scholarly journals Visible-Light Photodegradation of Dye on Co-Doped Titania Nanotubes Prepared by Hydrothermal Synthesis

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Jung-Pin Wang ◽  
Hsi-Chi Yang ◽  
Chien-Te Hsieh

Highly porous Co-doped TiO2nanotubes synthesized from a hydrothermal treatment were used to photodecompose methylene blue (MB) in liquid phase under visible light irradiation. The anatase-type titania nanotubes were found to have high specific surface areas of about 289–379 m2/g. These tubes were shown to be hollow scrolls with outer diameter of about 10–15 nm and length of several micrometers. UV absorption confirmed that Co doping makes the light absorption of nanotubes shift to visible light region. With increasing the dopant concentration, the optical band gap of nanotubes became narrower, ranging from 2.4 eV to 1.8 eV, determined by Kubelka-Munk plot. The Co-doped nanotubes exhibit not only liquid-phase adsorption ability, but also visible-light-derived photodegradation of MB in aqueous solution. The synergetic effect involves two key factors in affecting the photocatalytic activity of Co-doped titania nanotubes under fluorescent lamp, that is, high porosity and optical band gap. The merit of the present work is to provide an efficient route for preparing Co-doped TiO2nanotubes and to clarifying their adsorption and photocatalytic activity under fluorescent lamp.

2017 ◽  
Vol 19 (36) ◽  
pp. 24915-24927 ◽  
Author(s):  
A. H. Reshak

The amalgamation of a wide optical band gap photocatalyst with visible-light-active CdO quantum dots (QDs) as sensitizers is one of the most efficient ways to improve photocatalytic performance under visible light irradiation.


2014 ◽  
Vol 6 (7) ◽  
pp. 4622-4629 ◽  
Author(s):  
Peng Zhang ◽  
Yanlong Yu ◽  
Enjun Wang ◽  
Jingsheng Wang ◽  
Jianghong Yao ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 8651-8660 ◽  
Author(s):  
Sachin Kumar ◽  
Animesh K. Ojha

The recombination rate of photo-induced electrons and holes for Ni–Co codoped CeO2 nanostructures is reduced significantly, which essentially improve the photocatalytic activity for photo-degradation of MB dye.


2020 ◽  
Vol 49 (22) ◽  
pp. 7451-7458
Author(s):  
Rui Feng ◽  
Rong Wu ◽  
Yuncheng Cao ◽  
Xiaolin Guo ◽  
Xu Ma

Amorphous co-doped MoSex enhances photocatalytic activity. There are three types of unsaturated Se–Se bonds in Co-MoSex: bridging Se–Se, shared Se–Se and terminal Se–Se. The band gap of Co-MoSex was reduced and the light response range was expanded.


2019 ◽  
Vol 18 (03n04) ◽  
pp. 1940043 ◽  
Author(s):  
O. Linnik ◽  
L. Khoroshko

Nitrogen and ruthenium co-doped titania films synthesized by sol–gel technique exhibit high photocatalytic activity under both UV and visible light. Incorporation of nitrogen and ruthenium ions in titania lattice is proven by XPS. Both doping agents affected the structural properties of the films.


Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3874 ◽  
Author(s):  
Abderrahim El Mragui ◽  
Yuliya Logvina ◽  
Luís Pinto da Silva ◽  
Omar Zegaoui ◽  
Joaquim C.G. Esteves da Silva

Pure TiO2 and Fe- and Co-doped TiO2 nanoparticles (NPs) as photocatalysts were synthesized using wet chemical methods (sol-gel + precipitation). Their crystalline structure and optical properties were analyzed using X-ray diffraction (XRD), Raman spectroscopy and Fourier-transform infrared (FTIR) spectroscopy, ultraviolet-visible light (UV-Vis) diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. The photocatalytic activity of the synthesized nanoparticles was evaluated through degradation of carbamazepine (CBZ) under UV-A and visible-light irradiations. The XRD and Raman analyses revealed that all synthesized nanomaterials showed only the anatase phase. The DRS results showed that the absorption edge was blue-shifted for Fe-doped TiO2 NPs. The decrease in charge recombination was evidenced from the PL investigation for both Co-doped and Fe-doped TiO2 nanomaterials. An enhancement in photocatalytic degradation of carbamazepine in aqueous suspension under both UV-A light and visible-light irradiations was observed for Fe-doped Titania NPs by comparison with pure TiO2. These results suggest that the doping cations could suppress the electron/hole recombination. Therefore, the photocatalytic activity of TiO2-based nanomaterials was enhanced.


RSC Advances ◽  
2017 ◽  
Vol 7 (27) ◽  
pp. 16282-16289 ◽  
Author(s):  
Chao Zhang ◽  
Nan Jiang ◽  
Shiai Xu ◽  
Zheng Li ◽  
Xingliang Liu ◽  
...  

The band structure and photocatalytic activity of RE (La, Ce, Pr or Nd) mono-doped and RE–N co-doped SrTiO3 for band gap reduction are studied systematically using first principles calculations.


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