Synthesis, characterization, theoretical investigations and fluorescent sensing behavior of oligomeric azine-based Fe3+Chemosensors

2021 ◽  
pp. 095400832110556
Author(s):  
Subramani Manigandan ◽  
Athianna Muthusamy ◽  
Raju Nandhakumar ◽  
Charles Immanuel David ◽  
Siddeswaran Anand
Keyword(s):  
Electrical Conductivity ◽  
Metal Ion ◽  
Fluorescent Sensing ◽  
Electrical Studies ◽  
Imine Nitrogen ◽  
Basic Set ◽  
Theoretical Investigations ◽  
Different Temperatures ◽  
Density Values ◽  
High Dielectric

Three azine oligomeric esters were synthesized, characterized by IR, UV, 1H, 13C{1H} and GPC technique, and applied to chemosensor application. The sensitivity response of the oligomers towards the metal ion was evaluated for a metal ion series. The results have shown selective and sensitive “turn off” fluorescence response towards Fe3+ ion in DMF/H2O (1:1, pH: 7.4, fluorophore: 5 μM) solution. The binding stoichiometry and binding constant of the fluorophores were calculated using the Stern–Volmer equation and Benesi–Hildebrand plots, respectively. The quenching of fluorophores on the addition of Fe3+ ion indicates the capability of fluorophore towards quantitative analysis of Fe3+. The dimer of oligomers was theoretically studied using DFT, B3LYP/6-311G level basic set to support and explain the quenching mechanism of LMCT, PET process and to explain the DC, AC electrical studies results. The electrical conductivity measurements of solid-state, I2 doped and undoped oligomers were carried out and the conductivity gradually increases with increase in iodine vapor contact time of oligomers. The electrical conductivity was related with band gap and charge density values of imine nitrogen obtained by Huckel calculations. The dielectric measurements at different temperatures and frequencies were made by two probe method. Among the oligomers, EBHAP has recorded a high dielectric constant at the low applied frequency of 50 Hz at 373 K due to loosely attached π bonds resulting good polarization.

scholarly journals A multicolor and ratiometric fluorescent sensing platform for metal ions based on arene–metal-ion contact

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Anna Kanegae ◽  
Yusuke Takata ◽  
Ippei Takashima ◽  
Shohei Uchinomiya ◽  
Ryosuke Kawagoe ◽  
...  
Keyword(s):  
Metal Ions ◽  
Metal Ion ◽  
Near Infrared ◽  
Molecular Design ◽  
Theoretical Calculations ◽  
Probe Design ◽  
One Pot ◽  
Fluorescent Sensing ◽  
Sensing Platform ◽  
Ratiometric Detection

AbstractDespite continuous and active development of fluorescent metal-ion probes, their molecular design for ratiometric detection is restricted by the limited choice of available sensing mechanisms. Here we present a multicolor and ratiometric fluorescent sensing platform for metal ions based on the interaction between the metal ion and the aromatic ring of a fluorophore (arene–metal-ion, AM, coordination). Our molecular design provided the probes possessing a 1,9-bis(2′-pyridyl)-2,5,8-triazanonane as a flexible metal ion binding unit attached to a tricyclic fluorophore. This architecture allows to sense various metal ions, such as Zn(II), Cu(II), Cd(II), Ag(I), and Hg(II) with emission red-shifts. We showed that this probe design is applicable to a series of tricyclic fluorophores, which allow ratiometric detection of the metal ions from the blue to the near-infrared wavelengths. X-ray crystallography and theoretical calculations indicate that the coordinated metal ion has van der Waals contact with the fluorophore, perturbing the dye’s electronic structure and ring conformation to induce the emission red-shift. A set of the probes was useful for the differential sensing of eight metal ions in a one-pot single titration via principal component analysis. We also demonstrate that a xanthene fluorophore is applicable to the ratiometric imaging of metal ions under live-cell conditions.

scholarly journals A Personal Journey across Fluorescent Sensing and Logic Associated with Polymers of Various Kinds

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1351 ◽  
Author(s):  
Chao-Yi Yao ◽  
Seiichi Uchiyama ◽  
A. Prasanna de Silva
Keyword(s):  
Phase Separation ◽  
Metal Ion ◽  
Chemical Species ◽  
Polymer Science ◽  
Molecular Sensing ◽  
Fluorescent Sensing ◽  
Molecular Logic ◽  
Fluorescent Molecular Sensing ◽  
Molecular Scale ◽  
Identification Tags

Our experiences concerning fluorescent molecular sensing and logic devices and their intersections with polymer science are the foci of this brief review. Proton-, metal ion- and polarity-responsive cases of these devices are placed in polymeric micro- or nano-environments, some of which involve phase separation. This leads to mapping of chemical species on the nanoscale. These devices also take advantage of thermal properties of some polymers in water in order to reincarnate themselves as thermometers. When the phase separation leads to particles, the latter can be labelled with identification tags based on molecular logic. Such particles also give rise to reusable sensors, although molecular-scale resolution is sacrificed in the process. Polymeric nano-environments also help to organize rather complex molecular logic systems from their simple components. Overall, our little experiences suggest that researchers in sensing and logic would benefit if they assimilate polymer concepts.

