scholarly journals Stability of Leapfrog Constant-Coefficients Semi-Implicit Schemes for the Fully Elastic System of Euler Equations: Case with Orography

2005 ◽  
Vol 133 (5) ◽  
pp. 1065-1075 ◽  
Author(s):  
P. Bénard ◽  
J. Mašek ◽  
P. Smolíková
Keyword(s):  
Euler Equations ◽  
Evolution Equations ◽  
Momentum Equation ◽  
Primitive Equations ◽  
Prognostic Variables ◽  
Flat Terrain ◽  
Implicit Schemes ◽  
Constant Coefficients ◽  
The Stability ◽  
The One

Abstract The stability of constant-coefficients semi-implicit schemes for the hydrostatic primitive equations and the fully elastic Euler equations in the presence of explicitly treated thermal residuals has been theoretically examined in the earlier literature, but only for the case of a flat terrain. This paper extends these analyses to a case in which an orography is present, in the shape of a uniform slope. It is shown, with mass-based coordinates, that for the Euler equations, the presence of a slope reduces furthermore the set of the prognostic variables that can be used in the vertical momentum equation to maintain the robustness of the scheme, compared to the case of a flat terrain. The situation appears to be similar for systems cast in mass-based and height-based vertical coordinates. Still for mass-based vertical coordinates, an optimal prognostic variable is proposed and is shown to result in a robustness similar to the one observed for the hydrostatic primitive equations system. The prognostic variables that lead to robust semi-implicit schemes share the property of having cumbersome evolution equations, and an alternative time treatment of some terms is then required to keep the evolution equation reasonably simple. This treatment is shown not to modify substantially the stability of the time scheme. This study finally indicates that with a pertinent choice for the prognostic variables, mass-based vertical coordinates are equally suitable as height-based coordinates for efficiently solving the compressible Euler equations system.

Use of a Lyophilized Reference Plasma to Compare Coagulation Test Procedures

1975 ◽  
Vol 34 (02) ◽  
pp. 426-444 ◽  
Author(s):  
J Kahan ◽  
I Nohén
Keyword(s):  
Oral Anticoagulant Therapy ◽  
Repeated Measurements ◽  
Test Procedures ◽  
Coagulation Activity ◽  
Close Relationship ◽  
Measured Activity ◽  
Test Materials ◽  
The Difference ◽  
The Stability ◽  
The One

SummaryIn 4 collaborative trials, involving a varying number of hospital laboratories in the Stockholm area, the coagulation activity of different test materials was estimated with the one-stage prothrombin tests routinely used in the laboratories, viz. Normotest, Simplastin-A and Thrombotest. The test materials included different batches of a lyophilized reference plasma, deep-frozen specimens of diluted and undiluted normal plasmas, and fresh and deep-frozen specimens from patients on long-term oral anticoagulant therapy.Although a close relationship was found between different methods, Simplastin-A gave consistently lower values than Normotest, the difference being proportional to the estimated activity. The discrepancy was of about the same magnitude on all the test materials, and was probably due to a divergence between the manufacturers’ procedures used to set “normal percentage activity”, as well as to a varying ratio of measured activity to plasma concentration. The extent of discrepancy may vary with the batch-to-batch variation of thromboplastin reagents.The close agreement between results obtained on different test materials suggests that the investigated reference plasma could be used to calibrate the examined thromboplastin reagents, and to compare the degree of hypocoagulability estimated by the examined PIVKA-insensitive thromboplastin reagents.The assigned coagulation activity of different batches of the reference plasma agreed closely with experimentally obtained values. The stability of supplied batches was satisfactory as judged from the reproducibility of repeated measurements. The variability of test procedures was approximately the same on different test materials.

Structure, Stability and Water Adsorption on Ultra-Thin TiO2 Supported on TiN

2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  
Keyword(s):  
Density Functional ◽  
Water Adsorption ◽  
Chemical Potential ◽  
Energy Gap ◽  
Molecular Water ◽  
Structure Stability ◽  
Ambient Conditions ◽  
Rutile Structure ◽  
The Stability ◽  
The One

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>

scholarly journals Stability of a one-dimensional morphoelastic model for post-burn contraction

