scholarly journals Source Identification, Bioavailability, and Risk Assessment based on Geochemical Fractionation of Heavy Metals Pb, Cu, and Zn in Surface Sediments of Kelabat Bay, Bangka Island

2019 ◽  
Vol 24 (3) ◽  
pp. 139
Author(s):  
Mohammad Agung Nugraha ◽  
Mu’alimah Hudatwi ◽  
Fajar Indah Puspita Puspita Sari
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
At Risk ◽  
Surface Sediments ◽  
Anthropogenic Activities ◽  
Residual Fraction ◽  
Risk Assessment Code ◽  
Geochemical Fractionation ◽  
Not At Risk ◽  
Cu And Zn

Although concentrations of many heavy metals has been measured totally, they may not give a good indicator for environmentally hazard to organism. The purpose of this study is to identify sources, determine bioavailability, and assess risk based on the geochemical fractionation of heavy metals Pb, Cu and Zn on the surface sediments of Kelabat Bay, Bangka Island. Fractionation of heavy metals was analyzed by sequential extraction. The concentrations of heavy metals Pb, Cu, and Zn in sediments ranged from 8.86-29.21 mg.kg-1 (average 16.85 mg /kg), 0.16-9.54 mg.kg-1 (average 4.39 mg.kg-1), and 25.58-237.24 mg.kg-1 (average 71.99 mg.kg-1). Pb and Zn in Kelabat Bay are more bound to non-residual fractions (F1+F2+F3) or non-resistant with a range of 60.63-89.87% and 47.98-84.66% that are mainly come from anthropogenic activities. Cu tend to be stored or bound to the residual fraction (F4) with a proportion of 97.7-100% meaning that it comes from natural sources. Based on the Risk Assessment Code (RAC), Pb have a low to moderate risk in the environment and Zn heavy metals are not at risk to low. These conditions indicate the potential for biological availability (bioavailability) of Pb and Zn in the inner bay waters. For heavy metals Cu is not at risk in the environment.

scholarly journals Sequential extraction and risk assessment of pollutants from one major tributary of the Ganga

2021 ◽  
Author(s):  
Vinay Kumar ◽  
Pokhraj Sahu ◽  
Markandeya
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
High Risk ◽  
Sequential Extraction ◽  
Hierarchical Cluster ◽  
Residual Fraction ◽  
Toxic Heavy Metals ◽  
Risk Assessment Code ◽  
Bed Sediments ◽  
Gomti River

Abstract The geochemical fractionation of toxic heavy metals Cd, Pb, Cr, Co, Mn, Ni, Cu, Fe and Zn was investigated in 10 different sites of river bed sediments (up, mid and downstream) of Gomti River at Lucknow city. Sequential extraction technique was used to identify the distribution of trace elements binding in different fractions i.e., exchangeable, carbonate, Fe and Mn oxide, organic matter and residual. Heavy metal concentrations were least at upstream and significantly higher in mid and downstream. Fractionation indicated that dominant metals were bound in residual fraction to the bed sediments except for Cd and Pb which were bound in an equivalent fraction. Geo-accumulation index factor reveals that the enrichment of heavy metals in the bio-available fraction is contributed anthropogenically. Hierarchical cluster analysis also shows the metal pollution load in the river. Risk assessment code of Cd and Ni showed very high risk (ranged from 54.41 to 85.56 and 20.57 to 44.92 respectively) followed by Pb (high risk), Zn, Co (medium risk), Cr, Mn, Cu, Fe (low risk) in Gomti River water. Further, concentrations of Cd and Pb at mid Lucknow were 31 and 75%, high enough to pose a substantial risk to the environment.

scholarly journals Distribution characteristics, source identification, and risk assessment of heavy metals in surface sediments of the salt lakes in the Ordos Plateau, China

2021 ◽  
Author(s):  
Shengyin Zhang ◽  
Shuncun Zhang ◽  
Yongxin Chen ◽  
Bo Chen ◽  
Tianzhu Lei
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Surface Sediments ◽  
Dust Storms ◽  
Water Soluble ◽  
Salt Lakes ◽  
Alkaline Ph ◽  
Sediment Samples ◽  
Ordos Plateau ◽  
Cu And Zn

