Inorganic acids – technology background and future perspectives

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Filip Ciesielczyk
Keyword(s):  
Environmental Impact ◽  
Raw Materials ◽  
Process Conditions ◽  
Future Perspectives ◽  
Main Attention ◽  
Inorganic Acids ◽  
Innovative Solutions ◽  
Scientific Papers ◽  
Acid Anhydrides ◽  
The Individual

AbstractThe presented chapter deals with technological aspects concerning industrial production of major inorganic chemicals such as sulfuric, nitric and phosphorous acids. The idea was to highlight the main assumptions related to their fabrication as well as to point out novel aspects and perspectives concerning their industry. The main attention will be paid to raw materials and their transformation in order to obtain indirect precursors of inorganic acids – acid anhydrides. Characteristics of the individual stages of synthesis, with a special regard to the process conditions will be also of key importance. The environmental impact of this particular technology will be raised and discussed. Finally, the review over recently published scientific papers, concerning innovative solutions in inorganic acids production, will be performed.

scholarly journals New Approach in Research of Quartzes and Quartzites for Ferroalloys and Silicon Production

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 670
Author(s):  
Jaroslav Legemza ◽  
Róbert Findorák ◽  
Branislav Buľko ◽  
Jaroslav Briančin
Keyword(s):  
Raw Materials ◽  
Electricity Consumption ◽  
Process Conditions ◽  
Material Research ◽  
New Approach ◽  
Pure Silicon ◽  
Metallurgical Properties ◽  
Similar Chemical ◽  
The Individual ◽  
Individual Grains

This article deals with material research of selected types of quartz and quartzites in order to determine the priority of their use in the production of ferrosilicon and pure silicon, respectively. The highest quality quartzes and quartzites are commonly used in metallurgy, but not all types of these silicon raw materials are suitable for the production of ferrosilicon and pure silicon, despite their similar chemical composition. Behavior differences can be observed in the process conditions of heating and carbothermic production of ferrosilicon and silicon. These differences depend, in particular, on the nature and content of impurities, and the granularity (lumpiness) and microstructure of individual grains. The research focused primarily on determining the physicochemical and metallurgical properties of silicon raw materials. An integral part of the research was also the creation of a new methodology for determining the reducibility of quartzes (or quartzites), which could be used for real industrial processes and should be very reliable. The results of the laboratory experiments and evaluation of the physicochemical and metallurgical properties of the individual quartzes (or quartzites) are presented in the discussion. Based on comparison of the tested samples’ properties, their priority of use was determined. This research revealed the highest quality in quartzite from Sweden (Dalbo deposit) and Ukraine (Ovruč deposit) and quartz from Slovakia (Švedlár deposit). The use of these raw materials in industrial conditions is expected to result in the achievement of better production parameters, such as higher yield and product quality and lower electricity consumption.

scholarly journals Thermal Characterization of Recycled Materials for Building Insulation

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3564
Author(s):  
Arnas Majumder ◽  
Laura Canale ◽  
Costantino Carlo Mastino ◽  
Antonio Pacitto ◽  
Andrea Frattolillo ◽  
...  
Keyword(s):  
Environmental Impact ◽  
Environmental Sustainability ◽  
Building Materials ◽  
Raw Materials ◽  
Natural Fibers ◽  
Thermal Characterization ◽  
Recycled Materials ◽  
Building Insulation ◽  
Operational Phase

The building sector is known to have a significant environmental impact, considering that it is the largest contributor to global greenhouse gas emissions of around 36% and is also responsible for about 40% of global energy consumption. Of this, about 50% takes place during the building operational phase, while around 10–20% is consumed in materials manufacturing, transport and building construction, maintenance, and demolition. Increasing the necessity of reducing the environmental impact of buildings has led to enhancing not only the thermal performances of building materials, but also the environmental sustainability of their production chains and waste prevention. As a consequence, novel thermo-insulating building materials or products have been developed by using both locally produced natural and waste/recycled materials that are able to provide good thermal performances while also having a lower environmental impact. In this context, the aim of this work is to provide a detailed analysis for the thermal characterization of recycled materials for building insulation. To this end, the thermal behavior of different materials representing industrial residual or wastes collected or recycled using Sardinian zero-km locally available raw materials was investigated, namely: (1) plasters with recycled materials; (2) plasters with natural fibers; and (3) building insulation materials with natural fibers. Results indicate that the investigated materials were able to improve not only the energy performances but also the environmental comfort in both new and in existing buildings. In particular, plasters and mortars with recycled materials and with natural fibers showed, respectively, values of thermal conductivity (at 20 °C) lower than 0.475 and 0.272 W/(m⋅K), while that of building materials with natural fibers was always lower than 0.162 W/(m⋅K) with lower values for compounds with recycled materials (0.107 W/(m⋅K)). Further developments are underway to analyze the mechanical properties of these materials.

