Increased Cycling Performance of Li-Ion Batteries by Phosphoric Acid Modified LiNi0.5Mn1.5O4 Cathodes in the Presence of LiBOB

LiNi0.5Mn1.5O4 (LNMO), which has an operating voltage of 4.8 vs Li/Li+ and a theoretical capacity of 147 mAh g−1, is an interesting cathode material for advanced lithium ion batteries. However, electrolyte decomposition at the electrode can gradually decrease the capacity of the battery. In this study, the surface of the LNMO cathode has been modified with phosphoric acid (PA) to improve the capacity of the LNMO/graphite full cell. Modification of LNMO cathodes by PA is confirmed by surface analysis. Additionally, the presence of lithium bis-(oxalato) borate (LiBOB) as an electrolyte additive further enhances the performance of PA modified LNMO/graphite cells. The improved performance of PA modified cathodes and electrolytes containing LiBOB can be attributed to the suppressed Mn and Ni deposition on the anode. Elemental analysis suggests that the Mn and Ni dissolution is significantly reduced compared to unmodified LNMO/graphite cells with standard electrolyte.

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Facile and controllable synthesis of solid Co3V2O8 micro-pencils as a highly efficient anode for Li-ion batteries

RSC Advances ◽

10.1039/c7ra03118a ◽

2017 ◽

Vol 7 (39) ◽

pp. 24418-24424 ◽

Cited By ~ 8

Author(s):

Jian Yang ◽

Mengqiang Wu ◽

Feng Gong ◽

Tingting Feng ◽

Cheng Chen ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

Lithium Ion ◽

Cycling Performance ◽

Li Ion Batteries ◽

Controllable Synthesis ◽

Mixed Metal ◽

Highly Efficient ◽

Li Ion

Mixed metal vanadate oxides are promising superior anode materials for lithium ion batteries due to their high specific capacities, improved cycling performance and excellent rate properties.

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Metal dicarboxylates: new anode materials for lithium-ion batteries with good cycling performance

Dalton Transactions ◽

10.1039/c5dt00500k ◽

2015 ◽

Vol 44 (21) ◽

pp. 9909-9914 ◽

Cited By ~ 19

Author(s):

Hailong Fei ◽

Xin Liu ◽

Zhiwei Li ◽

Wenjing Feng

Keyword(s):

Lithium Ion Batteries ◽

Anode Material ◽

Anode Materials ◽

Lithium Ion ◽

Cycling Performance ◽

Cycling Stability ◽

Li Ion Batteries ◽

Li Ion ◽

Good Cycling Stability

Manganese 3,5-pyridinedicarboxylate as an anode material for Li-ion batteries showed good cycling stability.

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Overcharge protection of lithium-ion batteries with phenothiazine redox shuttles

New Journal of Chemistry ◽

10.1039/d0nj05935h ◽

2021 ◽

Author(s):

Susan A. Odom

Keyword(s):

Lithium Ion Batteries ◽

Lithium Ion ◽

Li Ion Batteries ◽

Phenothiazine Derivatives ◽

Redox Shuttles ◽

Li Ion ◽

Overcharge Protection

Overcharge protection of Li-ion batteries with a variety of phenothiazine derivatives.

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Parameter optimization and yield prediction of cathode coating separation process for direct recycling of end-of-life lithium-ion batteries

RSC Advances ◽

10.1039/d1ra04086c ◽

2021 ◽

Vol 11 (39) ◽

pp. 24132-24136

Author(s):

Liurui Li ◽

Tairan Yang ◽

Zheng Li

Keyword(s):

Lithium Ion Batteries ◽

End Of Life ◽

Lithium Ion ◽

Separation Process ◽

Yield Prediction ◽

Li Ion Batteries ◽

Treatment Efficiency ◽

Control Factors ◽

Li Ion ◽

Pre Treatment

The pre-treatment efficiency of the direct recycling strategy in recovering end-of-life Li-ion batteries is predicted with levels of control factors.

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Dealloying-Derived Nanoporous Cu6Sn5 Alloy as Stable Anode Materials for Lithium-Ion Batteries

Materials ◽

10.3390/ma14154348 ◽

2021 ◽

Vol 14 (15) ◽

pp. 4348

Author(s):

