A Relation between Ion-exchange Selectivity Coefficient and Degree of Distribution for Model Compounds in Solvent Extraction

1968 ◽  
Vol 41 (8) ◽  
pp. 1757-1760 ◽  
Author(s):  
Tadao Kenjo ◽  
Takuji Ito
Keyword(s):  
Solvent Extraction ◽  
Ion Exchange ◽  
Selectivity Coefficient ◽  
Model Compounds ◽  
Exchange Selectivity

Alginate Polyelectrolyte Ionotropic Gels-XII. Chromatographic Separation of Divalent Transition Metal Ions using Alginates as Ion Exchangers

1992 ◽  
Vol 4 (1) ◽  
pp. 49-54 ◽  
Author(s):  
Refat M. Hassan ◽  
S. A. El-Shatoury ◽  
M. Th. Makhlouf
Keyword(s):  
Ion Exchange ◽  
Metal Ions ◽  
Metal Ion ◽  
Transition Metal Ions ◽  
Selectivity Coefficient ◽  
Divalent Metal ◽  
Divalent Metal Ions ◽  
Ion Exchangers ◽  
Calcium Alginate Gel ◽  
Exchange Selectivity

The separation of divalent metal ion mixtures has been investigated chromatographically on columns of either gel or sol forms of alginate polyelectrolyte. Separation was obtained in the form of narrow sharp zones for the metal ions. Ion exchange selectivity indicated that Cu2+ ions were most strongly retained among the divalent metal ions studied. The factors which affect the ion exchange selectivity, such as the strength of chelation and the mobility and radii of the metal ions, are discussed. The selectivity coefficient for the separation of a mixture of Cu2+ and Co2+ ions on columns of calcium alginate gel or sodium alginate sol was determined and found to be 1.9 ± 0.1 in both ion exchangers at 25°C.

Am3+ and Eu3+ /alkali cation exchange selectivity on mordenite and zeolite L

2000 ◽  
Vol 15 (12) ◽  
pp. 2849-2856 ◽  
Author(s):  
Masamichi Tsuji ◽  
Hitoshi Mimura
Keyword(s):  
Ion Exchange ◽  
Cation Exchange ◽  
Selectivity Coefficient ◽  
Alkali Cation ◽  
Ionic Form ◽  
Alkali Cations ◽  
Ionic Radii ◽  
Zeolite L ◽  
Exchange Site ◽  
Exchange Selectivity

Am3+ and Eu3+ /alkali cation exchange selectivity was studied on mordenite and zeolite L at 25 to 60 °C to examine the effect of their openings of ion-exchange sites. The corrected selectivity coefficient at the infinitesimal exchange increased in the order of Eu3+ < Am3+ on mordenite and Am3+ < Eu3+ on zeolite L. The selectivity reversal did not reflect the effect of the ionic form, but reflected the dimension of the opening of the ion-exchange site and charge of trivalent cations, since the crystal ionic radii of alkali cations were much smaller than the openings of these zeolites (7–8 Å).

Application of Ion Exchange, Solvent Extraction, and Ion-Imprinted Methods for Separation of 203Pb

2019 ◽  
Vol 61 (6) ◽  
pp. 724-727
Author(s):  
M. Yarmohammadi ◽  
M. Mirzaei ◽  
A. Samadi-Maybodi
Keyword(s):  
Solvent Extraction ◽  
Ion Exchange ◽  
Ion Imprinted

scholarly journals Separation of Ag(I) by Ion Exchange and Cementation from a Raffinate Containing Ag(I), Ni(II) and Zn(II) and Traces of Cu(II) and Sn(II)

Processes ◽  
2018 ◽  
Vol 6 (8) ◽  
pp. 112 ◽  
Author(s):  
Wei Xing ◽  
Man Lee ◽  
Seung Choi
Keyword(s):  
Ascorbic Acid ◽  
Nitric Acid ◽  
Solvent Extraction ◽  
Ion Exchange ◽  
Anode Slime ◽  
Silver Particles ◽  
Copper Sheet ◽  
Agno3 Solution ◽  
Micron Size ◽  
Leaching Solution

Ion exchange and cementation experiments were done to separate silver(I) from a raffinate containing silver(I), nickel(II), and zinc(II) and small amounts of copper(II) and tin(II). The raffinate resulted from the recovery of gold(III), tin(II) and copper(II) by solvent extraction from a leaching solution of anode slime. Ion exchange with anionic resins was not effective in separating silver(I) because tin(II) and zinc(II) were selectively adsorbed into the anionic resins. It was possible to separate silver(I) by cementation with copper sheet. Treatment of the cemented silver with nitric acid solution increased the purity of silver(I) in the solution from 50.9% to 99.99%. Adjusting the pH of the AgNO3 solution to higher than 6, followed by adding ascorbic acid as a reducing agent, led to the synthesis of silver particles with micron size.

Cation Exchange Selectivity Coefficient Values on Smectite and Mixed-Layer Illite/Smectite Minerals

2009 ◽  
Vol 73 (3) ◽  
pp. 928-942 ◽  
Author(s):  
Christophe Tournassat ◽  
Hélène Gailhanou ◽  
Catherine Crouzet ◽  
Gilles Braibant ◽  
Anne Gautier ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Mixed Layer ◽  
Selectivity Coefficient ◽  
Exchange Selectivity
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