scholarly journals Donor-π-Conjugated Spacer-Acceptor Dye-Sensitized Solid-State Solar Cell Using CuI as the Hole Collector

2019 ◽  
Vol 2019 ◽  
pp. 1-5
Author(s):  
D. N. Liyanage ◽  
K. D. M. S. P. K. Kumarasinghe ◽  
G. R. A. Kumara ◽  
A. C. A. Jayasundera ◽  
K. Tennakone ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Solid State ◽  
Short Circuit ◽  
Electrical Power ◽  
Short Circuit Current ◽  
Liquid Electrolyte ◽  
Short Circuit Current Density ◽  
Dye Sensitized ◽  
Type Semiconductor

Dye-sensitized solid-state solar cells (DSSCs) replacing the liquid electrolyte with a p-type semiconductor have been extensively examined to solve the practical problems associated with wet-type solar cells. Here, we report the fabrication of a solid-state solar cell using copper iodide (CuI) as the hole conductor and alkyl-functionalized carbazole dye (MK-2) as the sensitizer. A DSSC sensitized with MK-2 showed a solar-to-electrical power conversion efficiency of 3.33% with a Voc of 496 mV and a Jsc of 16.14 mA cm-2 under AM 1.5 simulated sunlight. The long alkyl chains act as a barrier for charge recombination, and the strong accepting and donating abilities of the cyanoacrylic and carbazole groups, respectively, enhance the absorption of light at a longer wavelength, increasing the short-circuit current density. The efficiency recorded in this work is higher than similar DSSCs based on other hole collectors.

scholarly journals Improved conversion efficiency of 10% for solid-state dye-sensitized solar cells utilizing P-type semiconducting CuI and multi-dye consisting of novel porphyrin dimer and organic dyes

2018 ◽  
Vol 6 (45) ◽  
pp. 22508-22512 ◽  
Author(s):  
Naohiko Kato ◽  
Shinya Moribe ◽  
Masahito Shiozawa ◽  
Ryo Suzuki ◽  
Kazuo Higuchi ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Organic Dyes ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Dye Sensitized ◽  
P Type ◽  
Sensitized Solar Cells

To realize highly efficient solid-state dye-sensitized solar cells (SDSCs), the absorption range of the dye should be extended to the near-IR range to increase short-circuit current density (Jsc); a high Jsc in turn requires a highly conductive p-type semiconductor.

Hydrochloric Acid Treatment of TiO2 Electrode for Quasi-Solid-State Dye-Sensitized Solar Cells

2007 ◽  
Vol 7 (11) ◽  
pp. 3722-3726 ◽  
Author(s):  
Dong-Won Park ◽  
Kyung-Hee Park ◽  
Jae-Wook Lee ◽  
Kyung-Jun Hwang ◽  
Yong-Kook Choi
Keyword(s):  
Solar Cell ◽  
Solid State ◽  
Hydrochloric Acid ◽  
Acid Treatment ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized ◽  
Hydrochloric Acid Treatment

Quasi-solid-state dye-sensitized solar cell was fabricated by sandwiched polymer electrolyte containing liquid electrolytes between the dye-sensitized TiO2 electrode and a Pt electrode. The influence of hydrochloric acid treatment of TiO2 photoelectrode on the photoelectronic performance was investigated. Quasi-solid-state dye-sensitized solar cell showed better photoelectronic performance when the TiO2 electrode was treated with hydrochloric acid than that without treatment. The short-circuit current density (Jsc), the open-circuit voltage (Voc), and a conversion efficiency obtained for an incident light intensity of 100 mW m−2 were 6.49 mA cm−2, 0.76 V and 4.1%, respectively. It was found that the hydrochloric acid treatment of TiO2 electrode increased the short-circuit current density and cell efficiency.

scholarly journals Design of a Free-Ruthenium In2S3Crystalline Photosensitized Solar Cell

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Byeong Sub Kwak ◽  
Younghwan Im ◽  
Misook Kang
Keyword(s):  
Solar Cell ◽  
Solid State ◽  
Ruthenium Complex ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Visible Radiation ◽  
Dye Sensitized ◽  
Ruthenium Dye

