scholarly journals Development of a Fast Simultaneous Analysis Method for Determination of Middle Rare-Earth Elements in Monazite Samples

2021 ◽  
Vol 24 (5) ◽  
pp. 177-184
Author(s):  
Heru Agung Saputra ◽  
Anni Anggraeni ◽  
Abdul Mutalib ◽  
Husein Hernandi Bahti
Keyword(s):  
Multivariate Analysis ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Good Accuracy ◽  
High Tech ◽  
Analysis Method ◽  
Metallic Elements ◽  
Accuracy And Precision ◽  
Sulfate Hydrate

Rare earth elements are a set of seventeen metallic elements, which is an essential part of many high-tech devices. Hence, analysis and/or separation of the rare earth elements from their mineral become crucial. A novel analysis method combining ultraviolet-visible spectroscopic and multivariate analysis was developed to determine middle rare earth elements quickly and simultaneously. The data collected from ultraviolet-visible spectroscopic were analyzed by multivariate analysis. The results showed that the developed method has good accuracy and precision with a detection limit of 1.375 (± 0.012), 0.332 (± 0.004), 42.117 (± 0.200), 1.767 (± 0.011), and 0.576 (± 0.002) ppm, respectively for samarium, europium, gadolinium, terbium, and dysprosium. The interference effect of ammonium iron(II) sulfate hexahydrate, manganese(III) sulfate hydrate, calcium carbonate, sodium carbonate, and lead(II) nitrate were examined. The reliability of the proposed method was evaluated using monazite samples. Conclusively, the developed method was successfully applied to determine the middle rare earth elements in monazite samples.

scholarly journals THE NEWEST ANALYTICAL TECHNOLOGIES FOR DETERMINING RARE-EARTH ELEMENTS IN GRANITOIDS OF THE UKRAINIAN SHIELD

2021 ◽  
Vol 17 (1) ◽  
pp. 96-102
Author(s):  
Олександр Пономаренко ◽  
Анатолій Самчук ◽  
Катерина Вовк ◽  
Ольга Заяць ◽  
Ірина Кураєва
Keyword(s):  
Mineral Resource ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Ukrainian Shield ◽  
High Tech ◽  
Resource Base ◽  
Icp Ms ◽  
Relative Standard ◽  
Rare Earth Mineral

Introduction. To date, rare earth elements (REE) are used to manufacture most high-tech goods and are crucial in defense technologies (lasers, radars, and electromagnetic weapons), nuclear engineering, metallurgy, and others. All this determines the relevance of their study to assess the rare earth mineral resource base of Ukraine. Problem Statement. The determination of REE in rocks and minerals is a fundamental problem in geochemistry and petrology for understanding the processes of rock formation. However, it is a complex analytical task related to the similar chemical properties of these elements, which are caused by the "lanthanide compression effect". Purpose. The purpose is to develop analytical technologies for determining REE content by the ICP-MS method, to evaluate their content and distribution in granitoids of the Ukrainian Shield. Materials and Methods. The hybrid method of ICP-MS analysis and microwave decomposition of rocks and minerals has been used to measure the REE content. This technique has been tested and used to estimate the content and distribution of REE in fluorites and rare-metal granitoids of the Rusko-Polyanskyi massif of the Korsun-Novomirgorod pluton of the Ukrainian Shield. Results. Analytical technologies for determination of REE in granites and minerals have been developed. The method for determining REE in fluorites and granites without their prior concentration in the range from 0.01 to 1000 ppm with a relative standard deviation of 0.01–0.10 has been described. The content of rare earth elements in the Rusko-Polianskyi granites increases (218–797 g/t), the main concentrator of these elements is fluorite (692–26933 g/t REE). An inverse relationship has been observed between the REE content in fluorites and granites. Conclusions. The developed analytical technologies are the basis for establishing quality assessment criteria and developing principles for the rational use of rare-earth granitoids to create a rare-earth mineral resource base in Ukraine.

The fluorimetric determination of cerium and terbium

1989 ◽  
Vol 54 (3) ◽  
pp. 616-621 ◽  
Author(s):  
Záviš Holzbecher
Keyword(s):  
Rare Earth ◽  
Detection Limit ◽  
Rare Earth Elements ◽  
Fluorimetric Determination ◽  
Fluorescence Maximum ◽  
Relative Standard ◽  
And Shifts ◽  
Hcl Medium ◽  
Fold Excess

It has been found that phosphoric acid decreases the first excitation maximum of Ce(III) at 256 nm, increases the second excitation maximum at 297 nm and shifts the fluorescence maximum from 350 to 346 nm. Under optimum conditions, with λexc = 297 nm and λem = 346 nm, Ce(III) can be determined fluorimetrically with a detection limit of 1.2 ng ml-1 in 12M-H3PO4 medium. No interference was observed from a 20-200 fold excess of HCl, H2SO4, Na, K, NH4+, Al and the rare earth elements. HNO3 interferes and Ce(IV) and Fe(III) interfere strongly. It follows from the stereofluorograms of Ce and Tb that the spectra of the two elements are practically independent. The detection limit for Tb(III) in 0.02-2.5M-H2SO4 medium for λexc = 222 nm and λem = 494 nm is 33 ng ml-1. No interference was observed from a 5-20 fold excess of Al3+ and the other rare earth elements. The determination is slightly less sensitive in H3PO4 or HCl medium. The relative standard deviation of the measurement for 10 ng ml-1 Ce(III) or 50 ng ml-1 Tb(III) is about 3%.

scholarly journals Editorial for Special Issue “Leaching of Rare Earth Elements from Various Sources”

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 164
Author(s):  
Kenneth N. Han
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
High Strength ◽  
Green Energy ◽  
High Tech ◽  
Special Issue ◽  
Important Group ◽  
Military Applications

Rare earth elements (REEs) have become an important group of metals used in many high-tech industries, including high-strength magnets, plasma TVs, various military applications, and clean and efficient green energy industries [...]

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