Clinopyroxenes of the gabbro cumulates of the Kap Edvard Holm complex, east Greenland

1965 ◽  
Vol 34 (268) ◽  
pp. 177-193 ◽  
Author(s):  
W. A. Deer ◽  
D. Abbott
Keyword(s):  
Optical Properties ◽  
Chemical Composition ◽  
Large Volume ◽  
Major Part ◽  
Progressive Change ◽  
Layered Series ◽  
East Greenland ◽  
Cell Parameters ◽  
Lower Temperature ◽  
Primary Minerals

SummaryThe major part of the Kap Edvard Holm complex consists of two series of conspicuously banded gabbroic rocks. The primary minerals of both lower and upper layered series show a progressive change in composition, from higher to lower temperature phases, with increasing height in the complex. Minor fluctuations in the differentiation of the two series occur but the division of the layered rocks into the lower and upper series is based on abrupt and major changes in the compositions of the pyroxenes, olivine and plagioclase. This break is correlated with the injection of a large volume of undifferentiated magma which occurred after much of the lower layered series had consolidated, and from which the rocks of the upper layered series were formed. Twelve pyroxenes, five from the lower and seven from the upper layered series have been analysed; the relationships between their optical properties and chemical composition, and between the cell parameters and composition are considered. The crystallization trend of the pyroxenes is compared with that of the Skaergaard calcium-rich pyroxenes; it is suggested that the restricted enrichment in iron shown by the Kap Edvard Holm pyroxenes may be related to the higher water-vapour pressures which prevailed during much of the period of crystallization.

Clinopyroxenes from the Upper Layered Series Kap Edvard Holm, East Greenland

1971 ◽  
Vol 38 (293) ◽  
pp. 49-57 ◽  
Author(s):  
R. Elsdon
Keyword(s):  
Optical Properties ◽  
Single Crystals ◽  
Olivine Basalt ◽  
Parent Magma ◽  
Chemical Compositions ◽  
Measurable Effect ◽  
Layered Series ◽  
East Greenland ◽  
X Ray ◽  
Alkali Olivine Basalt

SummaryChemical compositions, unit-cell contents, and optical properties of six clinopyroxenes from the Upper Layered Series are presented. There is a gradual enrichment in iron upwards in the intrusion although there is no measurable effect on the optical properties, possibly because of Cr variation and exsolution of Fe and Ti as oxides. The chemistry of the clinopyroxenes is consistent with crystallization from a water-rich magma of transitional nature between tholeiite and alkali-olivine basalt. X-ray oscillation photographs of single crystals reveal the presence of sub-microscopic exsolution lamellae of pigeonite, a feature consistent with the transitional nature of the parent magma. Exsolution lamellae of titanomagnetite are ubiquitous and were formed at subsolidus temperatures in response to high buffered oxygen fugacity. Comparisons are made between the properties of clinopyroxenes from the Lower, Middle, and Upper Layered Series, and the conditions of crystallization of each series.

scholarly journals Mineralogy of the Vorontsovskoe gold deposit (Northern Urals). Part 4: Oxysalts

2021 ◽  
pp. 5-31
Author(s):  
A.V. Kasatkin ◽  
S.Yu. Stepanov ◽  
M.V. Tsyganko ◽  
R. Skoda ◽  
F. Nestola ◽  
...  
Keyword(s):  
Optical Properties ◽  
Chemical Composition ◽  
Gold Deposit ◽  
Russian Federation ◽  
Unit Cell ◽  
Unit Cell Parameters ◽  
Entire Series ◽  
Cell Parameters ◽  
Northern Urals

This is a fnal paper in a series of publications devoted to the mineralogy of the Vorontsovskoe gold deposit in the Northern Urals. The article reports on oxygen compounds (oxyhalides, oxides, hydroxides, carbonates, sulfates, tungstates, phosphates, arsenates and silicates) of the Vorontsovskoe deposit, their chemical composition and, for selected minerals, unit-cell parameters and optical properties. Armenite, claudetite, ramsdellite, hingganite-(Nd) and chapmanite are found for the frst time in Russian Federation. As a conclusion for the entire series of publications, the general features of mineralogy of the Vorontsovskoe deposit are discussed, thanks to which it is considered as a unique mineral locality not only in Urals but in general in Russia.

Some Observations on Igneous Ferrohastingsites

1963 ◽  
Vol 33 (263) ◽  
pp. 646-662 ◽  
Author(s):  
G. Borley ◽  
M. T. Frost
Keyword(s):  
Optical Properties ◽  
Chemical Composition ◽  
Unit Cell ◽  
Refractive Indices ◽  
Northern Nigeria ◽  
Unit Cell Parameters ◽  
Cell Parameters ◽  
Respective Parent ◽  
Parent Rocks ◽  
Southern Rhodesia

SummaryNine ferrohastingsites from the Younger Granites of Northern Nigeria and five from the nepheline-bearing rocks in the Marangudzi complex of Southern Rhodesia have been analysed chemically and their optical properties and unit-cell parameters determined.All the minerals have compositions that can be expressed by the formula NaCa2(Fe″Mg)4Fe‴Al2Si6O22(OH)2, but the Nigerian minerals differ from those of Marangudzi in their lower alumina contents, generally greater degree of iron enrichment, lower potassium, and more variable fluorine contents. These differences are considered to reflect the differences in composition of their respective parent rocks. The compositional similarities between some hastingsites and barkevikite are commented upon and the pleochroism of barkevikite is briefly discussed.Refractive indices of the analysed hastingsites have been plotted on the optical curves of Tröger. It is suggested that such curves are of limited use and that variations in unit-cell parameters might be a more useful method of determining the iron contents of hastingsites.The variation in cell parameters with variation in chemical composition of the analysed minerals is also discussed.

