a flow battery with high Coulombic efficiency, high voltaic efficiency, and high energy efficiency.


2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Jinchao Tong ◽  
Fei Suo ◽  
Tianning Zhang ◽  
Zhiming Huang ◽  
Junhao Chu ◽  
...  

AbstractHigh-performance uncooled millimetre and terahertz wave detectors are required as a building block for a wide range of applications. The state-of-the-art technologies, however, are plagued by low sensitivity, narrow spectral bandwidth, and complicated architecture. Here, we report semiconductor surface plasmon enhanced high-performance broadband millimetre and terahertz wave detectors which are based on nanogroove InSb array epitaxially grown on GaAs substrate for room temperature operation. By making a nanogroove array in the grown InSb layer, strong millimetre and terahertz wave surface plasmon polaritons can be generated at the InSb–air interfaces, which results in significant improvement in detecting performance. A noise equivalent power (NEP) of 2.2 × 10−14 W Hz−1/2 or a detectivity (D*) of 2.7 × 1012 cm Hz1/2 W−1 at 1.75 mm (0.171 THz) is achieved at room temperature. By lowering the temperature to the thermoelectric cooling available 200 K, the corresponding NEP and D* of the nanogroove device can be improved to 3.8 × 10−15 W Hz−1/2 and 1.6 × 1013 cm Hz1/2 W−1, respectively. In addition, such a single device can perform broad spectral band detection from 0.9 mm (0.330 THz) to 9.4 mm (0.032 THz). Fast responses of 3.5 µs and 780 ns are achieved at room temperature and 200 K, respectively. Such high-performance millimetre and terahertz wave photodetectors are useful for wide applications such as high capacity communications, walk-through security, biological diagnosis, spectroscopy, and remote sensing. In addition, the integration of plasmonic semiconductor nanostructures paves a way for realizing high performance and multifunctional long-wavelength optoelectrical devices.


RSC Advances ◽  
2014 ◽  
Vol 4 (81) ◽  
pp. 42764-42771 ◽  
Author(s):  
Yana Liu ◽  
Jinxin Zou ◽  
Xiaoqin Zeng ◽  
Wenjiang Ding

A Mg–Ti nano-composite was co-precipitated through an adapted Rieke method, which exhibits high capacity and superior absorption kinetics at room temperature (∼6.2 wt% within 2 h).


2022 ◽  
Vol 522 ◽  
pp. 230995
Author(s):  
Mingjun Nan ◽  
Lin Qiao ◽  
Yuqin Liu ◽  
Huamin Zhang ◽  
Xiangkun Ma

2018 ◽  
Vol 378 ◽  
pp. 353-361 ◽  
Author(s):  
Eric Allcorn ◽  
Ganesan Nagasubramanian ◽  
Harry D. Pratt ◽  
Erik Spoerke ◽  
David Ingersoll

2019 ◽  
Vol 9 (16) ◽  
pp. 1803865 ◽  
Author(s):  
Nanzhong Wu ◽  
Wenjiao Yao ◽  
Xiaohe Song ◽  
Ge Zhang ◽  
Bingjie Chen ◽  
...  

2020 ◽  
Vol 3 (1) ◽  
pp. 6 ◽  
Author(s):  
André Oliveira Sawakuchi ◽  
Fernanda Costa Gonçalves Rodrigues ◽  
Thays Desiree Mineli ◽  
Vinícius Ribau Mendes ◽  
Dayane Batista Melo ◽  
...  

Finding the source or provenance of quartz grains occurring in a specific location allows us to constrain their transport pathway, which is crucial information to solve diverse problems in geosciences and related fields. The optically stimulated luminescence (OSL) sensitivity (light intensity per unit mass per unit radiation dose) has a high capacity for discrimination of quartz sediment grains and represents a promising technique for provenance analysis. In this study, we tested the use of quartz OSL sensitivity (ultraviolet emission) measured under different preheating temperatures and with blue light stimulation at room temperature (~20 °C) for sediment provenance analysis. Quartz OSL sensitivity measured at 20 °C is positively correlated with the sensitivity of an OSL signal measured using procedures (preheat at 190 °C for 10 s, blue stimulation at 125 °C and initial 1 s of light emission) to increase the contribution of the fast OSL component, which has been successfully applied for sediment provenance analysis. The higher OSL signal intensity measured without preheating and with light stimulation at room temperature allows the use of lower given doses, thus reducing measurement time. Additionally, the OSL sensitivity measured at 20 °C in polymineral silt samples of a marine sediment core is also suitable for provenance analysis, as demonstrated by comparison with other independent proxies. OSL signals obtained through light stimulation at room temperature have thus the potential to considerably expand measurement possibilities, including in situ measurements using portable OSL readers.


2015 ◽  
Vol 8 (8) ◽  
pp. 2504-2511 ◽  
Author(s):  
Bin Li ◽  
Hui-Min Wen ◽  
Hailong Wang ◽  
Hui Wu ◽  
Taner Yildirim ◽  
...  

Incorporation of functional groups with Lewis basic nitrogen sites, including pyridine, pyridazine and pyrimidine groups, into NOTT-101 can remarkably improve both the total volumetric methane storage (at 65 bar and room temperature) and working capacities.


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