Abstract Salt lakes have a significant effect on the regional climate, environment, and ecology in semi-arid regions characterized by lower rainfall and high evaporation. However, under the stresses of global change and human disturbance, anthropogenic pollution is the main factor threatening the lake ecological environment. Surface sediment samples collected from four salt lakes in the Ordos Plateau were used to investigate the salinity, concentration, pollution status, potential sources of heavy metals, and influencing factors. The surface sediments of Beida Pond and Gouchi Pond were weakly alkaline (pH < 9) owing to Na2SO4, whereas those of Chaigannaoer and Hongjiannao were strongly alkaline (pH > 9) owing to Na2CO3. The concentration range of Cr, Ni, Cu, Zn, As, Cd, and Pb in the sediment samples collected from the salt lake in the Ordos followed the order of Cr > Zn > Ni > Pb > Cu > As > Cd. The Cr values were higher in Chagannaoer and Hongjiannao, but the Ni, Cu, and Zn values were higher in Beida Pond and Gouchi Pond. The geoaccumulation index (Igeo) and enrichment factor (EF) consistently indicated that Cr posed the greatest potential ecological risk and that Ni, Cu, and Zn pollution was more severe in Beida Pond and Gouchi Pond than in Chagannaoer or Hongjiannao. However, Er and RI indicated these heavy metals were a low risk to the environment. Risk assessment code (RAC) revealed that Pb and Cr exhibited no mobility and had low potential bioavailability risk, although Zn, Ni, and As were categorized as medium risk. Cu had the highest mobility and high risk. Principal component analysis for Beida Pond and Gouchi Pond revealed that the source of Ni, Cu, Zn, Cd, and Pb might be associated with water - soluble elements in aqueous migration, and the source of Cr, Pb, and As might be lithospheric minerals carried by dust storms. Ni, Cu, Zn, Cd, Cr, and Pb in Chagannaoer and Hongjiannao may be derived from surface runoff, and chemicals from these sources may eventually accumulate in sediments. Pearson’s correlation analysis indicated that pH was the main environmental factor controlling the distribution of heavy metals in Chagannaoer and Hongjiannao.

scholarly journals Distribution characteristics, source identification, and risk assessment of heavy metals in surface sediments of the salt lakes in the Ordos Plateau, China

2021 ◽  
Author(s):  
Shengyin Zhang ◽  
Shuncun Zhang ◽  
Yongxin Chen ◽  
Bo Chen ◽  
Tianzhu Lei
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Surface Sediments ◽  
Dust Storms ◽  
Water Soluble ◽  
Salt Lakes ◽  
Alkaline Ph ◽  
Sediment Samples ◽  
Ordos Plateau ◽  
Cu And Zn

Abstract Salt lakes have a significant effect on the regional climate, environment, and ecology in semi-arid regions characterized by lower rainfall and high evaporation. However, under the stresses of global change and human disturbance, anthropogenic pollution is the main factor threatening the lake ecological environment. Surface sediment samples collected from four salt lakes in the Ordos Plateau were used to investigate the salinity, concentration, pollution status, potential sources of heavy metals, and influencing factors. The surface sediments of Beida Pond and Gouchi Pond were weakly alkaline (pH < 9) owing to Na2SO4, whereas those of Chaigannaoer and Hongjiannao were strongly alkaline (pH > 9) owing to Na2CO3. The concentration range of Cr, Ni, Cu, Zn, As, Cd, and Pb in the sediment samples collected from the salt lake in the Ordos followed the order of Cr > Zn > Ni > Pb > Cu > As > Cd. The Cr values were higher in Chagannaoer and Hongjiannao, but the Ni, Cu, and Zn values were higher in Beida Pond and Gouchi Pond. The geoaccumulation index (Igeo) and enrichment factor (EF) consistently indicated that Cr posed the greatest potential ecological risk and that Ni, Cu, and Zn pollution was more severe in Beida Pond and Gouchi Pond than in Chagannaoer or Hongjiannao. However, Er and RI indicated these heavy metals were a low risk to the environment. Risk assessment code (RAC) revealed that Pb and Cr exhibited no mobility and had low potential bioavailability risk, although Zn, Ni, and As were categorized as medium risk. Cu had the highest mobility and high risk. Principal component analysis for Beida Pond and Gouchi Pond revealed that the source of Ni, Cu, Zn, Cd, and Pb might be associated with water - soluble elements in aqueous migration, and the source of Cr, Pb, and As might be lithospheric minerals carried by dust storms. Ni, Cu, Zn, Cd, Cr, and Pb in Chagannaoer and Hongjiannao may be derived from surface runoff, and chemicals from these sources may eventually accumulate in sediments. Pearson’s correlation analysis indicated that pH was the main environmental factor controlling the distribution of heavy metals in Chagannaoer and Hongjiannao .