2021 ◽  
Vol 83 (3) ◽  
Author(s):  
Ginger Egberts ◽  
Fred Vermolen ◽  
Paul van Zuijlen
Keyword(s):  
Wound Healing ◽  
Residual Stresses ◽  
Truncation Error ◽  
Signaling Molecules ◽  
Discrete Problem ◽  
One Dimensional ◽  
Stability Constraint ◽  
Biological Interpretation ◽  
The Stability ◽  
The One

AbstractTo deal with permanent deformations and residual stresses, we consider a morphoelastic model for the scar formation as the result of wound healing after a skin trauma. Next to the mechanical components such as strain and displacements, the model accounts for biological constituents such as the concentration of signaling molecules, the cellular densities of fibroblasts and myofibroblasts, and the density of collagen. Here we present stability constraints for the one-dimensional counterpart of this morphoelastic model, for both the continuous and (semi-) discrete problem. We show that the truncation error between these eigenvalues associated with the continuous and semi-discrete problem is of order $${{\mathcal {O}}}(h^2)$$ O ( h 2 ) . Next we perform numerical validation to these constraints and provide a biological interpretation of the (in)stability. For the mechanical part of the model, the results show the components reach equilibria in a (non) monotonic way, depending on the value of the viscosity. The results show that the parameters of the chemical part of the model need to meet the stability constraint, depending on the decay rate of the signaling molecules, to avoid unrealistic results.

scholarly journals One-Dimensional Organic–Inorganic Material (C6H9N2)2BiCl5: From Synthesis to Structural, Spectroscopic, and Electronic Characterizations

2021 ◽  
Vol 22 (4) ◽  
pp. 2030
Author(s):  
Hela Ferjani ◽  
Hammouda Chebbi ◽  
Mohammed Fettouhi
Keyword(s):  
Hydrogen Bonding ◽  
Density Functional ◽  
Crystal Packing ◽  
Diffuse Reflectance Spectrum ◽  
Enrichment Ratio ◽  
One Dimensional ◽  
Organic Part ◽  
Fukui Indices ◽  
The Stability ◽  
The One

The new organic–inorganic compound (C6H9N2)2BiCl5 (I) has been grown by the solvent evaporation method. The one-dimensional (1D) structure of the allylimidazolium chlorobismuthate (I) has been determined by single crystal X-ray diffraction. It crystallizes in the centrosymmetric space group C2/c and consists of 1-allylimidazolium cations and (1D) chains of the anion BiCl52−, built up of corner-sharing [BiCl63−] octahedra which are interconnected by means of hydrogen bonding contacts N/C–H⋯Cl. The intermolecular interactions were quantified using Hirshfeld surface analysis and the enrichment ratio established that the most important role in the stability of the crystal structure was provided by hydrogen bonding and H···H interactions. The highest value of E was calculated for the contact N⋯C (6.87) followed by C⋯C (2.85) and Bi⋯Cl (2.43). These contacts were favored and made the main contribution to the crystal packing. The vibrational modes were identified and assigned by infrared and Raman spectroscopy. The optical band gap (Eg = 3.26 eV) was calculated from the diffuse reflectance spectrum and showed that we can consider the material as a semiconductor. The density functional theory (DFT) has been used to determine the calculated gap, which was about 3.73 eV, and to explain the electronic structure of the title compound, its optical properties, and the stability of the organic part by the calculation of HOMO and LUMO energy and the Fukui indices.

scholarly journals The Concepts of Well-Posedness and Stability in Different Function Spaces for the 1D Linearized Euler Equations

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Stefan Balint ◽  
Agneta M. Balint
Keyword(s):  
Euler Equation ◽  
Function Space ◽  
Euler Equations ◽  
Small Perturbation ◽  
Function Spaces ◽  
Well Posedness ◽  
Small Solution ◽  
Null Solution ◽  
Linearized Euler Equations ◽  
The Stability

This paper considers the stability of constant solutions to the 1D Euler equation. The idea is to investigate the effect of different function spaces on the well-posedness and stability of the null solution of the 1D linearized Euler equations. It is shown that the mathematical tools and results depend on the meaning of the concepts “perturbation,” “small perturbation,” “solution of the propagation problem,” and “small solution, that is, solution close to zero,” which are specific for each function space.