Chi Zhang ◽

Zheng Wang ◽

Yu Cui ◽

Xuyao Niu ◽

Mei Chen ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Anode Materials ◽

Coulombic Efficiency ◽

Lithium Ion ◽

Specific Area ◽

Cycling Performance ◽

Ex Situ ◽

Li Ion ◽

Xrd Patterns ◽

Cu6sn5 Alloy

The volume expansion during Li ion insertion/extraction remains an obstacle for the application of Sn-based anode in lithium ion-batteries. Herein, the nanoporous (np) Cu6Sn5 alloy and Cu6Sn5/Sn composite were applied as a lithium-ion battery anode. The as-dealloyed np-Cu6Sn5 has an ultrafine ligament size of 40 nm and a high BET-specific area of 15.9 m2 g−1. The anode shows an initial discharge capacity as high as 1200 mA h g−1, and it remains a capacity of higher than 600 mA h g−1 for the initial five cycles at 0.1 A g−1. After 100 cycles, the anode maintains a stable capacity higher than 200 mA h g−1 for at least 350 cycles, with outstanding Coulombic efficiency. The ex situ XRD patterns reveal the reverse phase transformation between Cu6Sn5 and Li2CuSn. The Cu6Sn5/Sn composite presents a similar cycling performance with a slightly inferior rate performance compared to np-Cu6Sn5. The study demonstrates that dealloyed nanoporous Cu6Sn5 alloy could be a promising candidate for lithium-ion batteries.

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Metal–organic nanofibers as anodes for lithium-ion batteries

RSC Advances ◽

10.1039/c4ra16416d ◽

2015 ◽

Vol 5 (26) ◽

pp. 20386-20389 ◽

Cited By ~ 34

Author(s):

Chongchong Zhao ◽

Cai Shen ◽

Weiqiang Han

Keyword(s):

Amino Acid ◽

Lithium Ion Batteries ◽

Anode Materials ◽

Lithium Ion ◽

Copper Nitrate ◽

Li Ion Batteries ◽

Metal Organic ◽

Li Ion

Metal organic nanofibers (MONFs) synthesized from precursors of amino acid and copper nitrate were applied as anode materials for Li-ion batteries.

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Alternative Anodes for Low Temperature Lithium-Ion Batteries

Journal of Materials Chemistry A ◽

10.1039/d1ta00998b ◽

2021 ◽

Author(s):

Gearoid A Collins ◽

Hugh Geaney ◽

Kevin Michael Ryan

Keyword(s):

Low Temperature ◽

Lithium Ion Batteries ◽

Electric Vehicles ◽

Lithium Ion ◽

Li Ion Batteries ◽

Li Ion ◽

Critical Components

Li-ion batteries (LIBs) have become critical components in the manufacture of electric vehicles (EV) as they offer the best all-round performance compared to competing battery chemistries. However, LIB performance at...

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Silicon oxycarbide ceramics as anodes for lithium ion batteries: influence of carbon content on lithium storage capacity

RSC Advances ◽

10.1039/c6ra24539k ◽

2016 ◽

Vol 6 (106) ◽

pp. 104597-104607 ◽

Cited By ~ 21

Author(s):

Monika Wilamowska-Zawlocka ◽

Paweł Puczkarski ◽

Zofia Grabowska ◽

Jan Kaspar ◽

Magdalena Graczyk-Zajac ◽

...

Keyword(s):

Carbon Content ◽

Lithium Ion Batteries ◽

Storage Capacity ◽

Lithium Ion ◽

Silicon Oxycarbide ◽

Synthesis And Characterization ◽

Li Ion Batteries ◽

Lithium Storage ◽

Li Ion

We report here on the synthesis and characterization of silicon oxycarbide (SiOC) in view of its application as a potential anode material for Li-ion batteries.

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Capacity Loss Estimation For Li-Ion Batteries Based On A Semi-Empirical Model

ECMS 2021 Proceedings edited by Khalid Al-Begain, Mauro Iacono, Lelio Campanile, Andrzej Bargiela ◽

10.7148/2021-0235 ◽

2021 ◽

Author(s):

Mohammed Rabah ◽

Eero Immonen ◽

Sajad Shahsavari ◽

Mohammad-Hashem Haghbayan ◽

Kirill Murashko ◽

...

Keyword(s):

Lithium Ion Batteries ◽

Empirical Model ◽

Lithium Ion ◽

Average Error ◽

Li Ion Batteries ◽

Capacity Loss ◽

Capacity Degradation ◽

Battery Capacity ◽

Li Ion ◽

Semi Empirical

Understanding battery capacity degradation is instrumental for designing modern electric vehicles. In this paper, a Semi-Empirical Model for predicting the Capacity Loss of Lithium-ion batteries during Cycling and Calendar Aging is developed. In order to redict the Capacity Loss with a high accuracy, battery operation data from different test conditions and different Lithium-ion batteries chemistries were obtained from literature for parameter optimization (fitting). The obtained models were then compared to experimental data for validation. Our results show that the average error between the estimated Capacity Loss and measured Capacity Loss is less than 1.5% during Cycling Aging, and less than 2% during Calendar Aging. An electric mining dumper, with simulated duty cycle data, is considered as an application example.

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