scholarly journals ELECTRICAL CONDUCTIVITY AND QUALITY OF DIFFERENT UMBEL ORDER CARROT SEEDS

2020 ◽  
Vol 9 (04) ◽  
pp. 75-81
Author(s):  
Luana de Souza Marinke ◽  
Hugo César Rodrigues Moreira Catão ◽  
Gabrielly Fernanda Francisco ◽  
Ítala Menegon Castilho ◽  
Letícia Rodrigues de Oliveira ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Germination Rate ◽  
Statistical Design ◽  
Germination Test ◽  
Aerial Portion ◽  
Initial Characterization ◽  
Different Temperatures ◽  
Physiological Quality ◽  
Final Score

Carrot seeds exhibit irregular vigor due to the wide blooming period of the crop. Results from germination tests are insufficient to evaluate the physiological potential. Thus, vigor tests are used in combination with germination tests. The objective of this work was to evaluate the quality of carrot seeds from different umbel order and the electrical conductivity under different temperatures and imbibing periods. Carrot seeds from cultivar Brasilia were used to perform the experiments. Content of water, the first and the final score of the germination test, index of germination rate, and length of roots and of the aerial portion were determined in the initial characterization. The electrical conductivity test was completed with replicates containing 50 seeds, in 25 mL deionized water at 20, 25 and 30oC. Evaluations were performed with 2, 4, 6, 8, 12 and 24 hours of imbibing period. The experiment was accomplished under a completely random statistical design. The quality of carrot seeds varied according to the umbel order. Seeds of secondary umbels showed better physiological quality. The electrical conductivity test is efficient to evaluate the vigor of carrot seeds with 8 hours of imbibing period at 25°C.

Two isostructural linear coordination polymers: the size of the metal ion impacts the electrical conductivity

2018 ◽  
Vol 42 (12) ◽  
pp. 10309-10316 ◽  
Author(s):  
Basudeb Dutta ◽  
Arka Dey ◽  
Kaushik Naskar ◽  
Suvendu Maity ◽  
Faruk Ahmed ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Metal Ions ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Linear Coordination

Electrical conductivity was tuned by altering the metal ions in acetylenedicarboxylate (adc) and 4-styrylpyridine (4-spy)-based 1D coordination polymers, {[M(adc)(4-spy)2(H2O)2]}n (M = Zn and Cd).

scholarly journals CNT Reinforced Silver Nanocomposites: Mechanical and Electrical Studies

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Dinesh Kumar ◽  
Sonia Nain ◽  
Neena ◽  
Hemant Pal ◽  
Ravi Kumar
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Elastic Modulus ◽  
Multiwalled Carbon Nanotubes ◽  
Multiwalled Carbon ◽  
Electrical Studies ◽  
Silver Nanocomposites ◽  
Silver Matrix ◽  
Nanoindentation Hardness

Nanoindentation hardness and elastic modulus of the silver/MWCNT (multiwalled carbon nanotubes) composites, fabricated by modified wet mixing technique, are studied in the present work. CNT reinforced silver nanocomposites, fabricated by introducing 4.5 volume percentages of CNT in the silver matrix, have increased elastic modulus and approximately 50% higher hardness than pure nanosilver. It is also observed from the results that the electrical conductivity of the fabricated materials was decreased by increasing the CNTs volume %.

Methodology for Measurement of Density of Liquid Oxides

2020 ◽  
Vol 7 (2) ◽  
Author(s):  
Jan Hrbek ◽  
Bence Mészáros ◽  
Mykhaylo Paukov ◽  
Martin Kudláč
Keyword(s):  
High Temperature ◽  
Temperature Dependence ◽  
Extreme Conditions ◽  
Nuclear Accidents ◽  
System A ◽  
Different Temperatures ◽  
Density Values ◽  
Properties Of Materials ◽  
The Difference

Abstract Measurement of physical properties of materials in extreme conditions, such as high temperature, is limited by technological challenges. Nevertheless, modeling of several phenomena relies on the existence of experimental data for their validation. In this study, a method suitable for determination of density in a liquid phase at high temperature is proposed and tested on Al2O3–ZrO2 system. A methodology for acquiring the temperature dependence of density for radioactive materials is proposed and is aimed to refine severe nuclear accidents modeling. The oxide was melted in an induction furnace with a cold crucible. The measurement was based on evaluation of the volume of the melt at different temperatures, in a range from 2100 to 2400 °C. The densities of the oxide in the solid-state and the skull-layer were measured using a pycnometer. A temperature dependence of the density was established and the results were compared with literature. The difference between existing data and the measured values in this work was less than 5%. Thus, the proposed methodology provides reliable density values in extreme conditions.

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