New Antiozonants for Rubber Compounds Based on Oxyalkylated Derivatives of 4-Aminodiphenylamine

2017 ◽  
Vol 44 (11) ◽  
pp. 29-36 ◽  
Author(s):  
N.F. Ushmarin ◽  
S.M. Kavun

This paper sets out the properties and the results of the testing of new antiozonants 2PPD and 3PPD in place of standard and imported 6PPD and IPPD which are used in the production of mechanical rubber goods and tyres (in the sidewall, tread, and other elements). The proposed method for producing the new antiozonants makes it possible to organise their industrial production by low-cost technology, in contrast to 6PPD and IPPD production technology. The raw materials for the new antiozonants include ethylene and propylene glycols, available in Russia, and 4-aminodiphenylamine, imported for the production in Russia of antioxidant S789, which is widely used in the production of large-tonnage rubbers, in particular synthetic isoprene rubber SKI-3, over 70% of the volume of which is exported. A number of advantages of 3PPD over imported stabilisers have been established. These include a greater effectiveness in protecting rubber compounds against thermal oxidation and ozone cracking by comparison with the stabilisers it is replacing. The shortcomings of the new antiozonant (in terms of the form in which it is produced and in terms of its influence on the vulcanisation kinetics) are considered, and various ways to overcome these shortcomings are presented.

Author(s):  
Rena E. Mustafaeva

The work is devoted to the search for new effective modifying additives that allow to purposefully regulate the technological properties of rubber compounds and physical-mechanical properties of rubbers based on combinations of non-polar rubbers and at the same time being cheaper and more affordable than traditional products, in particular, with resorcinol-urotropin complex (modifier RU -1). It was proposed to use as a modifier of frame rubbers based on a combination of isoprene (SKI-3) and butadiene-styrene (SCS-30ARKM-15) rubbers, chlorinated atactic polypropylene (CHAPP). It is shown that when the RU-1 modifier is replaced with this compound, the conditional stresses and tensile strength, tearing resistance, rebound elasticity, fatigue resistance in the regime of constant deformation amplitude, heat resistance, resistance to thermal aging of rubbers, as well as the strength of rubber bonding with rubber Textile cord, including at elevated temperatures are observed. Comparison of the CHAPP for the effectiveness of the action in the carcass gum with the previously proposed oligoefirmetacrylate epichlorhydrine, from the point of view of the provided complex of properties, showed the advantage of chlorinated atactic polypropylene for a number of priority indicators. From the comparative analysis of the modifying activity of chlorinated atactic polypropylene and oligoether methacrylate epichlorohydrin, it follows that the vulcanizates of rubber compounds containing instead of RU-1 chlorinated atactic polypropylene CHAPP are characterized by more improved parameters of hardness in TM-2, elasticity by rebound, the strength of the rubber-cord connection. It is also revealed that the main advantage of the proposed modifier is the low cost of the modifier used, as well as the use of secondary raw materials for its production.Forcitation:Mustafayeva R.E. Technological aspects of production and research of polymers composite materials with increased strength. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 10. P. 82-86


2018 ◽  
Vol 39 (3) ◽  
pp. 126 ◽  
Author(s):  
Marina Donova

Structural modification of steroids by microorganisms, known since the 1950s, is nowadays a base for industrial production of many steroid hormones and their high-value precursors. Phytosterols, renewable biomaterials of plant origin, are recognised now as most attractive, low-cost and available raw materials for the pharmaceutical industry.


2013 ◽  
Vol 690-693 ◽  
pp. 1057-1060
Author(s):  
Jian Hai Guo ◽  
Jun Yan Huang ◽  
Xin Sun ◽  
Shuang Ling Wu ◽  
Jie Ma

The paper wooden compound pallets are produced through the processing and assembly by using particle board, paper tubes and PE coated paper board as raw materials. Comparing with traditional wooden flat plate, the new type of green environmental protection pallets has many advantages such as high strength, light weight, low cost, waterproof, anti-moth-eaten, no need fumigation, etc. is an ideal green transport packaging materials for export commodities. The paper discusses and probes into the process and technology of paper wooden compound pallets.


