Luminescence Linewidth Broadening and Nonradiative Energy Transfer Studies of Solid UO2+2-Datura

1992 ◽  
Vol 46 (9) ◽  
pp. 1376-1381 ◽  
Author(s):  
Huei-Yang D. Ke ◽  
Gary D. Rayson
Keyword(s):  
Energy Transfer ◽  
Emission Spectra ◽  
Blue Shift ◽  
Liquid Nitrogen Temperature ◽  
Peak Position ◽  
Nonradiative Energy Transfer ◽  
Wall Material ◽  
Transfer Model ◽  
Solution Ph ◽  
Linewidth Broadening

The emission spectra and fluorescence decay curves of solid UO2+2- Datura at liquid nitrogen temperature have been measured. The linewidth of the emission peaks of UO2+2 ions in UO2+2- Datura decreases with the UO2+2 concentration. This linewidth broadening phenomenon can be explained by the existence of resonance interactions between adjacent UO2+2- Datura species. The analysis of the emission peak position of the bound ions has been used to provide a measure of the electronic factors contributing to the interaction between the uranyl ion and phosphoryl and dicarboxyl moieties on the cell wall material. An observed blue shift of the uranyl fluorescence spectrum as a function of solution pH has been ascribed to a distortion of the normally linear O-U-O bond. An inter- and intra-molecular nonradiative energy transfer model has been successfully used to interpret the measured lifetime data of UO2+2- Datura.

scholarly journals Dynamics of the Green and Red Upconversion Emissions inYb3+-Er3+-CodopedY2O3Nanorods

2010 ◽  
Vol 2010 ◽  
pp. 1-8 ◽  
Author(s):  
O. Meza ◽  
L. A. Diaz-Torres ◽  
P. Salas ◽  
C. Angeles-Chavez ◽  
A. Martínez ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Excellent Agreement ◽  
Upconversion Emission ◽  
Nonradiative Energy Transfer ◽  
Transfer Model ◽  
Solvent Ratio ◽  
Upconversion Emissions ◽  
Transfer Mechanisms ◽  
Energy Transfer Model ◽  
Experimental Decay

Efficient green and red upconversion emission inY2O3:Yb3+,Er3+nanorods under 978 nm radiation excitation is achieved. Experimental effective lifetimes, luminescent emissions, and nanorod sizes depend strongly on the solvent ratios used during the synthesis. A microscopic nonradiative energy transfer model is used to approach the dynamics of the green, red, and infrared emissions. The excellent agreement between simulated and experimental decay suggests that the energy transfer mechanisms responsible of the visible emission depend on the solvent ratio.

Recent Applications of Nonradiative Energy Transfer to Polymer Studies

1993 ◽  
Vol 58 (10) ◽  
pp. 2266-2271 ◽  
Author(s):  
Herbert Morawetz
Keyword(s):  
Energy Transfer ◽  
Polymer Chain ◽  
Cluster Formation ◽  
Nonradiative Energy Transfer ◽  
Molecular Cluster ◽  
Fluorescent Labels ◽  
Latex Particles ◽  
Polymer Latex

Recent studies of polymers in solution and in bulk by energy transfer between two fluorescent labels are reviewed. Such studies are concerned with the equilibrium and dynamics of polymer chain expansion, molecular cluster formation in solution, the miscibility of polymers in bulk, and the interdiffusion of polymer latex particles.

scholarly journals Partial Energy Transfer Model of Lamb Waves Scattering in Materially Isotropic Waveguides

2021 ◽  
Vol 11 (10) ◽  
pp. 4508
Author(s):  
Pavel Šofer ◽  
Michal Šofer ◽  
Marek Raček ◽  
Dawid Cekus ◽  
Paweł Kwiatoń
Keyword(s):  
Energy Transfer ◽  
Lamb Waves ◽  
Hybrid Approach ◽  
Wave Mode ◽  
Transfer Model ◽  
Material Interface ◽  
Modal Expansion ◽  
Scattering Coefficients ◽  
Expansion Technique ◽  
Partial Energy

The scattering phenomena of the fundamental antisymmetric Lamb wave mode with a horizontal notch enabling the partial energy transfer (PET) option is addressed in this paper. The PET functionality for a given waveguide is realized using the material interface. The energy scattering coefficients are identified using two methods, namely, a hybrid approach, which utilizes the finite element method (FEM) and the general orthogonality relation, and the semi-analytical approach, which combines the modal expansion technique with the orthogonal property of Lamb waves. Using the stress and displacement continuity conditions on the present (sub)waveguide interfaces, one can explicitly derive the global scattering matrix, which allows detailed analysis of the scattering process across the considered interfaces. Both methods are then adopted on a simple representation of a surface breaking crack in the form of a vertical notch, of which a certain section enables not only the reflection of the incident energy, but also its nonzero transfer. The presented results show very good conformity between both utilized approaches, thus leading to further development of an alternative technique.

