scholarly journals Determination of the Rate Equation for a Certain Reaction by a Single Kinetic Pursuit

1983 ◽  
Vol 103 (3) ◽  
pp. 350-355
Author(s):  
YOSHIAKI FURUYA ◽  
YOSHIO YANAGA ◽  
RYUICHI UEOKA ◽  
MASAMI TOMIYAMA ◽  
AKIRA INOUE
Keyword(s):  
2005 ◽  
Vol 70 (7) ◽  
pp. 987-993 ◽  
Author(s):  
Violeta Mitic ◽  
Snezana Nikolic ◽  
Vesna Stankov-Jovanovic

Anew sensitive kinetic method has been developed for the determination of trace amounts of phenylhydrazine in the range of 1.08x10-7 to 1.08x10-6 g/cm3. The detection limit of this method is 0.008 ?g/cm3, based on the 3Sb criterion. Themethod is based on the inhibitory effect of phenylhydrazine on the oxidation of Victoria Blue 4-R by KBrO3. The reaction was monitored spectrophotometrically at 596.3 nm. The method development includes the optimization of the reagent concentration and temperature. The kinetic parameters of the reaction are reported and a rate equation is suggested. The effects of certain foreign ions upon the reaction rate were determined for the assessment of the selectivity of the method. The new developed method was found to have fairly good selectivity, sensitivity, simplicity and rapidity.


1970 ◽  
Vol 24 ◽  
pp. 1809-1818 ◽  
Author(s):  
Gösta Pettersson ◽  
Arne Holm ◽  
Erling Nilsson ◽  
S. Liaaen-Jensen ◽  
Aud Lamvik ◽  
...  

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
J. P. Abraham ◽  
J. M. Gorman ◽  
F. Reseghetti ◽  
E. M. Sparrow ◽  
W. J. Minkowycz

Computational fluid dynamic techniques have been applied to the determination of drag on oceanographic devices (expendable bathythermographs). Such devices, which are used to monitor changes in ocean heat content, provide information that is dependent on their drag coefficient. Inaccuracies in drag calculations can impact the estimation of ocean heating associated with global warming. Traditionally, ocean-heating information was based on experimental correlations which related the depth of the device to the fall time. The relation of time-depth is provided by a fall-rate equation (FRE). It is known that FRE depths are reasonably accurate for ocean environments that match the experiments from which the correlations were developed. For other situations, use of the FRE may lead to depth errors that preclude XBTs as accurate oceanographic devices. Here, a CFD approach has been taken which provides drag coefficients that are used to predict depths independent of an FRE.


Author(s):  
Meghmala R. Sangvikar ◽  
Gayatri M. Phadnaik ◽  
Omprakash S. Chavan

The kinetics of DMSO (dimethylsulphoxide) assisted one pot cyclocondensation of bisanilino disulphide and 1,3-dicarbonyls has been investigated using spectral method. The kinetic measurements have been carried by varying media, temperature and concentration of the reactants. The assistance of DMSO is investigated. The order of reaction, effects of substituents with dicarbonyls on the rates and thermodynamic parameters has also been reported. First time reaction conditions are optimised for performing the cyclocondensation conveniently and rapidly. Probably mechanism has been proposed and order of reaction was determined on the basis of rate expression and was in agreement with second order rate equation, used for the determination of rate constants.


Author(s):  
William J. Hankins ◽  
Robert A. Frederick ◽  
David M. Lineberry
Keyword(s):  

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