Scaling concepts for the dynamics of viscous liquids near an ideal glassy state

2001 ◽  
pp. 317-326
Keyword(s):  
Glassy State ◽  
Viscous Liquids

Scaling concepts for the dynamics of viscous liquids near an ideal glassy state

1989 ◽  
Vol 40 (2) ◽  
pp. 1045-1054 ◽  
Author(s):  
T. R. Kirkpatrick ◽  
D. Thirumalai ◽  
P. G. Wolynes
Keyword(s):  
Glassy State ◽  
Viscous Liquids

Integration of Atomistic Simulation with Experiment Using Time−Temperature Superposition for a Cross-Linked Epoxy Network

2019 ◽  
Author(s):  
Ketan Khare ◽  
Frederick R. Phelan Jr.
Keyword(s):  
Master Curve ◽  
Glassy State ◽  
Superposition Principle ◽  
Quantitative Comparison ◽  
Time Shift ◽  
Data Sets ◽  
Epoxy Network ◽  
Temperature Superposition ◽  
Time Temperature Superposition ◽  
Time Temperature Superposition Principle

<a></a><a>Quantitative comparison of atomistic simulations with experiment for glass-forming materials is made difficult by the vast mismatch between computationally and experimentally accessible timescales. Recently, we presented results for an epoxy network showing that the computation of specific volume vs. temperature as a function of cooling rate in conjunction with the time–temperature superposition principle (TTSP) enables direct quantitative comparison of simulation with experiment. Here, we follow-up and present results for the translational dynamics of the same material over a temperature range from the rubbery to the glassy state. Using TTSP, we obtain results for translational dynamics out to 10<sup>9</sup> s in TTSP reduced time – a macroscopic timescale. Further, we show that the mean squared displacement (MSD) trends of the network atoms can be collapsed onto a master curve at a reference temperature. The computational master curve is compared with the experimental master curve of the creep compliance for the same network using literature data. We find that the temporal features of the two data sets can be quantitatively compared providing an integrated view relating molecular level dynamics to the macroscopic thermophysical measurement. The time-shift factors needed for the superposition also show excellent agreement with experiment further establishing the veracity of the approach</a>.

Non-Newtonian effects in axially symmetric oscillatory flows of some elastico-viscous liquids

1970 ◽  
Vol 68 (3) ◽  
pp. 731-750 ◽  
Author(s):  
J. R. Jones
Keyword(s):  
Elastic Properties ◽  
Equations Of State ◽  
Time Lag ◽  
Physical Constant ◽  
Oscillatory Motion ◽  
Axially Symmetric ◽  
Metric Tensor ◽  
Oscillatory Flows ◽  
Viscous Liquids ◽  
Deformation Stress

In (general) elastico-viscous liquids the response to stress at any instant will depend on previous rheological history, the equations of state needed to describe the rheological properties of a typical material element at any instant t being expressible in the form of a (properly invariant†) set of integro-differential equations relating its deformation, stress and temperature histories (as defined by a metric tensor (of a convected frame of reference), a stress tensor and the temperature measured in the element as functions of previous time t'( < t)) together with the time lag (t – t') and physical constant tensors associated with the element (1). Thus in any type of oscillatory motion a rheological history will necessarily be a function of the frequency of the forcing agent, the rheological history of a number of different types of elastico-viscous liquids in some simple shearing oscillatory flows being a rather simple oscillatory history (see, for example, (2–4)). It is, therefore, to be expected that a liquid with elastic properties will behave somewhat differently from any inelastic viscous liquid when subjected to any kind of oscillatory motion, and it is for this reason that oscillatory motions have been used extensively to detect and measure the elastic properties of liquids (see, for example, (2–5)).

scholarly journals Physical Aging Behavior of a Glassy Polyether

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 954
Author(s):  
Xavier Monnier ◽  
Sara Marina ◽  
Xabier Lopez de Pariza ◽  
Haritz Sardón ◽  
Jaime Martin ◽  
...  
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Physical Aging ◽  
Glassy State ◽  
Aging Behavior ◽  
Scanning Calorimetry ◽  
Narrow Temperature Range ◽  
Glass Forming ◽  
Fast Scanning Calorimetry

The present work aims to provide insights on recent findings indicating the presence of multiple equilibration mechanisms in physical aging of glasses. To this aim, we have investigated a glass forming polyether, poly(1-4 cyclohexane di-methanol) (PCDM), by following the evolution of the enthalpic state during physical aging by fast scanning calorimetry (FSC). The main results of our study indicate that physical aging persists at temperatures way below the glass transition temperature and, in a narrow temperature range, is characterized by a two steps evolution of the enthalpic state. Altogether, our results indicate that the simple old-standing view of physical aging as triggered by the α relaxation does not hold true when aging is carried out deep in the glassy state.

scholarly journals Analysis of PLA Composite Filaments Reinforced with Lignin and Polymerised-Lignin-Treated NFC

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2174
Author(s):  
Diana Gregor-Svetec ◽  
Mirjam Leskovšek ◽  
Blaž Leskovar ◽  
Urška Stanković Elesini ◽  
Urška Vrabič-Brodnjak
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Tensile Strength ◽  
Glassy State ◽  
Nanofibrillated Cellulose ◽  
Dynamic Mechanical Properties ◽  
Initial Modulus ◽  
Surface Modified ◽  
Scanning Electron

Polylactic acid (PLA) is one of the most suitable materials for 3D printing. Blending with nanoparticles improves some of its properties, broadening its application possibilities. The article presents a study of composite PLA matrix filaments with added unmodified and lignin/polymerised lignin surface-modified nanofibrillated cellulose (NFC). The influence of untreated and surface-modified NFC on morphological, mechanical, technological, infrared spectroscopic, and dynamic mechanical properties was evaluated for different groups of samples. As determined by the stereo and scanning electron microscopy, the unmodified and surface-modified NFCs with lignin and polymerised lignin were present in the form of plate-shaped agglomerates. The addition of NFC slightly reduced the filaments’ tensile strength, stretchability, and ability to absorb energy, while in contrast, the initial modulus slightly improved. By adding NFC to the PLA matrix, the bending storage modulus (E’) decreased slightly at lower temperatures, especially in the PLA samples with 3 wt% and 5 wt% NFC. When NFC was modified with lignin and polymerised lignin, an increase in E’ was noticed, especially in the glassy state.

scholarly journals Cavity optomechanics on a microfluidic resonator with water and viscous liquids

2013 ◽  
Vol 2 (11) ◽  
pp. e110-e110 ◽  
Author(s):  
Kyu Hyun Kim ◽  
Gaurav Bahl ◽  
Wonsuk Lee ◽  
Jing Liu ◽  
Matthew Tomes ◽  
...  
Keyword(s):  
Cavity Optomechanics ◽  
Viscous Liquids
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