Oxidation of Cinacalcet Hydrochloride by Chloramine-B in
Acid Medium: A Kinetic and Mechanistic Study
Keyword(s):
Rate Law
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Kinetic and mechanistic study of cinacalcet hydrochloride by chloramine-B (CAB) in HCl medium at 308 K was the aim of this work. Analyzed the reaction at five different temperatures and determined the thermodynamic parameters using Arrhenius plots. The reaction had a stoichiometry of 1:2 and characterized the oxidation product using chromatographic and spectroscopic methods. The rate law is deduced from the marked effects, which were accompanied by plausible mechanisms.
1982 ◽
Vol 47
(10)
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pp. 2746-2748
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2011 ◽
Vol 4
(4)
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pp. 427-435
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1978 ◽
Vol 23
(2)
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pp. 103-107
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2009 ◽
Vol 39
(10)
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pp. 645-650
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2015 ◽
Vol 6
(1)
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pp. 106
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