scholarly journals Composition and Variability of Leaf Oil from Monodora Crispata -13C NMR Identification of Heat-sensitive Compounds

2017 ◽  
Vol 12 (3) ◽  
pp. 1934578X1701200
Author(s):  
Tra Marc Gabin Djié Bi ◽  
Acafou Thierry Yapi ◽  
Zana Adama Ouattara ◽  
Janat Akhanovna Mamyrbekova-Békro ◽  
Mathieu Paoli ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Two Samples ◽  
Sesquiterpene Hydrocarbons ◽  
Germacrene D ◽  
Fourth Sample ◽  
Leaf Oil ◽  
Nmr Techniques ◽  
Main Components ◽  
Nmr Identification ◽  
C Nmr

The composition of four samples of essential oil isolated from the leaves of individual Monodora crispata trees growing wild in an Ivorian forest (Adiopodoumé) were investigated by a combination of chromatographic (GC(RI)) and spectrometric (GC-MS, 13C NMR) techniques. In total, fifty-seven compounds accounting for 92.3–98.7% of the whole composition were identified. These oils were characterized by the preeminence of sesquiterpene hydrocarbons and the content of the main components varied substantially from sample to sample. Two samples were largely dominated by germacrene D (67.3% and 76.3%, respectively), a third sample was represented by germacrene D (28.3%), germacrene C (14.3%), δ-elemene (12.1%) and β-elemene (9.3%) and the fourth sample was characterized by 3-dimethylallylindole (15.1%), germacrene D (12.0%) and cyperene (7.8%). 13C NMR spectroscopy was particularly efficient for the identification of heat-sensitive compounds.

scholarly journals Composition and Chemical Variability of Ivoirian Xylopia staudtii Leaf Oil

2015 ◽  
Vol 10 (6) ◽  
pp. 1934578X1501000
Author(s):  
Thierry Acafou Yapi ◽  
Jean Brice Boti ◽  
Antoine Coffy Ahibo ◽  
Sylvain Sutour ◽  
Ange Bighelli ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Nmr Spectroscopy ◽  
Essential Oils ◽  
Oil Composition ◽  
Chemical Variability ◽  
Germacrene D ◽  
Leaf Oil ◽  
Nmr Techniques ◽  
C Nmr

The chemical composition of a leaf oil sample from Ivoirian Xylopia staudtii Engler & Diels (Annonaceae) has been investigated by a combination of chromatographic [GC(RI)] and spectroscopic (GC-MS, 13C NMR) techniques. Thirty-five components that accounted for 91.8% of the whole composition have been identified. The oil composition was dominated by the furanoguaiadienes furanoguaia-1,4-diene (39.0%) and furanoguaia-1,3-diene (7.5%), and by germacrene D (17.5%). The composition of twelve other leaf oil samples demonstrated qualitative homogeneity, but quantitative variability. Indeed, the contents of the major components varied substantially: furanoguaia-1,4-diene (24.7–51.7%) and germacrene D (5.9–24.8%). The composition of X. staudtii leaf oil is close to that of X. rubescens leaf oil but varied drastically from those of the essential oils isolated from other Xylopia species. 13C NMR spectroscopy appeared as a powerful and complementary tool for analysis of sesquiterpene-rich essential oils.

scholarly journals Chemical Composition and Variability of Leaf and Berry oils from Corsican Juniperus macrocarpa

2018 ◽  
Vol 13 (2) ◽  
pp. 1934578X1801300
Author(s):  
Joséphine Ottavioli ◽  
Ange Bighelli ◽  
Joseph Casanova ◽  
Félix Tomi
Keyword(s):  
Principal Component Analysis ◽  
Statistical Analysis ◽  
Chemical Composition ◽  
Principal Component ◽  
Component Analysis ◽  
Germacrene D ◽  
Leaf Oil ◽  
Main Components ◽  
Main Component ◽  
C Nmr

