High resolution ultrasonic interferometry for quantitative nondestructive characterization of interfacial adhesion in multilayer (metal/polymer/metal) composites

1993 ◽  
Vol 7 (7) ◽  
pp. 719-741 ◽  
Author(s):  
D. Lévesque ◽  
A. Legros ◽  
A. Michel ◽  
L. Piché
2013 ◽  
Vol 461 ◽  
pp. 402-406
Author(s):  
Yan Ding ◽  
Zhan Shi Jiao ◽  
Yun Xia Xu ◽  
Dong Jie Guo ◽  
Zhen Dong Dai

A macromoleclar polymer (Sulfonated polystyrene - Polyhydromethylsilane, SPS-PMHS) was synthesized from polystyrene by sulfonation, acylation, amination and hydrosilylation. Characterization of the hydrosilylation process was performed with attenuated total reflectance-fourier transform infrared (ATR-FTIR) spectroscopy. The SPS-PMHS was homogeneously dispersed in the Nafion matrix with doping level of 33.3 wt %. Experimental results show that the yield tip-displacement values of the polymer nanocomposite have not been enhanced, but the nonaqueous working time is 2.7 times higher than that of the virgin nafion.


2008 ◽  
Vol 80 (11) ◽  
pp. 2425-2437 ◽  
Author(s):  
Dmitri N. Muraviev ◽  
Patricia Ruiz ◽  
Maria Muñoz ◽  
Jorge Macanás

Stabilization of metal nanoparticles (MNPs) in polymeric matrices of different types has proven to be one of the most promising strategies to prevent their aggregation and to retain their properties. Polymer-stabilized MNPs (PSMNPs) and those based on polymer-metal nanocomposite materials are starting to find wide application in various fields of science and technology. In this paper, we demonstrate that metal-polymer nanocomposite membranes (MPNCMs) containing MNPs can easily be prepared in an ion-exchange such as, for example, sulfonated polyetherether ketone (SPEEK) matrix by using the polymeric membranes as nanoreactors for synthesis and to characterize the composition and structure of the formed MNPs. Metal ions (or metal ion complexes) are first incorporated into the polymeric matrix where they undergo reduction, leading to formation of corresponding MPNCMs. Since this technique allows successive metal loading-reduction cycles to be carried out, it enables synthesis of both monometallic and bimetallic (e.g., core-shell) MNPs. The proposed approach is illustrated by synthesis and characterization of MPNCMs containing both monometallic and bimetallic core-shell MNPs, formed by combinations of Pd, Pt, Co, Ni, and Cu, along with their application in electrochemical sensor and biosensor constructions.


2017 ◽  
Vol 11 (2) ◽  
pp. 213-224 ◽  
Author(s):  
Peter Groche ◽  
David Übelacker ◽  
Philipp Stein ◽  
Frank Steinbach ◽  
A. Erman Tekkaya

2014 ◽  
Vol 1018 ◽  
pp. 137-144 ◽  
Author(s):  
David Übelacker ◽  
Johannes Hohmann ◽  
Peter Groche

New approaches in lightweight design require the use of multi materials like metalpolymermetal composites. Composite materials, especially so-called sandwich panels, offer the possibility to combine properties of different materials synergistically. Shear cutting is one of the commonly used manufacturing processes. However, conventional shear cutting of sandwich panels leads to characteristic types of failure, such as high bending of the facings, delamination effects, burr formation and an undefined cracking of the core material. In the present research, the cutting force requirement and the failure progress for lubricant free shear cutting of metal-polymer-metal composites is studied. Two thermoplastic polymers, an aluminum sheet and an unalloyed steel sheet are combined in order to create different composite materials. Furthermore, the composite materials are cut stepwise to examine the different stages of a cutting process in detail.


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