Carbon Nanotubes in Tyre Rubbers. Part 2: A Study of the Effect of Nanotubes on the Properties of Carbon-black-filled Tread Rubbers

2017 ◽  
Vol 44 (3) ◽  
pp. 19-24
Author(s):  
A.R. Mukhtarov ◽  
A.M. Mokhnatkin ◽  
V.P. Dorozhkin ◽  
E.G. Mokhnatkina ◽  
V.E. Muradyan ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Black ◽  
Stearic Acid ◽  
Dynamic Properties ◽  
Single Layer ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cohesion Strength ◽  
Mooney Viscosity ◽  
Styrene Butadiene

The processing and mechanical properties of green and vulcanised tread rubbers based on a blend of two types of styrene butadiene rubber filled with carbon black and containing single-layer carbon nanotubes (SCNTs) were studied. Three types of rubber mix were prepared: one containing untreated SCNTs and stearic acid, and two with SCNTs treated by different methods. The properties of these composites were compared. In all cases, the introduction of SCNTs leads to an increase in the cohesion strength of green rubber mixes, to an improvement in their vulcanisation properties, and to an increase in the Mooney viscosity, and also to an improvement in the dynamic properties of the vulcanisates, and here the Payne effect increases. There is also an improvement in the wear resistance, especially in the case of introducing untreated SCNTs and stearic acid which ensures the presence of –COOH groups.

Carbon Nanotubes in Tyre Rubbers. Part 3: Study of the Effect of Nanotubes in Silica-filled Tread Rubbers

2017 ◽  
Vol 44 (3) ◽  
pp. 25-30
Author(s):  
R.R. Batrshina ◽  
A.M. Mokhnatkin ◽  
V.P. Dorozhkin ◽  
E.G. Mokhnatkina ◽  
V.E. Muradyan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Single Walled Carbon Nanotubes ◽  
The Other ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Cohesion Strength ◽  
Mooney Viscosity ◽  
Styrene Butadiene ◽  
Walled Carbon Nanotubes

The processing and mechanical properties of green and vulcanised tread rubbers based on styrene butadiene rubber and polybutadiene with the addition of natural rubbers filled with silica and containing single-walled carbon nanotubes (SCNTs) were studied. Two types of rubber were manufactured: one containing untreated SCNTs and stearic acid, ensuring the presence of – COOH groups, and the other with treated SCNTs. The properties of these composites were compared. In both cases, the introduction of SCNTs leads to an increase in the cohesion strength of the green rubber mixes, to an improvement in their vulcanisation properties, and to an increase in their Mooney viscosity. In contrast to tread rubbers filled with carbon black, in the case of filling with silica the Payne effect decreases. The dynamic and other mechanical properties of the vulcanisates change in different ways. The wear resistance, like other service properties, is improved.

Studies on Mechanical Properties and Dynamic Performance of SSBR/CB/Silica Composites

2016 ◽  
Vol 717 ◽  
pp. 52-56 ◽  
Author(s):  
Wei Liu ◽  
Lin Li ◽  
Bing Kai Han ◽  
Cheng Zhong Zong
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
Dynamic Properties ◽  
Dynamic Performance ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Hybrid Fillers ◽  
Two Component ◽  
Series Of Experiments ◽  
Styrene Butadiene

Carbon black ( CB ) and silica were used as two-component fillers to enhance the practicability of rubber. In this study, the microstructure, mechanical and dynamic properties of solution-polymerized styrene-butadiene rubber ( SSBR ) vulcanizates filled with carbon black and silica were characterized. 50 phr of total hybrid fillers was used as the base. A series of experiments with different ratios of CB/silica were carried out to determine the best contribution to the performance of SSBR vulcanizates. The studies have shown that when the vulcanizates exhibited the better overall mechanical and dynamic performance with 20 phr silica loading and 30 phr CB loading.

Evaluation of Isobutylene-Based Elastomers in a Model Winter Tire Tread

2003 ◽  
Vol 76 (2) ◽  
pp. 348-364 ◽  
Author(s):  
Walter H. Waddell ◽  
Julie H. Kuhr ◽  
Robert R. Poulter
Keyword(s):  
Carbon Black ◽  
Natural Rubber ◽  
Dynamic Properties ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Model Compounds ◽  
Styrene Butadiene

Abstract The performance of butyl, chlorobutyl, bromobutyl, and brominated isobutylene-co-para-methylstyrene (BIMS) rubbers were evaluated versus a solution-polymerized styrene-butadiene rubber with 20% bound styrene in model winter tire tread formulations containing natural rubber and butadiene rubber. Isobutylene-based elastomer performance was compared in carbon black-filled and silane-coupled silica-filled systems. Based on laboratory dynamic properties predictive of wet and winter traction, and on DIN abrasion index values, BIMS is the elastomer of choice affording increased tangent delta values between 0 °C and −40 °C, and the highest DIN abrasion index values of the isobutylene-based elastomers. Evaluation of BIMS / NR / BR blends in model compounds show its utility as a tread polymer for improving winter performance.

