scholarly journals Multi-isotope signatures (Cu, Zn, Pb) of different particle sizes in road-deposited sediments: a case study from industrial area

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Hyeryeong Jeong ◽  
Kongtae Ra

AbstractRoad-deposited sediments (RDS) are major sources of heavy metal contamination in urban areas and adversely affect surrounding environments and human health. Multi-isotope combinations (Cu, Zn, and Pb), which serve as environmental tracers, enable the identification and management of metal contaminants in RDS. Here, we present Cu, Zn, and Pb isotopic data for the first time in size-fractionated RDS samples collected from industrial areas to describe the relationship between the RDS and total suspended solids (TSS) in runoff, and to explore the feasibility of using multi-isotopes to identify sources of metal contamination. RDS in the industrial study areas had high concentrations of Cu, Zn, and Pb, and their δ65CuAE647, δ66ZnIRMM3702, and 206Pb/207Pb values ranged from − 0.33 to + 0.73‰, − 0.36 to + 0.01‰, and 1.1418 to 1.1616, respectively. The variation in δ65CuAE647 (δ65Cumax-min) was larger than that of δ66ZnIRMM3702 (i.e., δ66Znmax-min), and the isotope values of Zn and Pb (206Pb/207Pb) tended to increase with the concentrations of these elements. Meanwhile, the fine RDS particles (< 63 µm) had similar Cu, Zn, and Pb isotopic compositions to those of TSS. Hierarchical cluster analyses revealed that the < 63 µm RDS fractions were associated with the TSS. Our results also showed that a combination of Pb and either Cu or Zn could be used to distinguish between RDS and non-exhaust emissions (e.g., brake pads, tires, etc.). Multi-isotope approaches utilizing Cu, Zn, and Pb and more robust isotopic data on individual sources of metal contamination could be useful for identifying pollution sources and understanding their environmental impacts.

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Iqra Azam ◽  
Sumera Afsheen ◽  
Ahmed Zia ◽  
Muqaddas Javed ◽  
Rashid Saeed ◽  
...  

To study the accumulation and contamination of heavy metals (i.e., Cd, Cr, Cu, Ni, and Zn) in soil, air, and water, few insect species were assayed as ecological indicators. Study area comes under industrial zone of district Gujrat of Punjab, Pakistan. Insects used as bioindicators included a libellulid dragonfly (Crocothemis servilia), an acridid grasshopper (Oxya hyla hyla), and a nymphalid butterfly (Danaus chrysippus) near industrial zone of Gujrat. Accumulation of Cd was highest in insect species followed by Cu, Cr, Zn, and Ni atp<0.05. Hierarchical cluster analysis (HACA) was carried out to study metal accumulation level in all insects. Correlation and regression analysis confirmed HACA observations and declared concentration of heavy metals above permissible limits. Metal concentrations in insects were significantly higher near industries and nallahs in Gujrat and relatively higher concentrations of metals were found in Orthoptera than Odonata and Lepidoptera. The total metal concentrations in insects were pointed significantly higher at sites S3 (Mid of HalsiNala), S9 (End of HalsiNala), and S1 (Start of HalsiNala), whereas lowest value was detected at site S6 (Kalra Khasa) located far from industrial area. HACA indicates that these insect groups are potential indicators of metal contamination and can be used in biomonitoring.


2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
M. Adama ◽  
R. Esena ◽  
B. Fosu-Mensah ◽  
D. Yirenya-Tawiah

Waste incineration is the main waste management strategy used in treating hospital waste in many developing countries. However, the release of dioxins, POPs, and heavy metals in fly and bottom ash poses environmental and public health concerns. To determine heavy metal (Hg, Pb, Cd, Cr, and Ag) in levels in incinerator bottom ash and soils 100 m around the incinerator bottom ash dump site, ash samples and surrounding soil samples were collected at 20 m, 40 m, 60 m, 80 m, 100 m, and 1,200 m from incinerator. These were analyzed using the absorption spectrophotometer method. The geoaccumulation (Igeo) and pollution load indices (PLI) were used to assess the level of heavy metal contamination of surrounding soils. The study revealed high concentrations in mg/kg for, Zn (16417.69), Pb (143.80), Cr (99.30), and Cd (7.54) in bottom ash and these were above allowable limits for disposal in landfill. The study also found soils within 60 m radius of the incinerator to be polluted with the metals. It is recommended that health care waste managers be educated on the implication of improper management of incinerator bottom ash and regulators monitor hospital waste incinerator sites.


2012 ◽  
Vol 7 (2) ◽  
pp. 513-525 ◽  
Author(s):  
G. Machender ◽  
Ratnakar Dhakate ◽  
S. T. Mallikharjuna Rao ◽  
B. Mangaraja Rao ◽  
L. Prasanna

2017 ◽  
Vol 3 (01) ◽  
pp. 25-31 ◽  
Author(s):  
Charu Gangwar ◽  
Aprajita Singh ◽  
Raina Pal ◽  
Atul Kumar ◽  
Saloni Sharma ◽  
...  

E-waste is a popular name given to those electronic products nearing the end of their useful life which has become a major source of heavy metal contamination in soil and hence, became the global concern. Various samples of soil were collected from different sites and were determined for heavy metal analysis by the ICP-AAS after the digestion process. The main source of contamination is illegal e-waste recycling activities such as burning of PCB's acid baths etc. Different soil indices like contamination factor, I-geo, pollution load index, were calculated to determine the quality of the soil. Results indicate that e-waste recycling and industrial area are strongly contaminated by the heavy metals. Physiological analysis of soil revealed that e-waste processing and industrial activities decrease the soil pH and organic matter while enhancing the electrical conductivity of soil. The exceedance of metal contamination imposed negative impact to the soil environment and human health.


Agropedology ◽  
2019 ◽  
Vol 30 (2) ◽  
Author(s):  
Sandeep Kumar ◽  
◽  
Lal Chand Malav ◽  
Shiv Prasad ◽  
Sunita Yadav ◽  
...  

Presently, rapid industrialization and mechanization create a lot of heavy metal pollution around the globe. Both anthropogenic and natural sources are responsible for the discharge of heavy metal in the environment. Anyhow, these toxic metals reach into soil, water bodies, plants and finally to human beings through the food chain. These toxic metals create several problems in plants and living beings after intake from the soil and get accumulated in their body. Heavy metals also exhibit toxic effects on soil biological activities by affecting key microbial processes and also hamper the activities of soil microbes. Recently, due to industrial development in urban areas, heavy metal contamination has become a serious threat to peri-urban agriculture prevalent for vegetable production. There has long been a need for decontamination of these agricultural resources and prevention from the further contamination to avert the negative effects on living beings. In this article, an attempt has been made to provide an extensive understanding about different sources of heavy metal, such as zinc (Zn), copper (Cu), lead (Pb) and cadmium (Cd) etc., in agro-ecosystem and their possible risks to soil and plants. An effort has been also made to present in brief information on remediation techniques specially phytoremediation through this review.


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