Analyzing the Effect of Fiber, Yarn and Fabric Variables on Bagging Behavior of Single Jersey Weft Knitted Fabrics

2013 ◽  
Vol 8 (3) ◽  
pp. 155892501300800 ◽  
Author(s):  
Mitra Karimian ◽  
Hossein Hasani ◽  
Saeed Ajeli
Keyword(s):  
Optimum Process ◽  
Process Conditions ◽  
Knitted Fabrics ◽  
Yarn Twist ◽  
Fabric Density ◽  
Fabric Structure ◽  
Controllable Factors ◽  
Yarn Count ◽  
The Individual ◽  
Single Jersey

This research investigates the effect of fiber, yarn and fabric variables on the bagging behavior of single jersey weft knitted fabrics interpreted in terms of bagging fatigue percentage. In order to estimate the optimum process conditions and to examine the individual effects of each controllable factor on a particular response, Taguchi's experimental design was used. The controllable factors considered in this research are blending ratio, yarn twist and count, fabric structure and fabric density. The findings show that fabric structure has the largest effect on the fabric bagging. Factor yarn twist is second and is followed by fabric density, blend ratio and yarn count. The optimum conditions to achieve the least bagging fatigue ratio were determined.

Synthesis of Polyurethane Dendrimers and Transfer Properties of Dye

2013 ◽  
Vol 457-458 ◽  
pp. 65-71
Author(s):  
Jing Ru Jia
Keyword(s):  
Methyl Orange ◽  
Phase Transfer ◽  
Raw Materials ◽  
Toluene Diisocyanate ◽  
Polymerization Process ◽  
Process Conditions ◽  
Addition Polymerization ◽  
Different Temperatures ◽  
The Difference ◽  
Transfer Properties

The polyfunctional organic compounds 2- hydroxymethyl -1,4- butanediol (trihydric alcohol) and toluene diisocyanate -2, 4- diisocyanate (TDI) were taken as the raw materials in this study. A polyurethane dendrimer was synthesized by utilizing the difference in the reaction activity of two isocyanate groups of TDI at different temperatures. The polymerization process conditions were studied. The addition polymerization of para-position NCO groups occurred at 50 °C, and that of ortho NCO groups occurred at 90 °C. According to the structure of the dendrimer synthesized, methyl orange was used as the guest molecule. Consequently, the aqueous methyl orange showed a phase transfer. With the increase of dendrimer concentration, the transfer rate of methyl orange increased.

Use of Sugarcane Bagasse Ashes as Raw Material in the Replacement of Fluxes for Applications on Porcelain Tile

2016 ◽  
Vol 881 ◽  
pp. 383-386 ◽  
Author(s):  
Raimundo J.S. Paranhos ◽  
Wilson Acchar ◽  
Vamberto Monteiro Silva
Keyword(s):  
Mechanical Properties ◽  
Environmental Impact ◽  
Physical Properties ◽  
Sugarcane Bagasse ◽  
Sintering Temperature ◽  
Raw Materials ◽  
Raw Material ◽  
The Cost ◽  
Potential Use ◽  
Porcelain Tile

This study evaluated the potential use of Sugarcane Bagasse Ashes (SBA) as a flux, replacing phyllite for the production of enamelled porcelain tile. The raw materials of the standard mass components and the SBA residue were characterized by testing by XRF, XRD, AG, DTA and TGA. Test samples were fabricated, assembled in lots of 3 units and sintered at temperatures of 1150 ° C to 1210 ° C. The results of the physical properties, mechanical properties and SEM of the sintered samples, showed that the formulation, G4 - in which applied 10% of SBA replacing phyllite, sintering temperature 1210 ° C showed better performance as the previously mentioned properties due to the formation of mullite crystals, meeting the prerequisites of standards for enamelled porcelain tile, while reducing the environmental impact and the cost of production.

The current issues of using innovative solutions in waste-free management systems

2021 ◽  
pp. 136-148
Author(s):  
Olga Vytvytska ◽  
Mykyt Pundyk
Keyword(s):  
Raw Materials ◽  
Waste Recycling ◽  
Household Waste ◽  
Management Systems ◽  
Energy Technology ◽  
Processing Technologies ◽  
Management Technology ◽  
Innovative Solutions ◽  
The Cost ◽  
Theoretical Foundations

The purpose of the article. The purpose of the study is to substantiate the theoretical foundations and practical innovative solutions for the reuse of waste resources with a proposal for improved waste management technology with prospects for implementation in Ukraine. Research methodology: theoretical and practical aspects of the introduction and implementation of eco-management, because for Ukraine such an approach to the introduction of innovative processing technologies in enterprises is completely new. Methodical toolkit of substantiation of innovative decisions of reuse of resources from waste, structure of prime cost of the improved system for the Goloseevsky area. Kiev. Scientific novelty. It is proposed to optimize the existing garbage problem in most regions and replace waste trucks based on the method of the pneumatic system manufactured by Envac. The system allows you to reduce the cost of moving cargo over time sorting or disposal points. Conclusions. The introduction of innovative systems in Ukraine for the year saves UAH 34 billion 499 million, in addition, the sorting of household waste is gaining popularity, recycling tanks are being installed in cities, the population is beginning to treat waste with understanding, and a behavioral strategy has been introduced to stimulate waste recycling. In addition, the proposed technology of sorting raw materials allows you to sort up to 97% of household waste, and the rest to burn for energy. All this makes the development of the processing industry in Ukraine promising. Keywords: innovations, waste-free systems, secondary raw materials, energy, technology.

