Nitrogen-Substitution in the Flapping Wings of Cyclooctatetraene-Fused Molecules

Author(s):  
Kensuke Suga ◽  
Takuya Yamakado ◽  
Shohei Saito
2021 ◽  
Author(s):  
Kensuke Suga ◽  
Takuya Yamakado ◽  
Shohei Saito

New synthetic protocols to the nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[<i>a</i>,<i>e</i>]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.


2021 ◽  
Author(s):  
Kensuke Suga ◽  
Takuya Yamakado ◽  
Shohei Saito

New synthetic protocols to the nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[<i>a</i>,<i>e</i>]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.


2009 ◽  
Author(s):  
Christopher Kroninger ◽  
Jeffrey Pulskamp ◽  
Jessica Bronson ◽  
Ronald G. Polcawich ◽  
Eric Wetzel

Science ◽  
2021 ◽  
Vol 372 (6538) ◽  
pp. 175-182
Author(s):  
Hairong Lyu ◽  
Ilia Kevlishvili ◽  
Xuan Yu ◽  
Peng Liu ◽  
Guangbin Dong

Mild methods to cleave the carbon-oxygen (C−O) bond in alkyl ethers could simplify chemical syntheses through the elaboration of these robust, readily available precursors. Here we report that dibromoboranes react with alkyl ethers in the presence of a nickel catalyst and zinc reductant to insert boron into the C−O bond. Subsequent reactivity can effect oxygen-to-nitrogen substitution or one-carbon homologation of cyclic ethers and more broadly streamline preparation of bioactive compounds. Mechanistic studies reveal a cleavage-then-rebound pathway via zinc/nickel tandem catalysis.


Micromachines ◽  
2021 ◽  
Vol 12 (6) ◽  
pp. 650
Author(s):  
Ruide Yun ◽  
Yangsheng Zhu ◽  
Zhiwei Liu ◽  
Jianmei Huang ◽  
Xiaojun Yan ◽  
...  

We report a novel electrostatic self-excited resonator driven by DC voltage that achieves variable velocity-position characteristics via applying the pre-tension/pre-compression constraint. The resonator consists of a simply supported micro-beam, two plate electrodes, and two adjustable constraint bases, and it can be under pre-compression or pre-tension constraint by adjusting the distance L between two constraint bases (when beam length l > L, the resonator is under pre-compression and when l < L, it is under pre-tension). The oscillating velocity of the beam reaches the maximum value in the position around electrodes under the pre-compression constraint and reaches the maximum value in the middle position between two electrodes under the pre-tension condition. By changing the constraint of the microbeam, the position of the maximum velocity output of the oscillating beam can be controlled. The electrostatic self-excited resonator with a simple constraint structure under DC voltage has great potential in the field of propulsion of micro-robots, such as active rotation control of flapping wings.


2020 ◽  
Vol 11 (1) ◽  
pp. 126
Author(s):  
Jen-Chuan Tung ◽  
Tsung-Che Li ◽  
Yen-Jui Teseng ◽  
Po-Liang Liu

The aim of this research is the study of hydrogen abstraction reactions and methyl adsorption reactions on the surfaces of (100), (110), and (111) oriented nitrogen-doped diamond through first-principles density-functional calculations. The three steps of the growth mechanism for diamond thin films are hydrogen abstraction from the diamond surface, methyl adsorption on the diamond surface, and hydrogen abstraction from the methylated diamond surface. The activation energies for hydrogen abstraction from the surface of nitrogen-undoped and nitrogen-doped diamond (111) films were −0.64 and −2.95 eV, respectively. The results revealed that nitrogen substitution was beneficial for hydrogen abstraction and the subsequent adsorption of methyl molecules on the diamond (111) surface. The adsorption energy for methyl molecules on the diamond surface was generated during the growth of (100)-, (110)-, and (111)-oriented diamond films. Compared with nitrogen-doped diamond (100) films, adsorption energies for methyl molecule adsorption were by 0.14 and 0.69 eV higher for diamond (111) and (110) films, respectively. Moreover, compared with methylated diamond (100), the activation energies for hydrogen abstraction were by 0.36 and 1.25 eV higher from the surfaces of diamond (111) and (110), respectively. Growth mechanism simulations confirmed that nitrogen-doped diamond (100) films were preferred, which was in agreement with the experimental and theoretical observations of diamond film growth.


2011 ◽  
Vol 689 ◽  
pp. 32-74 ◽  
Author(s):  
C.-K. Kang ◽  
H. Aono ◽  
C. E. S. Cesnik ◽  
W. Shyy

AbstractEffects of chordwise, spanwise, and isotropic flexibility on the force generation and propulsive efficiency of flapping wings are elucidated. For a moving body immersed in viscous fluid, different types of forces, as a function of the Reynolds number, reduced frequency (k), and Strouhal number (St), acting on the moving body are identified based on a scaling argument. In particular, at the Reynolds number regime of $O(1{0}^{3} \ensuremath{-} 1{0}^{4} )$ and the reduced frequency of $O(1)$, the added mass force, related to the acceleration of the wing, is important. Based on the order of magnitude and energy balance arguments, a relationship between the propulsive force and the maximum relative wing-tip deformation parameter ($\gamma $) is established. The parameter depends on the density ratio, St, k, natural and flapping frequency ratio, and flapping amplitude. The lift generation, and the propulsive efficiency can be deduced by the same scaling procedures. It seems that the maximum propulsive force is obtained when flapping near the resonance, whereas the optimal propulsive efficiency is reached when flapping at about half of the natural frequency; both are supported by the reported studies. The established scaling relationships can offer direct guidance for micro air vehicle design and performance analysis.


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