Kinetic and Mechanism of Uncatalytic Oxidation of Dl-Threonine by Cerium (Iv) in Aqueous Acid Medium
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Kinetic of uncatalyzed oxidation of DL-Threonine has been studied by Ce (IV) in acidic medium has been investigatigated by spectrophotometer technique. The rate of reaction determined at three different temperatures ranging from 298 K to 318 K at the interval of 10 K. The reaction has been found to be a first order reaction in presence or in absence of KCl, CTAB, and SDS. The rate constant, decreases with increasing the concentration of [HSO4-] and [H+] ion. The various thermodynamic parameters were calculated at 298 K, 308 K and 318 K. The proposed mechanism and results is discussed.
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2013 ◽
Vol 380-384
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pp. 4395-4399
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2019 ◽
Vol 9
(1)
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pp. 159-164
1985 ◽
Vol 9
(3)
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pp. 203-207
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2019 ◽
1963 ◽
Vol 41
(10)
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pp. 2487-2491
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