scholarly journals Distribution characteristics, source identification, and risk assessment of heavy metals in surface sediments of the salt lakes in the Ordos Plateau, China

2021 ◽  
Author(s):  
Shengyin Zhang ◽  
Shuncun Zhang ◽  
Yongxin Chen ◽  
Bo Chen ◽  
Tianzhu Lei
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Surface Sediments ◽  
Dust Storms ◽  
Water Soluble ◽  
Salt Lakes ◽  
Alkaline Ph ◽  
Sediment Samples ◽  
Ordos Plateau ◽  
Cu And Zn

Abstract Salt lakes have a significant effect on the regional climate, environment, and ecology in semi-arid regions characterized by lower rainfall and high evaporation. However, under the stresses of global change and human disturbance, anthropogenic pollution is the main factor threatening the lake ecological environment. Surface sediment samples collected from four salt lakes in the Ordos Plateau were used to investigate the salinity, concentration, pollution status, potential sources of heavy metals, and influencing factors. The surface sediments of Beida Pond and Gouchi Pond were weakly alkaline (pH < 9) owing to Na2SO4, whereas those of Chaigannaoer and Hongjiannao were strongly alkaline (pH > 9) owing to Na2CO3. The concentration range of Cr, Ni, Cu, Zn, As, Cd, and Pb in the sediment samples collected from the salt lake in the Ordos followed the order of Cr > Zn > Ni > Pb > Cu > As > Cd. The Cr values were higher in Chagannaoer and Hongjiannao, but the Ni, Cu, and Zn values were higher in Beida Pond and Gouchi Pond. The geoaccumulation index (Igeo) and enrichment factor (EF) consistently indicated that Cr posed the greatest potential ecological risk and that Ni, Cu, and Zn pollution was more severe in Beida Pond and Gouchi Pond than in Chagannaoer or Hongjiannao. However, Er and RI indicated these heavy metals were a low risk to the environment. Risk assessment code (RAC) revealed that Pb and Cr exhibited no mobility and had low potential bioavailability risk, although Zn, Ni, and As were categorized as medium risk. Cu had the highest mobility and high risk. Principal component analysis for Beida Pond and Gouchi Pond revealed that the source of Ni, Cu, Zn, Cd, and Pb might be associated with water - soluble elements in aqueous migration. For Cr, Pb, and As, it was indicated that the source of these heavy metals might be lithospheric minerals carried by dust storms. Ni, Cu, Zn, Cd, Cr, and Pb in Chagannaoer and Hongjiannao may be derived from surface runoff, and chemicals from these sources may eventually accumulate in sediments. Pearson’s correlation analysis indicated that pH was the main environmental factor controlling the distribution of heavy metals in Chagannaoer and Hongjiannao.

scholarly journals Distribution and Risk Assessment of Heavy Metals in Sediment from Bohai Bay, China

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 111 ◽  
Author(s):  
Baolin Liu ◽  
Wensi Zhang ◽  
Guangxi Chi
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Chemical Properties ◽  
Local Environment ◽  
Anthropogenic Sources ◽  
Residual Fraction ◽  
Bohai Bay ◽  
Risk Assessment Code ◽  
Bcr Sequential Extraction ◽  
The Core

