scholarly journals Experimental Study on the High-Temperature and Low-Temperature Performance of Polyphosphoric Acid/Styrene-Butadiene-Styrene Composite-Modified Asphalt

2019 ◽  
Vol 2019 ◽  
pp. 1-16 ◽  
Author(s):  
Xueqian Li ◽  
Jianzhong Pei ◽  
Jiujian Shen ◽  
Rui Li
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Recovery Rate ◽  
Polyphosphoric Acid ◽  
Elastic Recovery ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The high-performance asphalt materials are used to replace the ordinary road asphalt that cannot meet the requirements of natural environment and traffic situation, which is the effective way to solve poor asphalt pavement durability. In this paper, polyphosphoric acid- (PPA-) modified asphalt and polyphosphoric acid (PPA)/styrene-butadiene-styrene (SBS) composite-modified asphalt with different PPA content were prepared by using two-type asphalt. The effect of PPA modifier on asphalt was analyzed by using the creep elastic recovery rate, accumulating strain and creep modulus tests. The results showed that asphalt types and the PPA could significantly improve the elastic recovery rate of asphalt, reduce the cumulative strain and creep stiffness of the viscosity part, improve the high-temperature performance, and reduce the permanent deformation of the asphalt under repeated load. The high-temperature performance and low-temperature performance of PPA-modified asphalt were studied by the chemical and physical modification techniques. The advantages of modified asphalt are well developed while reducing the price of it, which has important technical and economic significance.

The Rejuvenating and Aging Performances of Aged SBS Modified Asphalt Treated by Different Rejuvenator Sealer Materials

2013 ◽  
Vol 753-755 ◽  
pp. 734-740 ◽  
Author(s):  
Li Wan ◽  
Shao Peng Wu ◽  
Min Lei ◽  
Kim Jenkins
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Economic Benefits ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Low Performance ◽  
Aged Binder ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

Currently, rejuvenator seal which is one of the preventive maintenance methods is more widely used due to its economic benefits and convenience. This paper described the chemical and rheological evaluation of the aged styrene butadiene styrene modified asphalt (ASMA) treated by two rejuvenator sealer materials (RSMs). First the ASMA was rejuvenated by mixing with the RSMs. Then the ASMA and two rejuvenated binders were re-aged by 10h PAV test. At last, the new binder, ASMA, rejuvenated ASMAs, re-aged binders were tested by Dynamic shear rheometer (DSR) and Fourier Transform Infrared Spectroscopy (FTIR). The results showed that the first aging of the new binder had a significant decrease of the low temperature performance and slight improvement of the high temperature performance. In addition, the high temperature performance increased obviously after 10h PAV test. Two RSMs could significantly soften the aged binder due to increase of maltene content existing in the RSMs, and the rejuvenated binder exhibited a better low performance after the 10h PAV test. However they cannot restore the low temperature completely because that RSMs cannot remedy the degradation of SBS modifier and remove the carbonyl produced in the aging progress.

Effect of Shear Time and the Crumb Rubber Percentage on the Properties of Composite Modified Asphalt

2013 ◽  
Vol 848 ◽  
pp. 26-30
Author(s):  
Fu Qiang Dong ◽  
Wen Zhe Zhao ◽  
Yu Zhen Zhang ◽  
Hua Dong Sun ◽  
Wei Yu Fan ◽  
...  
Keyword(s):  
High Temperature ◽  
Crumb Rubber ◽  
Rubber Content ◽  
Step Method ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Important Measurement ◽  
Butadiene Styrene

This paper presents a laboratory study of Styrene-Butadiene-Styrene (SBS)/ crumb rubber modified asphalt by the two-step method. The conventional properties of the modified asphalt were determined. The effects of crumb rubber content and shearing time on the performance of the crumb rubber modified asphalt and composite modified asphalt. The results show that the crumb rubber contents and shearing time have significant impacts on the performance of the modified asphalt. With the crumb rubber content increasing, the high temperature performance was improved and the low temperature chanethe softening point increases and penetration decrease, and the ductility change little. It is comfortable for workability at the crumb rubber content of 20%. The viscosity is an important measurement for the workability of the modified asphalt. After adding the stabilizer, the viscosity increases until the shearing time reaching 1.5h, then it will decrease gradually.