2020 ◽  
Vol 4 (1) ◽  
pp. 41-48
Author(s):  
Teodoro Astorga Amatosa ◽  
Michael E. Loretero

Bamboo is a lightweight and high-strength raw materials that encouraged researchers to investigate and explore, especially in the field of biocomposite and declared as one of the green-technology on the environment as fully accountable as eco-products. This research was to assess the technical feasibility of making single-layer experimental Medium-Density Particleboard panels from the bamboo waste of a three-year-old (Dendrocalamus asper). Waste materials were performed to produce composite materials using epoxy resin (C21H25C105) from a natural treatment by soaking with an average of pH 7.6 level of sea-water. Three different types of MDP produced, i.e., bamboo waste strip MDP (SMDP), bamboo waste chips MDP (CMDP) and bamboo waste mixed strip-chips MDP (MMDP) by following the same process. The experimental panels tested for their physical-mechanical properties according to the procedures defined by ASTM D1037-12. Conclusively, even the present study shows properties of MDP with higher and comparable to other composite materials; further research must be given better attention as potential substitute to be used as hardwood materials, especially in the production, design, and construction usage.


2019 ◽  
Author(s):  
Yu Wang ◽  
Nachuan Yang ◽  
Yi Shuai ◽  
Yunpeng Zhang ◽  
Kanghua Chen

2014 ◽  
Vol 580-583 ◽  
pp. 2262-2265
Author(s):  
Yu Hong Zhao

Prefabricated buildings have the advantages of convenient construction, low cost, energy saving and environmental protection, etc., it is suitable for industrial production of buildings, lifting and connections of prefabricated components are key to construct the prefabricated buildings.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2910
Author(s):  
Chaoyi Ding ◽  
Chun Liu ◽  
Ligang Zhang ◽  
Di Wu ◽  
Libin Liu

The high cost of development and raw materials have been obstacles to the widespread use of titanium alloys. In the present study, the high-throughput experimental method of diffusion couple combined with CALPHAD calculation was used to design and prepare the low-cost and high-strength Ti-Al-Cr system titanium alloy. The results showed that ultra-fine α phase was obtained in Ti-6Al-10.9Cr alloy designed through the pseudo-spinodal mechanism, and it has a high yield strength of 1437 ± 7 MPa. Furthermore, application of the 3D strength model of Ti-6Al-xCr alloy showed that the strength of the alloy depended on the volume fraction and thickness of the α phase. The large number of α/β interfaces produced by ultra-fine α phase greatly improved the strength of the alloy but limited its ductility. Thus, we have demonstrated that the pseudo-spinodal mechanism combined with high-throughput diffusion couple technology and CALPHAD was an efficient method to design low-cost and high-strength titanium alloys.


2021 ◽  
Author(s):  
Junzhen Ren ◽  
Pengqing Bi ◽  
Jianqi Zhang ◽  
Jiao Liu ◽  
Jingwen Wang ◽  
...  

Abstract Developing photovoltaic materials with simple chemical structures and easy synthesis still remains a major challenge in the industrialization process of organic solar cells (OSCs). Herein, an ester substituted poly(thiophene vinylene) derivative, PTVT-T, was designed and synthesized in very few steps by adopting commercially available raw materials. The ester groups on the thiophene units enable PTVT-T to have a planar and stable conformation. Moreover, PTVT-T presents a wide absorption band and strong aggregation effect in solution, which are the key characteristics needed to realize high performance in non-fullerene-acceptor (NFA)-based OSCs. We then prepared OSCs by blending PTVT-T with three representative fullerene- and NF-based acceptors, PC71BM, IT-4F and BTP-eC9. It was found that PTVT-T can work well with all the acceptors, showing great potential to match new emerging NFAs. Particularly, a remarkable power conversion efficiency of 16.20% is achieved in a PTVT-T:BTP-eC9-based device, which is the highest value among the counterparts based on PTV derivatives. This work demonstrates that PTVT-T shows great potential for the future commercialization of OSCs.


Sign in / Sign up

Export Citation Format

Share Document