The chemical composition of five leaf oil samples and eighteen berry oil samples from Corsican Juniperus macrocarpa have been investigated by GC(RI), GC-MS and 13C NMR. The composition of berry oils was dominated by monoterpene hydrocarbons with α-pinene (56.4-78.9%) as main component followed by myrcene (2.2-11.9%). Germacrene D (4.5-103%) was the major sesquiterpene. The contents of the main components of leaf oils varied drastically from sample to sample: α-pinene (28.7-76.4%), δ3-carene (up to 17.3%), β-phellandrene (up to 12.3%), manoyl oxide (up to 8.1%). The occurrence of the unusual ( Z)-pentadec-6-en-2-one (0.1-1.2%) should be pointed out. Statistical analysis (Principal Component Analysis and k- means partition) suggested a unique group with atypical samples.

scholarly journals Combined Analysis of the Root Bark Oil of Cleistopholis glauca by Chromatographic and Spectroscopic Techniques

2013 ◽  
Vol 8 (12) ◽  
pp. 1934578X1300801 ◽  
Author(s):  
Zana A. Ouattara ◽  
Jean Brice Boti ◽  
Coffy Antoine Ahibo ◽  
Félix Tomi ◽  
Joseph Casanova ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Silica Gel ◽  
Ivory Coast ◽  
Retention Indices ◽  
Spectroscopic Techniques ◽  
Root Bark ◽  
Oxygenated Compounds ◽  
Germacrene D ◽  
Main Components ◽  
C Nmr

The composition of root bark oil from Cleistopholis glauca Pierre ex Engler & Diels growing wild in Ivory Coast was investigated by GC (in combination with retention indices) and 13C NMR spectroscopy after partition of hydrocarbons and oxygenated compounds on silica gel. Thirty-one compounds have been identified. C. glauca produces a sesquiterpene-rich oil, patchoulenone (33.5%), cyperene (9.5%) and germacrene D (6.6%) being the main components. Special attention was paid to the identification and quantification of germacrene C (a heat-sensitive compound) and δ-elemene, which were achieved by a combination of GC(FID) and 13C NMR spectroscopy. The composition of C. glauca root bark and leaf oils differed drastically.

scholarly journals Composition of the Essential Oils and Antibacterial Activities of Hymenocrater yazdianus, Stachys obtusicrena and Nepeta asterotricha Three Labiatae Herbs Growing Wild in Iran

2012 ◽  
Vol 7 (1) ◽  
pp. 1934578X1200700 ◽  
Author(s):  
Shiva Masoudi ◽  
Abdolhossein Rustaiyan ◽  
Razieh Mohebat ◽  
Mohammad Hossein Mosslemin
Keyword(s):  
Essential Oils ◽  
Antibacterial Activities ◽  
Gram Negative Bacteria ◽  
Inhibitory Zone ◽  
Growth Inhibitory ◽  
Germacrene D ◽  
Leaf Oil ◽  
Main Components ◽  
Total Oil ◽  
Stem Leaf

Water-distilled essential oils from leaves of Hymenocrater yazdianus Rech.f., flowers of Stachys obtusicrena Boiss., and stems and flowers of Nepeta asterotricha Rech.f, which are endemic to Iran, were analyzed by GC and GC/MS. Fifty-five components of the leaf oil of H. yazdianus were characterized, representing 95.1% of the total components detected. The major constituents were identified as 1,8-cineole (17.6%), β-caryophyllene (13.9%), α-pinene (10.6%) and caryophyllene oxide (10.4%). Germacrene-D (37.5%) and α-bisabolol (23.5%) were the main components among the twenty constituents characterized in the flower oil of S. obtusicrena, representing 90.8% of the total components detected. Thirty-five compounds representing 93.0% of the stem oil of N. asterotrica were identified among which terpinen-4-ol (22.8%) and γ-terpinene (14.1%) were the major ones. The flower oil of the species was characterized by higher amounts of terpinen-4-ol (24.8%), 4aα, 7aβ-nepetalactone (18.2%) and 1,8-cineole (11.6%) among the thirty-three components comprising 98.5% of the total oil detected. The antibacterial activity of the stem, leaf and flower oils of Hymenocrater yazdianus, Stachys obtusicrena and Nepeta asterotricha against seven Gram-positive and Gram-negative bacteria were determined using the MIC method. The growth inhibitory zone (mm) was also measured.

scholarly journals Composition and Antibacterial Activity of Essential Oils from Leaf, Stem and Root of Chrysanthemum parthenium (L.) Bernh. from Iran