A new type of sulfide-based, solid-state dye material that is sensitive to visible radiation was assessed as a potential replacement for commercial ruthenium complex dyes in a dye-sensitized solar cell (DSSC) assembly. The In2S3crystals on the surface of the TiO2bottom blocking layer were grown as a solid-state dye material. Scanning electron microscopy of In2S3revealed a microsized, 3D-connected sheet-like shape, which was confirmed by X-ray diffraction to be a beta-structure. The efficiency of the dye-sensitized solar cells assembled with a layer grown with In2S3increased with increasing In2S3mole concentrations to 0.05 M (1.02%) but decreased at concentrations greater than 0.6~0.8%. This suggests that crystalline In2S3acts as a dye sensitized to visible radiation, but the short-circuit current density is too low compared to the commercially available ruthenium dye. This suggests that In2S3crystals did not grow densely but were bulk-grown with large pores, resulting in a smaller amount of In2S3per unit area. Two IPCE curves were observed, which were assigned to TiO2and In2S3, meaning that the TiO2surfaces were covered completely with In2S3crystals. The exposure of TiO2eventually leads to a reaction with the electrolytes, resulting in lower quantum efficiency.

Hydrochloric Acid Treatment of TiO2 Electrode for Quasi-Solid-State Dye-Sensitized Solar Cells

2007 ◽  
Vol 7 (11) ◽  
pp. 3722-3726
Author(s):  
Dong-Won Park ◽  
Kyung-Hee Park ◽  
Jae-Wook Lee ◽  
Kyung-Jun Hwang ◽  
Yong-Kook Choi
Keyword(s):  
Solar Cell ◽  
Solid State ◽  
Hydrochloric Acid ◽  
Acid Treatment ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized ◽  
Hydrochloric Acid Treatment

Quasi-solid-state dye-sensitized solar cell was fabricated by sandwiched polymer electrolyte containing liquid electrolytes between the dye-sensitized TiO2 electrode and a Pt electrode. The influence of hydrochloric acid treatment of TiO2 photoelectrode on the photoelectronic performance was investigated. Quasi-solid-state dye-sensitized solar cell showed better photoelectronic performance when the TiO2 electrode was treated with hydrochloric acid than that without treatment. The short-circuit current density (Jsc), the open-circuit voltage (Voc), and a conversion efficiency obtained for an incident light intensity of 100 mW m−2 were 6.49 mA cm−2, 0.76 V and 4.1%, respectively. It was found that the hydrochloric acid treatment of TiO2 electrode increased the short-circuit current density and cell efficiency.

scholarly journals CdTe-Based Thin Film Solar Cells: Past, Present and Future

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1684
Author(s):  
Alessandro Romeo ◽  
Elisa Artegiani
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Early Years ◽  
Solar Cell Efficiency ◽  
Cell Efficiency

CdTe is a very robust and chemically stable material and for this reason its related solar cell thin film photovoltaic technology is now the only thin film technology in the first 10 top producers in the world. CdTe has an optimum band gap for the Schockley-Queisser limit and could deliver very high efficiencies as single junction device of more than 32%, with an open circuit voltage of 1 V and a short circuit current density exceeding 30 mA/cm2. CdTe solar cells were introduced at the beginning of the 70s and they have been studied and implemented particularly in the last 30 years. The strong improvement in efficiency in the last 5 years was obtained by a new redesign of the CdTe solar cell device reaching a single solar cell efficiency of 22.1% and a module efficiency of 19%. In this paper we describe the fabrication process following the history of the solar cell as it was developed in the early years up to the latest development and changes. Moreover the paper also presents future possible alternative absorbers and discusses the only apparently controversial environmental impacts of this fantastic technology.

Numerical Simulation of Single Junction InGaN Solar Cell by SCAPS

2019 ◽  
Vol 821 ◽  
pp. 407-413 ◽  
Author(s):  
Mohamed Orabi Moustafa ◽  
Tariq Alzoubi
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Collection Efficiency ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Surface Recombination ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Bandgap Energy ◽  
Single Junction