CORRELATION OF FILLER NETWORKING WITH REINFORCEMENT AND DYNAMIC PROPERTIES OF SSBR/CARBON BLACK/SILICA COMPOSITES

2015 ◽  
Vol 88 (4) ◽  
pp. 676-689 ◽  
Author(s):  
Wengjiang Feng ◽  
Zhenghai Tang ◽  
Peijin Weng ◽  
Baochun Guo
Keyword(s):  
Carbon Black ◽  
Network Structure ◽  
Dynamic Properties ◽  
Rolling Resistance ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Composites ◽  
Filler Network ◽  
Improved Performance ◽  
Styrene Butadiene

ABSTRACT The use of silica to partially replace carbon black is a common practice in the fabrication of “green tires.” Although some degree of consensus has been approached concerning the improved performance conferred by silica substitution, such as the improved dispersion of carbon black, a quantitative understanding of the relationship between filler networking and the performance of rubber composites has not been established. Thus, an investigation focusing on filler network structure and the correlation between the network structure and the reinforcement of rubber composites was conducted. We prepared solution-polymerized styrene–butadiene rubber (SSBR) reinforced by carbon black and carbon black/silica in different ratios. To exclude as much of the effect from changed crosslinking, and figure out how filler blending influences filler dispersion and filler network structure, the silane generally used in the tire industry was not adopted. The quantitative predictor, the mass fractal dimension df, was derived from the Kraus model and the Huber–Vilgis model. We found that when the amount of substituted silica increases, the filler cluster branching decreases, accompanied by increased reinforcement efficiency. The depressed filler networking induced by silica substitution at an appropriate proportion leads to improved dynamic properties, including lower rolling resistance and better wet skid. When the silica proportion in the filler is too high, severe filler networking is observed, resulting in decreased reinforcing efficiency and impaired dynamic properties.

Effect of Carbon Black Structures towards Heat Build-Up Measurements and its Dynamic Properties

2015 ◽  
Vol 1134 ◽  
pp. 131-137 ◽  
Author(s):  
Mohd Ismail Rifdi Rizuan ◽  
Mohammad Azizol Abdul Wahab ◽  
Ahmad Zafir Romli
Keyword(s):  
Carbon Black ◽  
Dynamic Properties ◽  
Loss Modulus ◽  
Rolling Resistance ◽  
Testing Procedure ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
High Carbon ◽  
Heat Build Up ◽  
Styrene Butadiene

The aim of this study is to investigate the effect of different carbon black structures towards heat build-up measurements and its dynamic properties such as tangent delta, loss modulus and storage modulus on the industrial rubber compounds containing Natural Rubber (NR) and Styrene Butadiene Rubber (SBR). Different carbon black structures were used and characterised with respect to their rheological and physical properties. Heat Build-up test is a testing procedure which is used to measure the rate of heat generated by the rubber vulcanisates when subjected to rapidly oscillating compressive stresses or strain under controlled conditions. It was found that NR compound containing low and high carbon black structures; N375 and N339 produced lower heat generation compared to NR/SBR blends that filled with the same type of carbon black fillers. It shows that NR with low and high carbon black structures exhibits low heat build-up (surface and intrinsic) with a balance of good traction and low rolling resistance for application in tyre.

EFFECT OF CURING ADDITIVES ON THE DISPERSION KINETICS OF CARBON BLACK IN RUBBER COMPOUNDS)

2011 ◽  
Vol 84 (3) ◽  
pp. 415-424 ◽  
Author(s):  
H. H. Le ◽  
S. Ilisch ◽  
E. Hamann ◽  
M. Keller ◽  
H-J. Radusch
Keyword(s):  
Carbon Black ◽  
Stearic Acid ◽  
Electrical Conductance ◽  
Rubber Matrix ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Dispersion Process ◽  
Styrene Content ◽  
Styrene Butadiene ◽  
Kinetics Of

Abstract The effect of curing additives on the dispersion kinetics of carbon black (CB) in styrene butadiene rubber (SBR) compounds was investigated by means of the method of the online measured electrical conductance. Addition of curing additives such as stearic acid and diphenylguanidine (DPG) accelerates the CB dispersion process significantly. The viscosity of the rubber matrix was not changed after their addition. The addition of stearic acid and DPG may alter the filler–filler interaction that consequently leads to faster dispersion processes. The obtained difference in morphologies of SBR mixtures containing stearic acid and DPG, respectively, are caused by their different infiltration behavior, which may lead to different dispersion mechanisms. Addition of ZnO could not improve the dispersion process of CB because of its limited interaction with CB. Sulfur and N-cyclohexylbenzothiazole-2-sulfenamide decelerate the CB dispersion process. The strong effect of the rubber microstructure such as styrene content and molecular weight on the CB dispersion in SBR mixtures without additives was found and discussed by taking into consideration the known dispersion mechanisms. The influence of addition of curing additives on the CB dispersion in low styrene-content SBR mixtures is much more pronounced than that in high styrene-content SBR mixtures.

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