ASSESSMENT OF WOODEN BUILDINGS IN TERMS OF CONSTRUCTION WASTE GENERATION

2020 ◽  
Author(s):  
Marcela Spišáková ◽  
Mária Kozlovská ◽  
Jozef Švajlenka
Keyword(s):  
Negative Impact ◽  
Raw Materials ◽  
Environmental Parameters ◽  
Constructional Material ◽  
Waste Generation ◽  
Construction Waste ◽  
Construction Market ◽  
Negative Impacts ◽  
The Individual ◽  
Wooden Structures

Construction industry creates an environment for people's lives. On the other hand, construction activities have a negative impact on various aspects of the environment. It consumes natural raw materials, significantly contributes to carbon footprint, waste, etc. Appropriate choice of constructional, material, technical, technological and environmental parameters of buildings can partially reduce this negative impacts. By designing, implementing and using wood-based constructions it is possible to reduce the negative impact in the area of construction waste generation. Currently, the construction market offers a large number of construction systems of wooden buildings, which have both strengths and weaknesses. In this paper are identified construction systems of wooden buildings offered on the Slovak construction market. The aim of the paper is a detailed identification of construction waste generation during the realization of particular wooden structures and monitoring of waste generation in production factory (off site) and on construction site (on site) during the construction of wooden buildings. Based on the obtained information, the individual construction systems of wood-based constructions are compared in terms of construction waste generation

Processing Technogenic Raw Materials-Phosphorus Slags with the Production of Precipitated Nanosilica and Simultaneous Recovery of Valuable Components

2021 ◽  
Vol 316 ◽  
pp. 637-642
Author(s):  
Yelena G. Bochevskaya ◽  
Zaure B. Karshigina ◽  
Aynash S. Sharipova
Keyword(s):  
Specific Surface ◽  
Raw Materials ◽  
Nitric Acid Concentration ◽  
Process Conditions ◽  
Flow Sheet ◽  
Process Duration ◽  
Precipitated Silica ◽  
Component Content ◽  
Slag Processing ◽  
White Soot

The paper provides a flow sheet of the phosphorus slag processing to produce precipitated silica (white soot). The process conditions for opening phosphorus slag at the I stage of leaching have been selected: the nitric acid concentration is 3.5 mol/dm3; the ratio S:L = 1:3.5; the temperature is 60 oС; and the process duration is 1 hour. The parameters of the white soot production II stage have been determined: the HNO3 concentration is 6.5 mol/dm3; the ratio S:L = 1:3.5; the temperature is 50 oС; and the process duration is 1 hour. The temperature effect on the white soot structure and the specific surface have been established. At optimal process parameters, the white soot batches have been obtained with the main SiO2 component content of 88.2 and 90.5 %, and a specific surface of 170 and 182 m2/g, respectively. The through recovery of silicon into a commercial product is 98.0 % of its initial content in slag.

Operationalising resilience in tropical agricultural value chains

2019 ◽  
Vol 24 (2) ◽  
pp. 271-300 ◽  
Author(s):  
Joshua Aboah ◽  
Mark M.J. Wilson ◽  
Karl M. Rich ◽  
Michael C. Lyne
Keyword(s):  
Value Chain ◽  
Food System ◽  
Raw Materials ◽  
Citation Network ◽  
System Level ◽  
Value Chains ◽  
Common Source ◽  
Content Type ◽  
The Individual ◽  
Stakeholder Interactions

Purpose The analysis of the concept of resilience in supply chain management studies mostly focuses on the downstream side of the value chain and tacitly assumes an unlimited supply of raw materials. This assumption is unreasonable for agricultural value chains, as upstream disruptions clearly have a material impact on the availability of raw materials, and indeed, are a common source of supply problems. This paper aims to present a framework for the operationalisation of the concept of socioecological resilience in agricultural value chains that incorporates upstream activities. Design/methodology/approach A citation network analysis was adopted to review articles. A conceptual framework is then advanced to identify elements of resilience and indicators relevant to tropical agricultural value chains. Findings There are limited studies that assess resilience in the food chain context. Flexibility, collaboration, adaptability and resourcefulness are key elements for assessing resilience at the individual chain actor level. However, the paper argues that adaptability is the relevant element for the assessment of resilience at an aggregate food system level because it considers the alteration of a system’s state of resilience. Practical implications The proposed framework and propositions accommodate stakeholder interactions in the value chain and could serve as a tool to guide the assessment of resilience in agricultural value chains. Originality/value This paper is one of the few to extend resilience to cover the socioecological interaction aspects for supply chains that yield the raw materials needed for continuity in channel-wide value creation processes.

Sign in / Sign up

Export Citation Format

Share Document