The performance of the InGaN single-junction thin film solar cells has been analyzed numerically employing the Solar Cell Capacitance Simulator (SCAPS-1D). The electrical properties and the photovoltaic performance of the InGaN solar cells were studied by changing the doping concentrations and the bandgap energy along with each layer, i.e. n-and p-InGaN layers. The results reveal an optimum efficiency of the InGaN solar cell of ~ 15.32 % at a band gap value of 1.32 eV. It has been observed that lowering the doping concentration NA leads to an improvement of the short circuit current density (Jsc) (34 mA/cm2 at NA of 1016 cm−3). This might be attributed to the increase of the carrier mobility and hence an enhancement in the minority carrier diffusion length leading to a better collection efficiency. Additionally, the results show that increasing the front layer thickness of the InGaN leads to an increase in the Jsc and to the conversion efficiency (η). This has been referred to the increase in the photogenerated current, as well as to the less surface recombination rate.

scholarly journals Dye-sensitized solar cells with natural dyes extracted from plant seeds

2014 ◽  
Vol 32 (4) ◽  
pp. 547-554 ◽  
Author(s):  
Hatem El-Ghamri ◽  
Taher El-Agez ◽  
Sofyan Taya ◽  
Monzir Abdel-Latif ◽  
Amal Batniji
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Tio2 Film ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Natural Dyes ◽  
Plant Seeds ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

AbstractThe application of natural dyes extracted from plant seeds in the fabrication of dye-sensitized solar cells (DSSCs) has been explored. Ten dyes were extracted from different plant seeds and used as sensitizers for DSSCs. The dyes were characterized using UV-Vis spectrophotometry. DSSCs were prepared using TiO2 and ZnO nanostructured mesoporous films. The highest conversion efficiency of 0.875 % was obtained with an allium cepa (onion) extract-sensitized TiO2 solar cell. The process of TiO2-film sintering was studied and it was found that the sintering procedure significantly affects the response of the cell. The short circuit current of the DSSC was found to be considerably enhanced when the TiO2 semiconducting layer was sintered gradually.

Preparation of the Three Main Layers of CdS/CdTe Thin Film Solar Cells Using a Single Vacuum System

2011 ◽  
Vol 378-379 ◽  
pp. 601-605 ◽  
Author(s):  
Saleh N. Alamri ◽  
M. S. Benghanem ◽  
A. A. Joraid
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Fused Silica ◽  
Vacuum System ◽  
Cdte Thin Film

This study investigates the preparation of the three main layers of a CdS/CdTe thin film solar cell using a single vacuum system. A Close Space Sublimation System was constructed to deposit CdS, CdTe and CdCl2 solar cell layers. Two hot plates were used to heat the source and the substrate. Three fused silica melting dishes were used as containers for the sources. The properties of the deposited CdS and CdTe films were determined via Atomic force microscopy, scanning electron microscopy, X-ray diffraction and optical transmission spectroscopy. An J-V characterization of the fabricated CdS/CdTe solar cells was performed under solar radiation. The short-circuit current density, Jsc, the open-circuit voltage, Voc, fill factor, FF and conversion efficiency, η, were measured and yielded values of 27 mA/cm2, 0.619 V, 58% and 9.8%, respectively.

Characteristics of Dye-Sensitized Solar Cells Using Dye from Pitaya Fruit

2015 ◽  
Vol 793 ◽  
pp. 450-454 ◽  
Author(s):  
N. Gomesh ◽  
R. Syafinar ◽  
Muhamad Irwanto ◽  
Y.M. Irwan ◽  
M. Fareq ◽  
...  
Keyword(s):  
Solar Cell ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Liquid Electrolyte ◽  
Open Circuit ◽  
Dye Sensitized Solar Cell ◽  
Photoelectrochemical Performance ◽  
Cell Efficiency ◽  
Dye Sensitized

Dye-sensitized solar cell (DSSC) consists of TiO2 nanoporous coating which acts as a photo electrode, a sensitizer of dye molecules soaked in the TiO2 film, liquid electrolyte and a counter electrode. This paper focuses on the usage of a sensitizer from the Pitaya fruit. Pitaya or commonly known as dragon fruit (Hylocereus polyrhizus) was extracted and used as a sensitizer to fabricate the dye sensitized solar cell (DSSC). The photoelectrochemical performance of Pitaya based solar cell shows an open circuit voltage (VOC) of 237 mV, short circuit current (ISC) of 4.98 mA, fill factor (FF) of 0.51, solar cell efficiency (η) of 0.70 % and has a peak absorbance rate of 2.7 at 550 nm. The photoelectrochemical and UV-Visible light absorbance performance of Pitaya-DSSC shows good potential in future solar cell fabrication.

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