Sediment core and porewater samples from the Western coastal tidal flat in Bohai Bay, China, were collected for meals and physical-chemical properties analysis. The vertical distribution characteristics of eight metals along the core was investigated based on 137Cs and 210Pb radionuclide dating. The chemical fractions of six metals (Cu, Pb, Zn, Ni, Mn and Cd) were also measured based on the modified European Community Bureau of Reference (BCR) sequential extraction procedures to better understand the mobility and bioavailability of these metals in the sediment. In addition, geoaccumulation index (Igeo) and risk assessment code (RAC) are used to assess risk status of these metals in the environment. 210Pb measurement indicates a sedimentation rate of about −1.87 cm∙year−1. The metals Cu, Zn, Pb and Ni show similar vertical distributions throughout the core, while Mn and Cd show different distribution patterns. Ni, Cu, Pb and Zn are strongly associated with the residual fraction while Mn and Cd are dominant in the acid-soluble fraction. According to the estimated diffusive fluxes, the Zn ions were the most mobilized, followed by Cu, Ni, Pb, and to a lesser extent Cd. The result of Igeo shows that Ni in sediments does not reflect any pollution, and Cu, Pb and Zn are in a level from unpolluted to modest polluted throughout the core. Mn and Cd have obvious anthropogenic sources. Based on the RAC, Cd and Mn pose a high to very high risk to the local environment, respectively, due to the significant percentage of exchangeable fraction. Clay content is significantly positively correlated with Ni, Cu, Al and Fe, and Cu, Pb, Zn and Ni might originate from the same sources or be influenced by similar geochemical processes. River runoff and atmospheric deposition are important sources for heavy metals, and since 1998, domestic sewage discharge might have had an important influence on the source of heavy metals (except for Cd and Mn).

scholarly journals Distribution characteristics, source identification, and risk assessment of heavy metals in surface sediments of the salt lakes in the Ordos Plateau, China

2021 ◽  
Author(s):  
Shengyin Zhang ◽  
Shuncun Zhang ◽  
Yongxin Chen ◽  
Bo Chen ◽  
Tianzhu Lei
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Surface Sediments ◽  
Dust Storms ◽  
Water Soluble ◽  
Salt Lakes ◽  
Alkaline Ph ◽  
Sediment Samples ◽  
Ordos Plateau ◽  
Cu And Zn

Abstract Salt lakes have a significant effect on the regional climate, environment, and ecology in semi-arid regions characterized by lower rainfall and high evaporation. However, under the stresses of global change and human disturbance, anthropogenic pollution is the main factor threatening the lake ecological environment. Surface sediment samples collected from four salt lakes in the Ordos Plateau were used to investigate the salinity, concentration, pollution status, potential sources of heavy metals, and influencing factors. The surface sediments of Beida Pond and Gouchi Pond were weakly alkaline (pH < 9) owing to Na2SO4, whereas those of Chaigannaoer and Hongjiannao were strongly alkaline (pH > 9) owing to Na2CO3. The concentration range of Cr, Ni, Cu, Zn, As, Cd, and Pb in the sediment samples collected from the salt lake in the Ordos followed the order of Cr > Zn > Ni > Pb > Cu > As > Cd. The Cr values were higher in Chagannaoer and Hongjiannao, but the Ni, Cu, and Zn values were higher in Beida Pond and Gouchi Pond. The geoaccumulation index (Igeo) and enrichment factor (EF) consistently indicated that Cr posed the greatest potential ecological risk and that Ni, Cu, and Zn pollution was more severe in Beida Pond and Gouchi Pond than in Chagannaoer or Hongjiannao. However, Er and RI indicated these heavy metals were a low risk to the environment. Risk assessment code (RAC) revealed that Pb and Cr exhibited no mobility and had low potential bioavailability risk, although Zn, Ni, and As were categorized as medium risk. Cu had the highest mobility and high risk. Principal component analysis for Beida Pond and Gouchi Pond revealed that the source of Ni, Cu, Zn, Cd, and Pb might be associated with water - soluble elements in aqueous migration. For Cr, Pb, and As, it was indicated that the source of these heavy metals might be lithospheric minerals carried by dust storms. Ni, Cu, Zn, Cd, Cr, and Pb in Chagannaoer and Hongjiannao may be derived from surface runoff, and chemicals from these sources may eventually accumulate in sediments. Pearson’s correlation analysis indicated that pH was the main environmental factor controlling the distribution of heavy metals in Chagannaoer and Hongjiannao.

