scholarly journals Preparation and Characterization of Antimony-Doped Tin Oxide Nanocrystallite Coatings on 316L Stainless Steel

2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Giang Nguyen Truong ◽  
Long Hoang Vinh ◽  
Suong Huynh Thu ◽  
Phuong Nguyen Thi Hong ◽  
Bac Nguyen Quang

The study on the coatings containing antimony-dope tin oxide mostly has been done on titanium and its alloys for preparation of electrode materials. In this study, we try to prepare the similar coatings on 316L stainless steel, which is more common than titanium, and investigate some characteristics of the formed coatings. The preparation of the coating is by the impregnation of the substrate in solution containing SnCl4 and SbCl3 with the ratio of 93/7, and the concentration of SbCl3, 10 g/L in isopropanol, pH of 1–1.2, and the annealed temperature of 450°C give suitable coating for electrode materials. Some coating features, such as the crystal structure (XRD), morphology (SEM), hardness, electrical resistant, and electrochemical behaviors of the coating on the substrate have been also investigated. The results of the study show that the coatings can be used as electrode materials for the effective treatment of organic colorants in water such as methylene blue in water treatment.

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 185
Author(s):  
Nina Arnosti ◽  
Marco Meyer ◽  
Alessandro Prescimone ◽  
Edwin C. Constable ◽  
Catherine E. Housecroft

The preparation and characterization of [Cu(POP)(biq)][PF6] and [Cu(xantphos)(biq)][PF6] are reported (biq = 1,1′-biisoquinoline, POP = bis(2-(diphenylphosphanyl)phenyl)ether, and xantphos = (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(diphenylphosphane). The single crystal structure of [Cu(POP)(biq)][PF6] 0.5Et2O was determined and compared to that in three salts of [Cu(POP)(bq)]+ in which bq = 2,2′-biquinoline. The P–C–P angle is 114.456(19)o in [Cu(POP)(biq)]+ compared to a range of 118.29(3)–119.60(3)o [Cu(POP)(bq)]+. There is a change from an intra-POP PPh2-phenyl/(C6H4)2O-arene π-stacking in [Cu(POP)(biq)]+ to a π-stacking contact between the POP and bq ligands in [Cu(POP)(bq)]+. In solution and at ambient temperatures, the [Cu(POP)(biq)][PF6]+ and [Cu(xantphos)(biq)]+ cations undergo several concurrent dynamic processes, as evidenced in their multinuclear NMR spectra. The photophysical and electrochemical behaviors of the heteroleptic copper (I) complexes were investigated, and the effects of changing from bq to biq are described. Short Cu···O distances within the [Cu(POP)(biq)]+ and [Cu(xantphos)(biq)]+ cations may contribute to their very low photoluminescent quantum yields.


2021 ◽  
Vol 27 (S1) ◽  
pp. 2160-2161
Author(s):  
Lingfeng He ◽  
Laura Hawkins ◽  
Jingfan Yang ◽  
Xiang Liu ◽  
Miao Song ◽  
...  

2020 ◽  
Vol 382 ◽  
pp. 125175 ◽  
Author(s):  
L.B. Coelho ◽  
S. Kossman ◽  
A. Mejias ◽  
X. Noirfalise ◽  
A. Montagne ◽  
...  

2016 ◽  
Vol 64 ◽  
pp. 93-101 ◽  
Author(s):  
Giuseppe Blanda ◽  
Valerio Brucato ◽  
Francesco Carfì Pavia ◽  
Silvia Greco ◽  
Salvatore Piazza ◽  
...  

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