Structural/Property Relationships for Optical Materials

1993 ◽  
Vol 329 ◽  
Author(s):  
Vivien D.
Keyword(s):  
Crystal Structure ◽  
Optical Properties ◽  
Electronic Structure ◽  
Chemical Composition ◽  
Field Strength ◽  
Optical Materials ◽  
Site Occupancy ◽  
Laser Materials ◽  
Crystal Field Strength ◽  
The Matrix

AbstractIn this paper the relationships between the crystal structure, chemical composition and electronic structure of laser materials, and their optical properties are discussed. A brief description is given of the different laser activators and of the influence of the matrix on laser characteristics in terms of crystal field strength, symmetry, covalency and phonon frequencies. The last part of the paper lays emphasis on the means to optimize the matrix-activator properties such as control of the oxidation state and site occupancy of the activator and influence of its concentration.

Optical properties and chemical composition of the atmospheric aerosol in urban Guangzhou, China

2008 ◽  
Vol 42 (25) ◽  
pp. 6335-6350 ◽  
Author(s):  
Meinrat O. Andreae ◽  
Otmar Schmid ◽  
Hong Yang ◽  
Duli Chand ◽  
Jian Zhen Yu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Chemical Composition ◽  
Atmospheric Aerosol

Pb-Sb zrudnění z Antimonitové žíly, důl Rudolf, Bohutín (Česká republika)

2021 ◽  
Vol 29 (2) ◽  
pp. 275-280
Author(s):  
Pavel Škácha ◽  
Jiří Sejkora
Keyword(s):  
Czech Republic ◽  
Chemical Composition ◽  
Empirical Formula ◽  
Unit Cell ◽  
Monoclinic Space Group ◽  
Unit Cell Parameters ◽  
X Ray ◽  
Cell Parameters ◽  
Ore District ◽  
Archive Material

The Pb-Sb mineralization with dominant stibnite and plagionite and associated semseyite and zinkenite was found in an archive material collected at the Antimonitová vein, Bohutín, Březové Hory ore district (Czech Republic). Plagionite forms subhedral aggregates up to 1 mm in size. The unit-cell parameters of plagionite for monoclinic space group C2/c refined from the X-ray powder data are: a 13.4890(17), b 11.8670(14), c 19.997(2) Å, β 107.199(8)° and V 3057.9(6) Å3. Its chemical composition (average of 26 analyses, based on 30 apfu) corresponds to the empirical formula Pb5.02Sb8.15S16.82. Associated zinkenite is forming subhedral crystals up to 1 mm in size. Its empirical formula can be expressed as (Cu0.25Ag0.02Fe0.01)Σ0.28Pb9.22Sb22.19S41.31 (average of 26 analyses, based on 73 apfu). Semseyite aggregates have the empirical formula (Pb8.72Fe0.14)8.86Sb8.42S20.73 (average of 11 analyses, based on 38 apfu).

scholarly journals Relationship between the Optical Properties and Chemical Composition of Urban Aerosol Particles in Lithuania

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Julija Pauraite ◽  
Kristina Plauškaitė ◽  
Vadimas Dudoitis ◽  
Vidmantas Ulevicius
Keyword(s):  
Optical Properties ◽  
Chemical Composition ◽  
Organic Aerosol ◽  
Single Scattering ◽  
Chemical Compositions ◽  
Spectra Analysis ◽  
Average Value ◽  
Aerosol Mass ◽  
In Situ Investigation

In situ investigation results of aerosol optical properties (absorption and scattering) and chemical composition at an urban background site in Lithuania (Vilnius) are presented. Investigation was performed in May-June 2017 using an aerosol chemical speciation monitor (ACSM), a 7-wavelength Aethalometer and a 3-wavelength integrating Nephelometer. A positive matrix factorisation (PMF) was used for the organic aerosol mass spectra analysis to characterise the sources of ambient organic aerosol (OA). Five OA factors were identified: hydrocarbon-like OA (HOA), biomass-burning OA (BBOA), more and less oxygenated OA (LVOOA and SVOOA, respectively), and local hydrocarbon-like OA (LOA). The average absorption (at 470 nm) and scattering (at 450 nm) coefficients during the entire measurement campaign were 16.59 Mm−1 (standard deviation (SD) = 17.23 Mm−1) and 29.83 Mm−1 (SD = 20.45 Mm−1), respectively. Furthermore, the absorption and scattering Angström exponents (AAE and SAE, respectively) and single-scattering albedo (SSA) were calculated. The average AAE value at 470/660 nm was 0.97 (SD = 0.16) indicating traffic-related black carbon (BCtr) dominance. The average value of SAE (at 450/700 nm) was 1.93 (SD = 0.32) and could be determined by the submicron particle (PM1) dominance versus the supermicron ones (PM > 1 µm). The average value of SSA was 0.62 (SD = 0.13). Several aerosol types showed specific segregation in the SAE versus SSA plot, which underlines different optical properties due to various chemical compositions.

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