Measurement of Long Range Order in the γ’ Phase of Nickel-Base Superalloys

1969 ◽  
Vol 13 ◽  
pp. 598-608
Author(s):  
J.R. Mihalisin

The long range order parameter (S) has been measured at room- temperature on the γ’ phase extracted from IN-731 and alloys 713C and 713LC by x-ray diffraction techniques. Measurements were obtained from specimens of IN-731 and alloy 713LC in the as-cast condition and after long time rupture testing. The alloy 713 c specimens were in the as-cast and high temperature heat treated conditions.It was found that long range order in the γ’ phase of IN-731 and alloy 713LC was changed very little after long time rupture testing, and after high temperature heat treatment in the case of alloy 713C.

1970 ◽  
Vol 48 (13) ◽  
pp. 1566-1577 ◽  
Author(s):  
D. D. Betts ◽  
C. J. Elliott ◽  
M. H. Lee

A method is developed for the exact high temperature series expansion of thermodynamic properties of the spin 1/2 XY model of ferromagnetism or of a quantum lattice gas. Eleven coefficients in the specific heat series for the f.c.c. and b.c.c. lattices and nine coefficients in the series for the fluctuation in the long range order for the f.c.c., b.c.c., and s.c. lattices are calculated. From the fluctuation series the critical temperatures Kc−1 ≡ kTc/J are estimated to be 4.520, 2.902, and 2.02 respectively, while the critical index for the square of the fluctuation in the long range order is γ = 1.35.


1982 ◽  
Vol 37 (11) ◽  
pp. 1361-1368 ◽  
Author(s):  
H.-J. Schweizer ◽  
Reginald Gruehn

By using chemical transport reactions with various transporting agents (HgCl2, NbCl5, Nb3O7Cl) a slightly substoiehiometric NbO2-phase, β-NbO2, was obtained from samples with O/Nb ∼ 1.5 (source; T > 1373 K) and with deposition temperatures > 1273 K (sink). The rango of composition of β-NbO2 was found to exist from NbO1.990 to NbO1.998.The structure of the tetragonal, column-shaped black crystals was determined by X-ray diffraction. It crystallizes tetragonally in the space group I41 with lattice constants a = 9.693(3) Å, c = 5.985(1) Å and Z = 10 formula units.The crystal structure of β-NbO2 is shown to be a deformed rutile type. As in α-NbO2 the Nb-atoms are grouped in pairs. However, both oxides are different with respect to their long-range order.


1999 ◽  
Vol 14 (1) ◽  
pp. 16-23 ◽  
Author(s):  
G. Behr ◽  
W. Löser ◽  
G. Graw ◽  
K. Nenkov ◽  
U. Krämer ◽  
...  

The influence of composition and high-temperature heat treatment on phase content and superconducting properties of the Yni2B2C phase was investigated. Phase relations in those parts of the Y–Ni–B–C quaternary phase diagram, which are relevant for the YNi2B2C intermetallic phase formation, were revealed by x-ray diffraction, optical and scanning electron microscopy, and high-temperature differential thermoanalysis. A widespread interval of superconducting transition temperatures TC = 10.4–15.2 K and small transition width <0.3 K were determined from samples of different nominal compositions after high-temperature annealing. The different intrinsic properties are ascribed to composition variations of the YNi2B2C phase and related to structure parameters, residual resistance ratios, and element concentrations determined by the electron probe microanalysis.


2012 ◽  
Vol 86 (2) ◽  
Author(s):  
M. Maret ◽  
C. Brombacher ◽  
P. Matthes ◽  
D. Makarov ◽  
N. Boudet ◽  
...  

2011 ◽  
Vol 399-401 ◽  
pp. 908-911
Author(s):  
Yu Yang Huang ◽  
Li Yuan Qin ◽  
Qin Guan Tian ◽  
Yu Xia Li ◽  
Wen Deng

The positron annihilation techniques and Mössbauer spectroscopy have been used to study the signals of 3d electrons and the hyperfine interactions in ordered and disorder Fe50Al50alloys. The results show that the signals of 3d electrons of ordered Fe50Al50alloy is very low. Mössbauer spectrum of ordered Fe50Al50alloy shows a singlet, this alloy is paramagnetic. However, Mössbauer spectrum of Fe50Al50powder being ball-milled for 70 h shows a discrete sextet, indicating a decrease in the long-range order within the Fe50Al50powder being ball-milled for a long time.


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