scholarly journals Molecular Resonances Observed in the Predissociation of Cs2

1995 ◽  
Vol 16 (1) ◽  
pp. 19-29 ◽  
Author(s):  
Bongsoo Kim ◽  
Keitaro Yoshihara
Keyword(s):  
Molecular Beam ◽  
Shape Parameter ◽  
Supersonic Jet ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Line Shapes ◽  
Sign Change ◽  
Source State ◽  
Molecular Resonances ◽  
Line Shape Parameter

Very cold molecular beam of Cs2 is generated by a high temperature supersonic jet source. State-specific photofragment yield spectrum is obtained in the orange band of Cs2. Asymmetric line shapes are observed. The Fano line shape parameter, q, shows a gradual sign change, which is called “q-reversal”. A very broad absorption band which has about 50 cm-1 width is observed and explained to occur through the perturbation by the D1∑u+ state. The complex resonance line shapes are attributed to the interfering resonances.

Accuracy of measurements of the band maximum shift for a broad absorption band

1973 ◽  
Vol 19 (5) ◽  
pp. 1538-1538
Author(s):  
A. I. Sidorova ◽  
T. V. Sukhanova ◽  
E. M. Ushakova
Keyword(s):  
Absorption Band ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Band Maximum ◽  
Accuracy Of Measurements

scholarly journals Dyson line and modified Dyson line in the EPR measurements

Nukleonika ◽  
2015 ◽  
Vol 60 (3) ◽  
pp. 385-388 ◽  
Author(s):  
Volodymyr Popovych ◽  
Mariusz Bester ◽  
Ireneusz Stefaniuk ◽  
Marian Kuzma
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Line Shape ◽  
Resonance Line ◽  
Shape Parameter ◽  
Resonance Field ◽  
Ferromagnetic Semiconductors ◽  
Paramagnetic Resonance ◽  
The Right ◽  
Electron Paramagnetic ◽  
Line Shape Parameter

Abstract The difficulty in determining the electron paramagnetic resonance (EPR) line parameters of ferromagnetic semiconductors has been addressed. For these materials, the resonance line is very broad and lies at low resonance field, so that only a part of the line can be detected experimentally. Moreover, the line is of asymmetric (Dysonian) shape as described by the line shape parameter α. We have compared values of line parameters derived by computer fitting of the whole experimental EPR line to the Dyson function (or modified Dyson function) with the values obtained by applying this procedure to the left and the right half of the line.

Influence of Eu2+ Doped Contents on the Spectroscopic Features of Sr2-X MgSi2O7:xEu2+

2012 ◽  
Vol 476-478 ◽  
pp. 1232-1236
Author(s):  
Jia Zhe Guo ◽  
Ya Dong Li ◽  
Yan Lin Huang
Keyword(s):  
Emission Spectra ◽  
Optical Excitation ◽  
Solid State Reaction Method ◽  
X Ray Diffraction ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Phase Purity ◽  
Reaction Method ◽  
X Ray ◽  
Uv Led

Silicate-based Sr2-xMgSi2O7:xEu2+(x=0.01, 0.03, 0.05, 0.07) phosphors were synthesized by the high temperature solid-state reaction method. Phase purity and crystal structure of the phosphors were characterized using X-ray diffraction spectrometer. The optical excitation and emission spectra of Eu2+ ion were measured using luminescence spectrometer and fluorescence spectrophotometer. The emission spectra showed a strong blue luminescence peaked around 470 nm, corresponds to the 4f65d1 →4f7 transition on Eu2+. Two different average decay time confirmed that the Eu2+ cations may occupy in two different lattice sites and presents different spectroscopic features. With a broad absorption band extending from 224 to 450 nm, it is suggestive that the phosphors have a potential application in UV-LED chips (360-400 nm).

Spectroscopic Line Shapes of Vibrational Quanta in the Presence of Molecular Resonances

2016 ◽  
Vol 7 (13) ◽  
pp. 2388-2393 ◽  
Author(s):  
Stefan Meierott ◽  
Nicolas Néel ◽  
Jörg Kröger
Keyword(s):  
Line Shapes ◽  
Molecular Resonances

Broad absorption band solar selective absorber analyzed by admittance loci

2016 ◽  
Author(s):  
Wei-Bo Liao ◽  
Ya-Chen Chang ◽  
Cheng-Chung Lee ◽  
Yu-Sheng Chen ◽  
Chien-Cheng Kuo
Keyword(s):  
Absorption Band ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Admittance Loci

Optical and Scintillation Properties of Eu-Doped Calcium Orthoborate

2012 ◽  
Vol 508 ◽  
pp. 235-239 ◽  
Author(s):  
Yutaka Fujimoto ◽  
Yoshisuke Futami ◽  
Takayuki Yanagida ◽  
Shunsuke Kurosawa ◽  
N. Kawaguchi ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Absorption Band ◽  
Radio Frequency ◽  
Single Crystals ◽  
Heating System ◽  
Radio Frequency Heating ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Decay Times ◽  
Frequency Heating

Single Crystals of Eu-Doped Calcium Orthoborate Have Been Grown by Micro-Pulling (μ-PD) Technique with Radio Frequency Heating System, and its Transmittance, Photoluminescence and Radiation Responses Were Investigated. In Transmittance Spectra, Eu-Doped Crystal Showed Broad Absorption Band around 200-450 nm, which Is due to the Complex of Charge Transfer (CT) Transition and 4f-4f Transition of Eu3+. Intense Eu2+5f-4f and Eu3+4f-4f Emission Peaks Were Observed when Excited to 265 nm and 385 nm, and the Calculated Decay Times Were 230 ns and 1.5 ms, Respectively.241Am 5.5 Mev α-Ray Excited Radioluminescence Spectra Indicated both Eu2+5f-4f and EuSuperscript text3+ 4f-4f Emission Peaks.

Study of Crystal Yb3+:Ca3Y2(BO3)4

2004 ◽  
Vol 19 (4) ◽  
pp. 1203-1207 ◽  
Author(s):  
Yan Wang ◽  
Chaoyang Tu ◽  
Changcang Huang ◽  
Zhenyu You
Keyword(s):  
Absorption Spectrum ◽  
Absorption Band ◽  
Emission Spectra ◽  
Czochralski Method ◽  
X Ray Diffraction ◽  
Broad Absorption ◽  
Broad Absorption Band ◽  
Orthorhombic System ◽  
X Ray ◽  
Broad Emission

Yb3+-doped single-crystal Ca3Y2(BO3)4 with dimension φ20 × 55 mm was grown by the Czochralski method. The structure of it was determined by x-ray diffraction. It belongs to the orthorhombic system, space group Pnma, with the following parameters: a= 7.1690(4), b = 15.4758(8), c = 8.5587(6) Å, V = 949.55(10)Å3, Mr = 537.51, Z = 2, Dc = 3.8 g/cm3, (MoKa) = 0.71073 Å, F(000) = 508, μ = 6.927 mm-1, final R = 0.0670, and wR = 0.1542 for 2975 independent reflections. The structure of Yb:Ca3Y2(BO3)4 is made up of three set of M-oxygen distorted polyhedrons, and three set of BO3 planar triangles. Ca2+ and Y3+ ions occupy three M sites statistically. Yb3+ ions substitute Y3+ ions to enter these three lattices. The adsorption and emission spectra were measured. It exhibits a broad absorption band ranging from 850 to 1000 nm in the absorption spectrum, which is well matched with the emission wavelength of a laser diode. A broad emission spectrum ranging from 927.95 to 1102.7 nm was observed under the excitation of 895 nm.

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