scholarly journals Synchrotron-Radiation X-Ray Investigation of Li+/Na+Intercalation into Prussian Blue Analogues

2013 ◽  
Vol 2013 ◽  
pp. 1-17 ◽  
Author(s):  
Yutaka Moritomo ◽  
Masamitsu Takachi ◽  
Yutaro Kurihara ◽  
Tomoyuki Matsuda
Keyword(s):  
Synchrotron Radiation ◽  
Prussian Blue ◽  
Cathode Materials ◽  
Structural Investigation ◽  
Lithium Ion ◽  
X Ray ◽  
Prussian Blue Analogues ◽  
The Stability ◽  
X Ray Absorption ◽  
Discharge Curves

Prussian blue analogies (PBAs) are promising cathode materials for lithium ion (LIB) and sodium ion (SIB) secondary batteries, reflecting their covalent and nanoporous host structure. With use of synchrotron-radiation (SR) X-ray source, we investigated the structural and electronic responses of the host framework of PBAs against Li+and Na+intercalation by means of the X-ray powder diffraction (XRD) and X-ray absorption spectroscopy (XAS). The structural investigation reveals a robust nature of the host framework against Li+and Na+intercalation, which is advantageous for the stability and lifetime of the batteries. The spectroscopic investigation identifies the redox processes in respective plateaus in the discharge curves. We further compare these characteristics with those of the conventional cathode materials, such as, LiCoO2, LiFePO4, and LiMn2O4.

scholarly journals Metal-to-ligand and ligand-to-metal charge transfer in thin films of Prussian blue analogues investigated by X-ray absorption spectroscopy

2008 ◽  
Vol 10 (38) ◽  
pp. 5882 ◽  
Author(s):  
Sébastien Bonhommeau ◽  
Niko Pontius ◽  
Saioa Cobo ◽  
Lionel Salmon ◽  
Frank M. F. de Groot ◽  
...  
Keyword(s):  
Thin Films ◽  
Charge Transfer ◽  
Prussian Blue ◽  
Absorption Spectroscopy ◽  
Metal Charge ◽  
X Ray ◽  
Prussian Blue Analogues ◽  
X Ray Absorption ◽  
Metal Charge Transfer

Photoinduced Ferrimagnetic Systems in Prussian Blue Analogues CIxCo4[Fe(CN)6]y(CI= Alkali Cation). 2. X-ray Absorption Spectroscopy of the Metastable State

2000 ◽  
Vol 122 (28) ◽  
pp. 6653-6658 ◽  
Author(s):  
Christophe Cartier dit Moulin ◽  
Françoise Villain ◽  
Anne Bleuzen ◽  
Marie-Anne Arrio ◽  
Philippe Sainctavit ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Absorption Spectroscopy ◽  
Metastable State ◽  
Alkali Cation ◽  
X Ray ◽  
Prussian Blue Analogues ◽  
X Ray Absorption

Formation of SEI on Cycled Lithium-Ion Battery Cathodes: Soft X-Ray Absorption Study

2002 ◽  
Vol 5 (1) ◽  
pp. A22 ◽  
Author(s):  
M. Balasubramanian ◽  
H. S. Lee ◽  
X. Sun ◽  
X. Q. Yang ◽  
A. R. Moodenbaugh ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Absorption Study ◽  
X Ray ◽  
X Ray Absorption
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