A TWELFTH-ORDER FOUR-STEP FORMULA FOR THE NUMERICAL INTEGRATION OF THE ONE-DIMENSIONAL SCHRÖDINGER EQUATION

2003 ◽  
Vol 14 (08) ◽  
pp. 1087-1105 ◽  
Author(s):  
ZHONGCHENG WANG ◽  
YONGMING DAI
Keyword(s):  
Schrödinger Equation ◽  
Numerical Integration ◽  
Schrodinger Equation ◽  
Numerical Test ◽  
New Method ◽  
Step Method ◽  
One Dimensional ◽  
The Stability ◽  
The One ◽  
Order Four

A new twelfth-order four-step formula containing fourth derivatives for the numerical integration of the one-dimensional Schrödinger equation has been developed. It was found that by adding multi-derivative terms, the stability of a linear multi-step method can be improved and the interval of periodicity of this new method is larger than that of the Numerov's method. The numerical test shows that the new method is superior to the previous lower orders in both accuracy and efficiency and it is specially applied to the problem when an increasing accuracy is requested.

First Principles Investigation of the Stability and the Chemical Behavior of Hydrogen in ThCoH4

2011 ◽  
Vol 66 (3) ◽  
pp. 269-274
Author(s):  
Samir F. Matar
Keyword(s):  
Negative Charge ◽  
Geometry Optimization ◽  
Full Geometry Optimization ◽  
Intermetallic Matrix ◽  
Charge Analysis ◽  
The Stability ◽  
The One ◽  
Site Selective ◽  
Bader Charge Analysis ◽  
Positively Charged

We address the changes in the electronic structure brought by the insertion of hydrogen into ThCo leading to the experimentally observed ThCoH4. Full geometry optimization positions the hydrogen in three sites stabilized in the expanded intermetallic matrix. From a Bader charge analysis, hydrogen is found to be in a narrow iono-covalent (~−0.6) to covalent (~−0.3) bonding which should enable site-selective desorption. The overall chemical picture shows a positively charged Thδ+ with the negative charge redistributed over a complex anion {CoH4}δ− with δ~1.8. Nevertheless this charge transfer remains far from the one in the more ionic hydridocobaltate anion CoH54− in Mg2CoH5, due to the largely electropositive character of Mg.

The M/G/1 queue with negative customers

1996 ◽  
Vol 28 (02) ◽  
pp. 540-566 ◽  
Author(s):  
Peter G. Harrison ◽  
Edwige Pitel
Keyword(s):  
Iterative Solution ◽  
Single Server ◽  
Negative Customers ◽  
Poisson Arrival ◽  
First Case ◽  
Full Study ◽  
Service Times ◽  
The Stability ◽  
The One ◽  
Iterative Solution Method

We derive expressions for the generating function of the equilibrium queue length probability distribution in a single server queue with general service times and independent Poisson arrival streams of both ordinary, positive customers and negative customers which eliminate a positive customer if present. For the case of first come first served queueing discipline for the positive customers, we compare the killing strategies in which either the last customer in the queue or the one in service is removed by a negative customer. We then consider preemptive-restart with resampling last come first served queueing discipline for the positive customers, combined with the elimination of the customer in service by a negative customer—the case of elimination of the last customer yields an analysis similar to first come first served discipline for positive customers. The results show different generating functions in contrast to the case where service times are exponentially distributed. This is also reflected in the stability conditions. Incidently, this leads to a full study of the preemptive-restart with resampling last come first served case without negative customers. Finally, approaches to solving the Fredholm integral equation of the first kind which arises, for instance, in the first case are considered as well as an alternative iterative solution method.

scholarly journals Dynamical system analysis of three-form field dark energy model with baryonic matter

2020 ◽  
Vol 80 (9) ◽  
Author(s):  
Soumya Chakraborty ◽  
Sudip Mishra ◽  
Subenoy Chakraborty
Keyword(s):  
Dynamical System ◽  
Dark Energy ◽  
Cold Dark Matter ◽  
System Analysis ◽  
Evolution Equations ◽  
Matter Field ◽  
Baryonic Matter ◽  
Form Field ◽  
The Stability ◽  
Manifold Theory

AbstractA cosmological model having matter field as (non) interacting dark energy (DE) and baryonic matter and minimally coupled to gravity is considered in the present work with flat FLRW space time. The DE is chosen in the form of a three-form field while radiation and dust (i.e; cold dark matter) are the baryonic part. The cosmic evolution is studied through dynamical system analysis of the autonomous system so formed from the evolution equations by suitable choice of the dimensionless variables. The stability of the non-hyperbolic critical points are examined by Center manifold theory and possible bifurcation scenarios have been examined.

Sign in / Sign up

Export Citation Format

Share Document