scholarly journals Geochemical Mapping, Risk Assessment, and Source Identification of Heavy Metals in Road Dust Using Positive Matrix Factorization (PMF)

Atmosphere ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 614
Author(s):  
Muhammad Faisal ◽  
Zening Wu ◽  
Huiliang Wang ◽  
Zafar Hussain ◽  
Chenyang Shen
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Matrix Factorization ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Road Dust ◽  
Positive Matrix Factorization ◽  
Prevention Measures ◽  
Positive Matrix ◽  
The City

Heavy metals in road dust pose a significant threat to human health. This study investigated the concentrations, patterns, and sources of eight hazardous heavy metals (Cr, Ni, Cu, Zn, As, Cd, Pb, and Hg) in the street dust of Zhengzhou city of PR China. Fifty-eight samples of road dust were analyzed based on three methods of risk assessment, i.e., Geo-Accumulation Index (Igeo), Potential Ecological Risk Assessment (RI), and Nemerow Synthetic Pollution Index (PIN). The results exhibited higher concentrations of Hg and Cd 14 and 7 times higher than their background values, respectively. Igeo showed the risks of contamination in a range of unpolluted (Cr, Ni) to strongly polluted (Hg and Cd) categories. RI came up with the contamination ranges from low (Cr, Ni, Cu, Zn, As, and Pb) to extreme (Cd and Hg) risk of contamination. The risk of contamination based on PIN was from safe (Cu, As, and Pb) to seriously high (Cd and Hg). The results yielded by PIN indicated the extreme risk of Cd and Hg in the city. Positive Matrix Factorization was used to identify the sources of contamination. Factor 1 (vehicular exhaust), Factor 2 (coal combustion), Factor 3 (metal industry), and Factor 4 (anthropogenic activities), respectively, contributed 14.63%, 35.34%, 36.14%, and 13.87% of total heavy metal pollution. Metal’s presence in the dust is a direct health risk for humans and warrants immediate and effective pollution control and prevention measures in the city.

scholarly journals An Assessment of Heavy Metal Contamination in the Nakdong River Around the Weir

Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 684
Author(s):  
Hee Won Son ◽  
Sun Hee Shim ◽  
Haeseong Oh ◽  
Jung Hyun Choi
Keyword(s):  
Heavy Metals ◽  
Sequential Extraction ◽  
Environmental Protection Agency ◽  
Heavy Metal Contamination ◽  
Environmental Research ◽  
Residual Fraction ◽  
Nakdong River ◽  
Risk Assessment Code ◽  
The Nakdong River ◽  
Reducible Fraction

In this study, the concentrations and characteristics of copper (Cu), zinc (Zn), and lead (Pb) contamination in sediment samples were investigated using aqua regia extraction and Tessier’s five-step sequential extraction. Based on the concentration of metals, the influence of the Hapcheon-Changnyeong weir on sediments in the Nakdong River was assessed. The origins of the contaminants, their bioavailability, and their mobility were determined using sequential extraction. Greater concentrations of heavy metals were found in samples collected closer to the weir. The largest proportion of Cu was identified in the residual fraction based on sequential extraction, whereas Zn was predominantly found in the reducible fraction. Iron-manganese in the reducible fraction of Zn has the potential to leach back to the water body. In addition, the combined concentration of fractions 1 and 2 of Cu comprised more than 20% of total amount that still has potential to affect the water quality. The results of this study were compared with existing sediment standards set out by the NIER (National Institute of Environmental Research), Canada, and US EPA (United States Environmental Protection Agency) guidelines, as well as the risk assessment code (RAC). The concentrations of heavy metals exceeded the standards set by the Canadian guideline by up to four times in particular samples, highlighting the need for continual monitoring.

scholarly journals Environmental Risk Assessment of Petroleum Activities in Surface Sediments, Suez Gulf, Egypt

