Exploiting a new europium(III) coordination polymer based on a zwitterionic ligand as a fluorescent probe for uranyl cations

Two new isostructural lanthanide(III) coordination polymers based on an unreported zwitterionic ligand, namely, [Ln(ox)(L)]n (ox = oxalate, HL = N,N'-dipropionic acid imidazolium, Ln = Eu or La), are synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared spectroscopy, powder X-ray diffraction, and thermogravimetric analysis. The fluorescence properties of the europium coordination polymer are investigated. In addition, the europium-based coordination polymer is utilized for specific sensing of UO22+ ions, showing high selectivity, a fast response time (8 min) and high sensitivity with noticeable quenching ( Ksv = 6.19 × 104 M−1) and limit of detection of 1.95 µM.

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A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

Zeitschrift für Naturforschung B ◽

10.1515/znb-2017-0104 ◽

2017 ◽

Vol 72 (12) ◽

pp. 937-940 ◽

Cited By ~ 1

Author(s):

Xiao-Hong Zhu ◽

Xiao-Chun Cheng ◽

Yun-Hua Qian

Keyword(s):

Magnetic Properties ◽

Infrared Spectroscopy ◽

Coordination Polymer ◽

Single Crystal ◽

Structural Characterization ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

Thermogravimetric Analyses ◽

X Ray ◽

3D Framework

AbstractThe neutral, four-fold protonated pyridine-3,5-dicarbox(3,5-dicarboxylatoanilide) (H4L) reacts with Mn(II) salts under hydrothermal conditions to yield a new complex: [Mn2(L)(H2O)2]·H2O (1), which has been characterized by single crystal X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 3D framework with flu (412.612.84)(46)2 topology. The magnetic properties of 1 were investigated.

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Selective and Recyclable Sensing of Aqueous Phase 2,4,6-Trinitrophenol (TNP) Based on Cd(II) Coordination Polymer with Zwitterionic Ligand

Crystals ◽

10.3390/cryst8120456 ◽

2018 ◽

Vol 8 (12) ◽

pp. 456 ◽

Cited By ~ 3

Author(s):

Kaimin Wang ◽

Huaijun Tang ◽

Donghua Zhang ◽

Yulu Ma ◽

Yuna Wang

Keyword(s):

Thermogravimetric Analysis ◽

Coordination Polymer ◽

Infrared Spectrum ◽

Aqueous Phase ◽

Organic Ligand ◽

Luminescent Material ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

X Ray ◽

First Case

A novel coordination polymer, {[Cd4(Dccbp)4]·H2O} (1) (Dccbp = 3,5-dicarboxy-1-(3-carboxybenzyl)pyridin-1-ium) was synthesized under hydrothermal conditions by a zwitterionic organic ligand and characterized by single crystal X-ray diffraction, infrared spectrum (IR), thermogravimetric analysis (TG), powder X-ray diffraction (PXRD) and luminescence. Complex 1 with a pyridine cation basic skeleton has the potential to serve as the first case of a luminescent material based on the zwitterionic type of organic ligand for selective, sensitive, and recyclable sensing of 2,4,6-trinitrophenol in the aqueous phase.

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Synthesis and structural characterization of a Ni(II) coordination polymer with a tripodal 4-imidazolyl-functional ligand

Zeitschrift für Naturforschung B ◽

10.1515/znb-2019-0137 ◽

2019 ◽

Vol 74 (11-12) ◽

pp. 857-860

Author(s):

Hai-Wei Kuai ◽

Xiao-Hong Zhu ◽

Ding-Yun Jiang ◽

Xiao-Chun Cheng ◽

Deng-Hao Li

Keyword(s):

Infrared Spectroscopy ◽

Coordination Polymer ◽

Single Crystal ◽

Network Structure ◽

Structural Characterization ◽

Monoclinic Space Group ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

X Ray

Abstract1,3,5-Tri(1H-imidazol-4-yl)benzene (H3L) reacts with Ni(ClO4)2 · 6H2O under hydrothermal conditions at T = 100°C to yield a new complex: [Ni(H2L)2] · 5.5H2O (1). The product is characterized by single crystal and powder X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 crystallizes in the monoclinic space group C2/c and exhibits a binodal (3,6)-connected 2D kgd network structure with (43)2(46.66.83) topology.

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A 2-D Zn(II) coordination polymer based on 4,5-imidazoledicarboxylate and bis(benzimidazole) ligands: synthesis, crystal structure and fluorescence properties

Zeitschrift für Naturforschung B ◽

10.1515/znb-2021-0003 ◽

2021 ◽

Vol 0 (0) ◽

Author(s):

Xinzhao Xia ◽

Lixian Xia ◽

Geng Zhang ◽

Yuxuan Jiang ◽

Fugang Sun ◽

...