2009 ◽  
Vol 4 (6) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Ali Shafaghat ◽  
Hajar Sadeghi ◽  
Khodamali Oji
Keyword(s):  
Escherichia Coli ◽  
Staphylococcus Aureus ◽  
Antibacterial Activity ◽  
Essential Oils ◽  
Salmonella Typhi ◽  
Inhibitory Effects ◽  
Germacrene D ◽  
Leaf Oil ◽  
Main Components ◽  
Microdilution Broth

The water distilled essential oils from leaves, stems and roots of Chrysanthemum parthenium (L.) Bernh. were analyzed by GC and GC/MS methods. The leaf oil was characterized by a high amount of camphor (56.4%), whereas in the stem oil, camphor (26.0%), trans-β-ocimene (23.6%) and germacrene-d (15.0%) were the major constituents. The main components of the root oil were α-pinene (50.0%), trans-β-farnesene (13.8%) and bicyclogermacrene (11.0%). Antibacterial activity of the leaf, stem and root oil were evaluated using the microdilution broth method. The oils showed inhibitory effects on Escherichia coli and Salmonella typhi, but were not active against Staphylococcus aureus.

scholarly journals Comparison of the Essential Oils of Leaves and Stem Bark from Two Different Populations of Drimys Winteri a Chilean Herbal Medicine

2011 ◽  
Vol 6 (6) ◽  
pp. 1934578X1100600 ◽  
Author(s):  
Orlando Muñoz ◽  
Phlippe Christen ◽  
Silvian Cretton ◽  
Alejandro F. Barrero ◽  
Armando Lara ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Herbal Medicine ◽  
Essential Oils ◽  
Stem Bark ◽  
Sesquiterpene Hydrocarbons ◽  
Germacrene D ◽  
Different Populations ◽  
Main Components ◽  
Chemical Groups ◽  
Drimys Winteri

The chemical composition of the essential oils obtained by hydrodistillation of stem bark and leaves of Drimys winteri J.R. et G. Foster var. chilensis /DC A. Gray ( Winteraceae) from Chiloe Island (ID) and Continental Chile (Santiago) (CD) were studied by GC and GC/MS. Sesquiterpene hydrocarbons constituted the main chemical groups in the stem bark oils, with α-santalene, trans-β-bergamotene and curcumenes as the major components. Monoterpenes constituted the main chemical groups in the leaves of Island plants with α-pinene (23.1%) β-pinene (43.6%) and linalool (10.5%) as the main components whereas sesquiterpenes (germacrene D 17.6%) and phenylpropanoids (safrole 20.8%) are the most abundant in the leaves of Continental plants.

scholarly journals Germacranolide Rich Essential Oil from Neolitsea pallens

2007 ◽  
Vol 2 (5) ◽  
pp. 1934578X0700200 ◽  
Author(s):  
Rajendra C. Padalia ◽  
Chandan S. Chanotiya ◽  
Bhawani C. Thakuri ◽  
Chandra S. Mathela
Keyword(s):  
Nmr Spectroscopy ◽  
Essential Oil ◽  
Spectroscopic Data ◽  
Volatile Constituents ◽  
Commercial Importance ◽  
Germacrene D ◽  
Leaf Oil ◽  
Fruit Oil

The composition of the steam volatile constituents of leaf, fruit and bark of Neolitsea pallens (D. Don) syn. Litsea umbrosa var. consimilis Nees Hook f. syn. L. consimilis Nees were analyzed by GC, GC-MS and NMR spectroscopy. The major constituents of the leaf oil were furanogermenone (30.6%), β-caryophyllene (19.3%) and germacrene D (12.7%), while oxygenated sesquiterpenoids (83.6%) constitute the major proportion of the bark oil, which is dominated by furanogermenone (59.1%), germacrone (9.3%), 10- epi-γ-eudesmol (7.8%) and curcumenol (5.3%). The fruit oil was mainly composed of furanogermenone (54.8%), trans-β-ocimene (8.8%), sabinene (6.4%) and germacrene D (4.0%). The major constituents were isolated and characterized on the basis of NMR spectroscopic data. The furano sesquiterpenoids, the major constituents of N. pallens, are of chemosystematic and commercial importance.