scholarly journals Melt-Spun Photoluminescent Polymer Optical Fibers for Color-Tunable Textile Illumination

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1740
Author(s):  
Konrad Jakubowski ◽  
Manfred Heuberger ◽  
Rudolf Hufenus
Keyword(s):  
Energy Transfer ◽  
Optical Fibers ◽  
Color Space ◽  
Emission Spectra ◽  
Wide Range ◽  
Color Tunable ◽  
Melt Spun ◽  
Polymer Optical Fibers ◽  
Collective Emission ◽  
Down Conversion

The increasing interest in luminescent waveguides, applied as light concentrators, sensing elements, or decorative illuminating systems, is fostering efforts to further expand their functionality. Yarns and textiles based on a combination of distinct melt-spun polymer optical fibers (POFs), doped with individual luminescent dyes, can be beneficial for such applications since they enable easy tuning of the color of emitted light. Based on the energy transfer occurring between differently dyed filaments within a yarn or textile, the collective emission properties of such assemblies are adjustable over a wide range. The presented study demonstrates this effect using multicolor, meltspun, and photoluminescent POFs to measure their superimposed photoluminescent emission spectra. By varying the concentration of luminophores in yarn and fabric composition, the overall color of the resulting photoluminescent textiles can be tailored by the recapturing of light escaping from individual POFs. The ensuing color space is a mean to address the needs of specific applications, such as decorative elements and textile illumination by UV down-conversion.

scholarly journals Upconversion Luminescence of Silica–Calcia Nanoparticles Co-doped with Tm3+ and Yb3+ Ions

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 937
Author(s):  
Katarzyna Halubek-Gluchowska ◽  
Damian Szymański ◽  
Thi Ngoc Lam Tran ◽  
Maurizio Ferrari ◽  
Anna Lukowiak
Keyword(s):  
Energy Transfer ◽  
Near Infrared ◽  
Upconversion Luminescence ◽  
Sol Gel ◽  
Emission Spectra ◽  
Transmission Electron ◽  
Characteristic Emission ◽  
Diffraction Patterns ◽  
Size Of Particles ◽  
Average Size

Looking for upconverting biocompatible nanoparticles, we have prepared by the sol–gel method, silica–calcia glass nanopowders doped with different concentration of Tm3+ and Yb3+ ions (Tm3+ from 0.15 mol% up to 0.5 mol% and Yb3+ from 1 mol% up to 4 mol%) and characterized their structure, morphology, and optical properties. X-ray diffraction patterns indicated an amorphous phase of the silica-based glass with partial crystallization of samples with a higher content of lanthanides ions. Transmission electron microscopy images showed that the average size of particles decreased with increasing lanthanides content. The upconversion (UC) emission spectra and fluorescence lifetimes were registered under near infrared excitation (980 nm) at room temperature to study the energy transfer between Yb3+ and Tm3+ at various active ions concentrations. Characteristic emission bands of Tm3+ ions in the range of 350 nm to 850 nm were observed. To understand the mechanism of Yb3+–Tm3+ UC energy transfer in the SiO2–CaO powders, the kinetics of luminescence decays were studied.

scholarly journals The Optical Properties of InGaN/GaN Nanorods Fabricated on (-201) β-Ga2O3 Substrate for Vertical Light Emitting Diodes

Photonics ◽  
2021 ◽  
Vol 8 (2) ◽  
pp. 42
Author(s):  
Jie Zhao ◽  
Weijiang Li ◽  
Lulu Wang ◽  
Xuecheng Wei ◽  
Junxi Wang ◽  
...  
Keyword(s):  
Stark Effect ◽  
Light Emitting Diodes ◽  
Light Emitting Diode ◽  
Strain Relaxation ◽  
Blue Shift ◽  
Peak Position ◽  
Excitation Power ◽  
Light Extraction Efficiency ◽  
Excitation Power Density ◽  
Light Emitting

We fabricated InGaN/GaN nanorod light emitting diode (LED) on (-201) β-Ga2O3 substrate via the SiO2 nanosphere lithography and dry-etching techniques. The InGaN/GaN nanorod LED grown on β-Ga2O3 can effectively suppress quantum confined Stark effect (QCSE) compared to planar LED on account of the strain relaxation. With the enhancement of excitation power density, the photoluminescence (PL) peak shows a large blue-shift for the planar LED, while for the nanorod LED, the peak position shift is small. Furthermore, the simulations also show that the light extraction efficiency (LEE) of the nanorod LED is approximately seven times as high as that of the planar LED. Obviously, the InGaN/GaN/β-Ga2O3 nanorod LED is conducive to improving the optical performance relative to planar LED, and the present work may lay the groundwork for future development of the GaN-based vertical light emitting diodes (VLEDs) on β-Ga2O3 substrate.

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