Keyword(s):

Crystal Structure ◽

Coordination Polymer ◽

Zigzag Chain ◽

Supramolecular Framework ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

Hydrogen Bond Interaction ◽

X Ray ◽

New Type ◽

Solid State Fluorescence

Abstract In this work, a new type of zinc(II) coordination polymer {[Zn(HIDC)(BBM)0.5]·H2O} n (Zn-CP) was synthesized using 4,5-imidazoledicarboxylic acid (H3IDC) and 2,2-(1,4-butanediyl)bis-1,3-benzimidazole (BBM) under hydrothermal conditions. Its structure has been characterized by infrared spectroscopy, elemental analysis and single crystal X-ray diffraction analysis. The Zn(II) ion is linked by the HIDC2− ligand to form a zigzag chain by chelating and bridging, and then linked by BBM to form a layered network structure. Adjacent layers are further connected by hydrogen bond interaction to form a 3-D supramolecular framework. The solid-state fluorescence performance of Zn-CP shows that compared with free H3IDC ligand, its fluorescence intensity is significantly enhanced.

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Valorization of Byproducts of Hemp Multipurpose Crop: Short Non-Aligned Bast Fibers as a Source of Nanocellulose

Molecules ◽

10.3390/molecules26164723 ◽

2021 ◽

Vol 26 (16) ◽

pp. 4723

Author(s):

Sara Dalle Vacche ◽

Vijayaletchumy Karunakaran ◽

Alessia Patrucco ◽

Marina Zoccola ◽

Loreleï Douard ◽

...

Keyword(s):

Infrared Spectroscopy ◽

Thermogravimetric Analysis ◽

Cannabis Sativa ◽

Crystallinity Index ◽

Residual Lignin ◽

Chemical Pretreatment ◽

X Ray Diffraction ◽

X Ray ◽

Bast Fibers ◽

Seed Maturity

Nanocellulose was extracted from short bast fibers, from hemp (Cannabis sativa L.) plants harvested at seed maturity, non-retted, and mechanically decorticated in a defibering apparatus, giving non-aligned fibers. A chemical pretreatment with NaOH and HCl allowed the removal of most of the non-cellulosic components of the fibers. No bleaching was performed. The chemically pretreated fibers were then refined in a beater and treated with a cellulase enzyme, followed by mechanical defibrillation in an ultrafine friction grinder. The fibers were characterized by microscopy, infrared spectroscopy, thermogravimetric analysis and X-ray diffraction after each step of the process to understand the evolution of their morphology and composition. The obtained nanocellulose suspension was composed of short nanofibrils with widths of 5–12 nm, stacks of nanofibrils with widths of 20–200 nm, and some larger fibers. The crystallinity index was found to increase from 74% for the raw fibers to 80% for the nanocellulose. The nanocellulose retained a yellowish color, indicating the presence of some residual lignin. The properties of the nanopaper prepared with the hemp nanocellulose were similar to those of nanopapers prepared with wood pulp-derived rod-like nanofibrils.

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Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer [Co3(bpd)5.5(NCS)6(NH3)]n⋅2H2O(bpd= 1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene)

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.803.80 ◽

2013 ◽

Vol 803 ◽

pp. 80-84

Author(s):

Yu Qi Liu ◽

Yong Yang ◽

Rui Yang ◽

Xiao Jun Xu

Keyword(s):

Crystal Structure ◽

Infrared Spectroscopy ◽

Coordination Polymer ◽

Single Crystal ◽

X Ray Diffraction ◽

Synthesis And Crystal Structure ◽

X Ray ◽

Elemental Analyses ◽

Ligand Coordination ◽

Point Symbol

A novel metalorganic coordination polymer, namely [Co3(bpd)5.5(NCS)6(NH3)]n2H2O (1) (bpd=1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene), has been synthesized and characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Compound 1 presents 2D[3,4,-connected 3-nodal net with the point symbol (4268210)(4462)(8210). In addition, four identical 2D single nets is interlocked with each other in parallel, thus directly leading to the formation of a polycatenated layer (2D2D).

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Synthesis, crystal structure and properties of a 2-D Cd(II) coordination polymer based on ferrocenecarboxylate and 4,4′-bipyridine ligands

Zeitschrift für Naturforschung B ◽

10.1515/znb-2021-0171 ◽

2021 ◽

Vol 0 (0) ◽

Author(s):

Kai-Long Zhong ◽

Jing Quan ◽

Xian-Xiao Pan ◽

Wei Song ◽

Bing-Feng Li

Keyword(s):

Coordination Polymer ◽

Gravimetric Analysis ◽

Structure And Properties ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

X Ray ◽

Carboxylate Oxygen ◽

Oxygen Chain ◽

Crystal Structural

Abstract A new cadmium(II)-based coordination polymer [Cd3(FcCOO)6(4,4′-bipy)(H2O)2] n (FcCOO = ferrocenecarboxylato and 4,4′-bipy = 4,4′-bipyridine) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The results of a crystal structural analysis has revealed that the title compound consists of two crystallographically unique CdII centers, one in a general position with a five-coordinated and one on an inversion center with a six-coordinated environment. The CdII centers are connected by FcCOO− units to form a metal carboxylate oxygen chain extending parallel to the [100] direction while the 4,4′-bipy ligands further act as bridging linkers of the CdII centers resulting in a layered polymer. In addition, an X-ray powder diffraction and thermal gravimetric analysis and a cyclo-voltammetric characterization of the complex have also been carried out.

