Thermodynamic State Functions

2021 ◽  
pp. 71-94
Author(s):  
John H. S. Lee ◽  
K. Ramamurthi
Author(s):  
Mirza Wasif Baig

To embrace the special theory of relativity with classical thermodynamics correct Lorentz transformations of thermodynamic state functions are formulated. All of these Lorentz transformations of state functions equally support the time dilation phenomenon which is experimentally verified fact. Relativistic Boltzmann constant proves entropy to be the Lorentz variant. Twin paradox thought experiments for heat engines prove heat flux to be Lorentz variant. Lorentz transformation of entropy and heat flux proves temperature Lorentz invariant. All thermodynamic state functions are proved to be Lorentz variant which is shown in accord with Lorentz transformation of thermodynamic work.


1965 ◽  
Vol 42 (12) ◽  
pp. 649
Author(s):  
Mordechai L. Kremer

2004 ◽  
Vol 69 (12) ◽  
pp. 2134-2146 ◽  
Author(s):  
Esther Quintanilla ◽  
Juan Z. Dávalos ◽  
Rebeca Herrero ◽  
Pilar Jiménez ◽  
Ibon Alkorta ◽  
...  

Here we report the results of the study of a set of thirteen hydrocarbons R-H not leading to extensively charge-delocalized anions R- upon ionization, R-H → R- + H+. It essentially involves the following: (i) The computation at the G2 level of the changes in thermodynamic state functions for this process in the gas phase. The reliability of the computational method was further assessed by comparison with CCSD(T)/Aug-cc-pVTZ results. (ii) A direct comparison of the experimentally available thermodynamic (gas phase) and kinetic (solution) data pertaining to this reaction. (iii) A careful re-examination of the experimental data sets and the Brønsted-type relationships derived therefrom by using the computed thermodynamic data. This treatment suggests the existence of mechanistic features affecting the experimental data and indicates the need for further experimental and computational work.


2010 ◽  
Vol 25 (02n03) ◽  
pp. 433-443 ◽  
Author(s):  
A. RITZ

We discuss some universal relations that hold for conformal field theories which admit a dual classical gravitational description in anti-de Sitter space. These relations therefore apply in a suitable large N limit, and imply that various hydrodynamic transport coefficients for conserved currents and thermodynamic state functions are entirely fixed by central charges.


2012 ◽  
Author(s):  
Erica G. Hepper ◽  
Timothy D. Ritchie ◽  
Constantine Sedikides ◽  
Tim Wildschut
Keyword(s):  

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