scholarly journals Chemical Composition of the Essential Oil from Chaerophyllum Temulum (Apiaceae)

2015 ◽  
Vol 10 (8) ◽  
pp. 1934578X1501000 ◽  
Author(s):  
Jelena G. Stamenković ◽  
Gordana S. Stojanović ◽  
Ivana R. Radojković ◽  
Goran M. Petrović ◽  
Bojan K Zlatković
Keyword(s):  
Chemical Composition ◽  
Essential Oil ◽  
Quantitative Composition ◽  
Qualitative Composition ◽  
Flowering Stage ◽  
Main Compound ◽  
Fruiting Stage ◽  
Sesquiterpene Hydrocarbons ◽  
Germacrene D ◽  
Main Components

The present study reports the chemical composition on the essential oil obtained from fresh roots, stems, inflorescences and fruits of Chaerophyllum temulum. In all samples, except the roots, the most dominant components were sesquiterpene hydrocarbons. ( Z)-Falcarinol was the principal constituent of the root essential oils (61.7% at the flowering stage and 62.3% at the fruiting stage). The blossom oil was dominated by ( Z,E)-α-farnesene (23.4%), ( E)-β-farnesene (9.0%) and germacrene D-4-ol (9%), whereas the oil from the fruit had germacrene D-4-ol (27.6%) as its main compound, accompanied by ( Z,E)-α-farnesene (13.4%). Germacrene D was the most abundant component of the stem essential oil (38.4% at the flowering stage and 32.5% at the fruiting stage). The obtained results show that the qualitative composition of the oil depends on the part of the plant which is analyzed, while the quantitative composition of the main components depends on the growing stage of the plant.

scholarly journals Composition and Antimicrobial Activities of the Leaf Essential Oil of Machilus kusanoi from Taiwan

2011 ◽  
Vol 6 (2) ◽  
pp. 1934578X1100600 ◽  
Author(s):  
Chen-Lung Ho ◽  
Kuang-Ping Hsu ◽  
Yen-Hsueh Tseng ◽  
Eugene I-Chen Wang ◽  
Pei-Chun Liao ◽  
...  
Keyword(s):  
Essential Oil ◽  
Wood Decay ◽  
Antimicrobial Activities ◽  
Sesquiterpene Hydrocarbons ◽  
Leaf Oil ◽  
Leaf Essential Oil ◽  
Main Components

The hydrodistillated leaf essential oil of Machilus kusanoi was analyzed to determine its composition and yield. Twenty-three compounds were identified, the main components being β-caryophyllene (23.3%), β-eudesmol (17.1%), α-terpineol (16.0%), n-dodecanal (14.2%), and n-decanal (10.4%). Sesquiterpene hydrocarbons (28.1%) and non-terpenoids (25.0%) were the predominant groups of compounds. The leaf oil exhibited excellent antimicrobial and anti-wood-decay fungal activities.

scholarly journals Composition and Antimicrobial Activity of the Leaf Essential oil of Litsea kostermansii from Taiwan

2009 ◽  
Vol 4 (8) ◽  
pp. 1934578X0900400 ◽  
Author(s):  
Chen-Lung Ho ◽  
Eugene I-Chen Wang ◽  
Kuang-Ping Hsu ◽  
Pei-Yeh Lee ◽  
Yu-Chang Su
Keyword(s):  
Antimicrobial Activity ◽  
Essential Oil ◽  
Antimicrobial Activities ◽  
Sesquiterpene Hydrocarbons ◽  
Leaf Oil ◽  
Leaf Essential Oil ◽  
Main Components

The hydrodistillated leaf essential oil of Litsea kostermansii was analyzed to determine its composition and yield. Seventy-three compounds were identified, the main components being β-eudesmol (22.5%), γ-eudesmol (18.6%), δ-selinene (8.5%), α-eudesmol (6.0%), and γ-muurolene (4.7%). Oxygenated sesquiterpenes (66.2%) and sesquiterpene hydrocarbons (32.8%) were the predominant groups of compounds. The leaf oil exhibited excellent antimicrobial activities.

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