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Synthesis, Structure and Properties of Two-Dimensional Coordination Polymer Based on 3,5-di(benzimidazol-1-yl)pyridine

Journal of the chemical society of pakistan ◽

10.52568/000634 ◽

2020 ◽

Vol 42 (2) ◽

pp. 249-249

Author(s):

Guo Jun Wu Guo Jun Wu

Keyword(s):

Infrared Spectroscopy ◽

Coordination Polymer ◽

Single Crystal ◽

Photocatalytic Degradation ◽

Elemental Analysis ◽

Solvothermal Reaction ◽

Two Dimensional ◽

Structure And Properties ◽

X Ray Diffraction ◽

X Ray

[Cu(L)(AIP)·1.5H2O]n (1) [L= 3,5-di(benzimidazol-1-yl)pyridine, H2AIP= 5-aminoisophthalic acid] was prepared by the solvothermal reaction, which was characterized by single-crystal X–ray diffraction, infrared spectroscopy, and elemental analysis. 1 exhibits an infinite two dimensional [Cu(AIP)]n sheet parallel to (0 1 1) crystal plane. Furthermore, complex 1 displays good photocatalytic degradation of methyl blue (MB).

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Coordination Assemblies of Zn(II) Coordination Polymers: Positional Isomeric Effect and Optical Properties

Crystals ◽

10.3390/cryst9120664 ◽

2019 ◽

Vol 9 (12) ◽

pp. 664 ◽

Cited By ~ 3

Author(s):

Chang-Jie Liu ◽

Tong-Tong Zhang ◽

Wei-Dong Li ◽

Yuan-Yuan Wang ◽

Shui-Sheng Chen

Keyword(s):

Optical Properties ◽

Infrared Spectroscopy ◽

Thermogravimetric Analysis ◽

Quantum Yield ◽

Coordination Polymers ◽

Square Lattice ◽

X Ray Diffraction ◽

X Ray ◽

Mixed Ligands ◽

Isomeric Effect

Two Zn(II) coordination polymers (CPs) [Zn(L)(pphda)] (1) and [Zn(L)(ophda)]·H2O (2) were prepared by reactions of ZnSO4·7H2O based on the N-donor 1,4-di(1H-imidazol-4-yl)benzene (L) ligand and two flexible carboxylic acids isomers of 1,4-phenylenediacetic acid (H2pphda) and 1,2-phenylenediacetic acid (H2ophda) as mixed ligands, respectively. Structures of CPs 1 and 2 were characterized by elemental analysis, Infrared spectroscopy (IR), thermogravimetric analysis and single-crystal X-ray diffraction. The CP 1 is a fourfold interpenetrating 66-diamond (dia) architecture, while 2 is a 2D (4, 4) square lattice (sql) layer based on the Zn2(cis-1,2-ophda2−)2 binuclear Zn(II) subunits. The luminescent property, including luminescence lifetime and quantum yield (QY), have been investigated for CPs 1 and 2.

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Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid

Molecules ◽

10.3390/molecules24244431 ◽

2019 ◽

Vol 24 (24) ◽

pp. 4431 ◽

Cited By ~ 1

Author(s):

Lingshu Meng ◽

Lun Zhao ◽

Guanlin Guo ◽

Xin Liu ◽

Zhijun Liang ◽

...

Keyword(s):

Acetic Acid ◽

Thermogravimetric Analysis ◽

Coordination Polymers ◽

Electrochemical Behavior ◽

Room Temperature ◽

X Ray Diffraction ◽

Hydrothermal Conditions ◽

X Ray ◽

Hexadentate Ligand ◽

Xrd Techniques

In this study, three new 3D coordination polymers (CPs), {[Cd3(L)(H2O)6]·H2O}n (1), {[Cu1.5(L)0.5(bimb)1.5]·5H2O·DMF}n (2), and {[Mn1.5(H3L)(bibp)0.5(H2O)2]·3H2O}n (3) (bimb= 1,3-bis(imidazol-1-yl)benzene, bibp= 1,4-bis((4-imidazol-1-yl)benzyl)piperazine), were prepared under solvothermal or hydrothermal conditions based on a hexadentate ligand (1,3,5-triazine-2,4,6-triamine hexa-acetic acid (H6L)). Structural elucidations were carried out by IR spectra along with single-crystal X-ray diffraction analysis, while thermogravimetric analysis (TGA) (dynamic and isothermal) and XRD techniques were used for property evaluations of the polymers. Furthermore, the fluorescence properties and detection of the Fe3+ ions in 1 were tested at room temperature, and the electrochemical behavior of 2 is also stated in this article.

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