Study on Performance of SBS Modified Asphalt

2013 ◽  
Vol 753-755 ◽  
pp. 715-718
Author(s):  
Xiu Hua Yang
Keyword(s):  
Block Copolymer ◽  
Low Temperature ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Styrene Butadiene Styrene ◽  
Low Temperature Performance ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

SBS is a styrene - butadiene - styrene block copolymer, the addition of SBS of high and low temperature performance and road can be very good to improve the performance of asphalt. This paper studied the performance of the modified asphalt on the content of modifier.

scholarly journals Characterization of Desulfurized Crumb Rubber/Styrene–Butadiene–Styrene Composite Modified Asphalt Based on Rheological Properties

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3780
Author(s):  
Jingyao Yang ◽  
Gang Xu ◽  
Peipei Kong ◽  
Xianhua Chen
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Construction Materials ◽  
Chemical Reactor ◽  
Crumb Rubber ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

With the growing interest in bituminous construction materials, desulfurized crumb rubber (CR)/styrene–butadiene–styrene (SBS) modified asphalts have been investigated by many researchers as low-cost environmental-friendly road construction materials. This study aimed to investigate the rheological properties of desulfurized CR/SBS composite modified asphalt within various temperature ranges. Bending beam rheometer (BBR), linear amplitude sweep (LAS), and multiple stress creep recovery (MSCR) tests were performed on conventional CR/SBS composite modified asphalt and five types of desulfurized CR/SBS modified asphalts. Meanwhile, Burgers’ model and the Kelvin–Voigt model were used to derive nonlinear viscoelastic parameters and analyze the viscoelastic mechanical behavior of the asphalts. The experimental results indicate that both the desulfurized CR/SBS composite modifier and force chemical reactor technique can enhance the crosslinking of CR and SBS copolymer, resulting in an improved high-, intermediate-, and low-temperature performance of desulfurized CR/SBS composite modified asphalt. Burgers’ model was found to be apposite in simulating the creep stages obtained from MSCR tests for CR/SBS composite modified asphalts. The superior high-temperature performance of desulfurized CR/SBS modified asphalt prepared with 4% SBS, 20% desulfurized rubber, and a force chemical reactor time of 45 min contributes to the good high-temperature elastic properties of the asphalt. Therefore, this combination is recommended as an optimal preparation process. In summary, the desulfurization of crumb rubber and using the force chemical reactor technique are beneficial to composite asphalt performance and can provide a new way of utilizing waste tire rubber.

scholarly journals Influence of Compound Modification of Oil Sands De-Oiled Asphalt and Polyphosphoric Acid on High- and Low-Temperature Performance of Styrene-Butadiene-Styrene-Modified Asphalt

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 797
Author(s):  
Xiaoguang Pei ◽  
Weiyu Fan
Keyword(s):  
Low Temperature ◽  
Oil Sands ◽  
Polyphosphoric Acid ◽  
Storage Stability ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Modified Binder ◽  
Styrene Butadiene ◽  
Compound Modification ◽  
Butadiene Styrene

Oil sands de-oiled asphalt (OSDOA) has become a bottleneck for refineries due to its enormous production and huge landfill costs. Applying OSDOA as a modifier is an effective way to reduce environmental pollution and disposal cost. In this study, the influences of OSDOA and polyphosphoric acid (PPA) compound modification on styrene-butadiene-styrene (SBS)-modified binder were investigated. The high-temperature rutting resistance, low-temperature anti-crack performance and fatigue resistance were obtained by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) test. Storage stability and microstructure were also investigated by storage test and Fourier-transform infrared (FTIR) spectroscopy. The results demonstrated that the compound modification of OSDOA/PPA dramatically enhanced the deformation resistance of SBS-modified binder and reduced its low-temperature cracking resistance. The anti-fatigue performance was also decreased. Moreover, the combined effect of OSDOA and PPA could produce composite modified asphalt with excellent storage stability, which was verified by desirable fluorescence images. Furthermore, both physical and chemical interactions coexisted during the OSDOA/PPA compound modification process. Consequently, the optimal doses of OSDOA and PPA were determined to be 10 wt% and 1.0 wt%, considering of the balance between high- and low-temperature characteristics and storage stability of composite modified asphalt.

scholarly journals Evaluation of Properties and Micro-Characteristics of Waste Polyurethane/Styrene-Butadiene-Styrene Composite Modified Asphalt

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng
Keyword(s):  
Low Temperature ◽  
Performance Test ◽  
Permanent Deformation ◽  
Modified Asphalt ◽  
Basic Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
And Storage ◽  
Butadiene Styrene

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.

scholarly journals Evolution of Rheological Behaviors of Styrene-Butadiene-Styrene/Crumb Rubber Composite Modified Bitumen after Different Long-Term Aging Processes

Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2345 ◽  
Author(s):  
Yangsheng Ye ◽  
Gang Xu ◽  
Liangwei Lou ◽  
Xianhua Chen ◽  
Degou Cai ◽  
...  
Keyword(s):  
Low Temperature ◽  
High Speed ◽  
Crumb Rubber ◽  
Modified Bitumen ◽  
High Speed Railway ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this study, a new type of composite modified bitumen was developed by blending styrene-butadiene-styrene (SBS) and crumb rubber (CR) with a chemical method to satisfy the durability requirements of waterproofing material in the waterproofing layer of high-speed railway subgrade. A pressure-aging-vessel test for 20, 40 and 80 h were conducted to obtain bitumen samples in different long-term aging conditions. Multiple stress creep recovery (MSCR) tests, linear amplitude scanning tests and bending beam rheometer tests were conducted on three kinds of asphalt binders (SBS modified asphalt, CR modified asphalt and SBS/CR composite modified asphalt) after different long-term aging processes, including high temperature permanent deformation performance, resistance to low temperature thermal and fatigue crack. Meanwhile, aging sensitivities were compared by different rheological indices. Results showed that SBS/CR composite modified asphalt possessed the best properties before and after aging. The elastic property of CR in SBS/CR composite modified asphalt improved the ability to resist low temperature thermal and fatigue cracks at a range of low and middle temperatures. Simultaneously, the copolymer network of SBS and CR significantly improved the elastic response of the asphalt SBS/CR modified asphalt at a range of high temperatures. Furthermore, all test results indicated that the SBS/CR modified asphalt possesses the outstanding ability to anti-aging. SBS/CR is an ideal kind of asphalt to satisfy the demand of 60 years of service life in the subgrade of high speed railway.

scholarly journals Study on Styrene-Butadiene-Styrene Modified Asphalt Binders Relaxation at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2888
Author(s):  
Sylwia Dziadosz ◽  
Mieczysław Słowik ◽  
Filip Niwczyk ◽  
Marcin Bilski
Keyword(s):  
Low Temperature ◽  
Force Measurement ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Short Term ◽  
Modified Bitumen ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The paper presents the results of laboratory investigation on asphalt binders relaxation at low temperature, carried out in a ductilometer using the tensile test with continuous force measurement. Polymer modified asphalt binder samples consisting of a 50/70 penetration grade bitumen mixed with a concentrate of styrene-butadiene-styrene (SBS) modified bitumen—a 160/220 penetration grade bitumen modified with a SBS copolymer in the amount of 9%—were tested. Therefore, polymer modified binders containing 3%, 4.5%, 6% and 7.5% SBS, respectively, were obtained and investigated. Tensile tests were performed at −16 °C on samples before aging and subjected to short-term aging (RTFOT). Test results in the form of relaxation curves have been mathematically described using a modified generalized Maxwell model. Based on the acquired results, it was shown that the increase of the SBS copolymer content in asphalt binder precipitates the relaxation process, while aging slows down this phenomenon. It has also been proven that with increased content of SBS elastomer in asphalt binder, the effect of short-term aging on binder’s stress relaxation ability at low temperatures is reduced.

scholarly journals Study on Mechanical Behavior of Aging Asphalt Based on Composite Regeneration and Modification

2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Haitao Zhang ◽  
Ying Wang ◽  
Zuoqiang Liu ◽  
Quansheng Sun
Keyword(s):  
Low Temperature ◽  
Social Benefits ◽  
Research Results ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Low Temperature Performance ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Better Than ◽  
Butadiene Styrene

Although the aging asphalt and its regeneration were researched by many researchers, the poor low-temperature performance of regenerating asphalt has still not been solved yet. In this project, the composite technology of regeneration and modification will be used to solve the problem mentioned above. Through the investigation and analysis on the composite mechanism of regeneration and modification for aging asphalt, the objective of the project attempts to explore a method for the synchronized recovery of high- and low-temperature performance of aging asphalt. The research results show that the single regenerating technology cannot fully recover the low-temperature performance of aging asphalt, and the composite technology of regeneration and modification can make the performance of aging asphalt recovery well. The indexes of aging asphalt after composite regeneration and modification have been recovered, which are better than the indexes of 90# asphalt (25°C penetration is 80–100/0.1 mm) and close with the indexes of styrene-butadiene-styrene (SBS) modified asphalt. The project has demonstrated that the composite technology of regeneration and modification can make the high- and low-temperature performance of aging asphalt recovery well. The research results can obtain better economic and social benefits.

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