2021 ◽  
Vol 9 (5) ◽  
pp. 473
Author(s):  
Magda M. Abou El-Safa ◽  
Mohamed Gad ◽  
Ebrahem M. Eid ◽  
Ashwaq M. Alnemari ◽  
Mohammed H. Almarshadi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Heavy Metal ◽  
Surface Sediment ◽  
Surface Sediments ◽  
Surf Zone ◽  
Risk Index ◽  
Negative Relationship ◽  
Anthropogenic Sources ◽  
Suez Gulf

The present study focuses on the risk assessment of heavy metal contamination in aquatic ecosystems by evaluating the current situation of heavy metals in seven locations (North Amer El Bahry, Amer, Bakr, Ras Gharib, July Water Floud, Ras Shokeir, and El Marageen) along the Suez Gulf coast that are well-known representative sites for petroleum activities in Egypt. One hundred and forty-six samples of surface sediments were carefully collected from twenty-seven profiles in the intertidal and surf zone. The hydrochemical parameters, such as pH and salinity (S‰), were measured during sample collection. The mineralogy study was carried out by an X-ray diffractometer (XRD), and the concentrations of Al, Mn, Fe, Cr, Cu, Co, Zn, Cd, and Pb were determined using inductively coupled plasma mass spectra (ICP-MS). The ecological risks of heavy metals were assessed by applying the contamination factor (CF), enrichment factor (EF), geoaccumulation index (Igeo), pollution load index (PLI), and potential ecological risk index (RI). The mineralogical composition mainly comprised quartz, dolomites, calcite, and feldspars. The average concentrations of the detected heavy metals, in descending order, were Al > Fe > Mn > Cr > Pb > Cu > Zn > Ni > Co > Cd. A non-significant or negative relationship between the heavy metal concentration in the samples and their textural grain size characteristics was observed. The coastal surface sediment samples of the Suez Gulf contained lower concentrations of heavy metals than those published for other regions in the world with petroleum activities, except for Al, Mn, and Cr. The results for the CF, EF, and Igeo showed that Cd and Pb have severe enrichment in surface sediment and are derived from anthropogenic sources, while Al, Mn, Fe, Cr, Co, Ni, Cu, and Zn originate from natural sources. By comparison, the PLI and RI results indicate that the North Amer El Bahry and July Water Floud are considered polluted areas due to their petroleum activities. The continuous monitoring and assessment of pollutants in the Suez Gulf will aid in the protection of the environment and the sustainability of resources.

scholarly journals Reforestation Impacted Soil Heavy Metal Fractionation and Related Risk Assessment in the Karst Area, Southwest China

Forests ◽  
2021 ◽  
Vol 12 (7) ◽  
pp. 891
Author(s):  
Qian Zhang ◽  
Guilin Han ◽  
Xingliang Xu
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Ecological Risk ◽  
Southwest China ◽  
Risk Index ◽  
Contamination Factor ◽  
Karst Area ◽  
Risk Assessment Code ◽  
Bcr Sequential Extraction ◽  
Soil Heavy Metals

Human agricultural activities have resulted in widespread land degradation and soil contamination in the karst areas. However, the effects of reforestation after agricultural abandonment on the mobility risks and contamination of heavy metals have been rarely reported. In the present study, six soil profiles were selected from cropland and abandoned cropland with reforestation in the Puding karst regions of Southwest China. The Community Bureau of Reference (BCR) sequential extraction method was used to evaluate the compositions of different chemical fractions of soil heavy metals, including Fe, Mn, Cr, Zn, Ni, and Cd. The total contents of Cr, Ni, Zn, Cd, and Mn in the croplands were significantly higher than those in the abandoned croplands. For all soils, Cr, Ni, Zn, and Fe were mainly concentrated in the residual fractions (>85%), whereas Mn and Cd were mostly observed in the non-residual fractions (>65%). The non-residual fractions of Cd, Cr, Ni, and Zn in the croplands were higher than those in the abandoned croplands. These results indicated that the content and mobility of soil heavy metals decreased after reforestation. The individual contamination factor (ICF) and risk assessment code (RAC) showed that Cd contributed to considerable contamination of karst soils. The global contamination factor (GCF) and potential ecological risk index (RI) suggested low contamination and ecological risk of the investigated heavy metals in the croplands, moreover they can be further reduced after reforestation.

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