scholarly journals Dosimetry and methodology of gamma irradiation for degradation studies on solvent extraction systems

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Bart Verlinden ◽  
Peter Zsabka ◽  
Karen Van Hecke ◽  
Ken Verguts ◽  
Liviu-Cristian Mihailescu ◽  
...  
Keyword(s):  
Solvent Extraction ◽  
Ionizing Radiation ◽  
Gamma Irradiation ◽  
Dose Rate ◽  
Nuclear Fuel ◽  
Spent Nuclear Fuel ◽  
High Dose ◽  
Spent Fuel ◽  
Irradiation Field ◽  
Pool Type

AbstractThe recycling of minor actinides from dissolved nuclear fuels by hydrometallurgical separation is one challenging strategy for the management of spent fuel. These future separation processes will likely be based on solvent extraction processes in which an organic solvent system (extractant and diluent) will be contacted with highly radioactive aqueous solutions. To establish a separation between different elements in spent nuclear fuel, many extractants have been studied in the past. A particular example is N,N,N′,N′-tetraoctyl diglycolamide (TODGA), which co-extracts lanthanides and actinides from nitric acid solutions into an organic phase (e.g. TODGA in n-dodecane). The radiolytic stability of these extractants is crucial, since they will absorb high doses of ionizing radiation during their usage. Worldwide, different gamma irradiation facilities are employed to expose extractants to ionizing radiation and gain insight in their radiation stability. The facilities differ in many ways, such as their environment (pool-type or dry), configuration and gamma sources (often 60Co or spent nuclear fuel). In this paper, a dosimetric assessment is made using different dosimeter systems in a pool-type irradiation facility, which has the advantage to be flexible in its arrangement of 60Co sources. It is shown that Red Perspex dosimeters can be used to accurately characterize this high dose rate gamma irradiation field (approx. 13.6 kGy h−1), after comparison with alanine, Fricke and ceric-cerous dosimetry in a lower dose rate gamma irradiation field (approx. 0.5 kGy h−1). A final validation of the whole chain of techniques is obtained by reproduction of the dose constants for TODGA in n-dodecane.

The effects of alpha-radiolysis on UO2 dissolution determined from electrochemical experiments with 238Pu-doped UO2

2002 ◽  
Vol 90 (9-11) ◽  
Author(s):  
S. Stroes-Gascoyne ◽  
F. King ◽  
J. S. Betteridge ◽  
F. Garisto
Keyword(s):  
Dose Rate ◽  
Nuclear Fuel ◽  
Spent Nuclear Fuel ◽  
Spent Fuel ◽  
Geologic Repository ◽  
Dissolution Rates ◽  
Term Stability ◽  
Long Term Stability ◽  
Alpha Radiolysis

SummaryThe long-term stability of spent nuclear fuel under deep geologic repository conditions will be determined mostly by the influence of α-radiolysis, since the dose-rate for α-radiolysis will exceed that for γ/β-radiolysis beyond a fuel age of ∼100 years and will persist for more than 10000 years. Dissolution rates derived from studies with currently available spent fuel include radiolysis effects from γ/β- as well as α-radiolysis. The use of external α-sources and chemically added H

Chemical Effects at the Reaction Front in Corroding Spent Nuclear Fuel

2006 ◽  
Vol 985 ◽  
Author(s):  
Jeffrey A. Fortner ◽  
A. Jeremy Kropf ◽  
James L. Jerden ◽  
James C. Cunnane
Keyword(s):  
Transition Zone ◽  
Nuclear Fuel ◽  
Spent Nuclear Fuel ◽  
Aqueous Environment ◽  
Spent Fuel ◽  
Aqueous Corrosion ◽  
Reduction Potentials ◽  
Chemical Effects ◽  
Before And After ◽  
X Ray Absorption

AbstractPerformance assessment models of the U. S. repository at Yucca Mountain, Nevada suggest that neptunium from spent nuclear fuel is a potentially important dose contributor. A scientific understanding of how the UO2 matrix of spent nuclear fuel impacts the oxidative dissolution and reductive precipitation of Np is needed to predict the behavior of Np at the fuel surface during aqueous corrosion. Neptunium would most likely be transported as aqueous Np(V) species, but for this to occur it must first be oxidized from the Np(IV) state found within the parent spent nuclear fuel. In this paper we present synchrotron x-ray absorption spectroscopy and microscopy findings that illuminate the resultant local chemistry of neptunium and plutonium within uranium oxide spent nuclear fuel before and after corrosive alteration in an air-saturated aqueous environment. We find the Pu and Np in unaltered spent fuel to have a +4 oxidation state and an environment consistent with solid-solution in the UO2 matrix. During corrosion in an air-saturated aqueous environment, the uranium matrix is converted to uranyl (UO22+) mineral assemblage that is depleted in Np and Pu relative to the parent fuel. The transition from U(IV) in the fuel to a fully U(VI) character across the corrosion front is not sharp, but occurs over a transition zone of ∼ 50 micrometers. We find evidence of a thin (∼ 20 micrometer) layer that is enriched in Pu and Np within a predominantly U(IV) environment on the fuel side of the transition zone. These experimental observations are consistent with available data for the standard reduction potentials for NpO2+/Np4+ and UO22+/U4+ couples, which indicate that Np(IV) may not be effectively oxidized to Np(V) at the corrosion potential of uranium dioxide spent nuclear fuel in air-saturated aqueous solutions.

scholarly journals The Need for Integrating the Back End of the Nuclear Fuel Cycle in the United States of America

MRS Advances ◽  
2018 ◽  
Vol 3 (19) ◽  
pp. 991-1003 ◽  
Author(s):  
Evaristo J. Bonano ◽  
Elena A. Kalinina ◽  
Peter N. Swift
Keyword(s):  
United States ◽  
Nuclear Fuel ◽  
United States Of America ◽  
Spent Nuclear Fuel ◽  
Fuel Cycle ◽  
Nuclear Fuel Cycle ◽  
The United States ◽  
Spent Fuel ◽  
Dry Storage ◽  
The Us

ABSTRACTCurrent practice for commercial spent nuclear fuel management in the United States of America (US) includes storage of spent fuel in both pools and dry storage cask systems at nuclear power plants. Most storage pools are filled to their operational capacity, and management of the approximately 2,200 metric tons of spent fuel newly discharged each year requires transferring older and cooler fuel from pools into dry storage. In the absence of a repository that can accept spent fuel for permanent disposal, projections indicate that the US will have approximately 134,000 metric tons of spent fuel in dry storage by mid-century when the last plants in the current reactor fleet are decommissioned. Current designs for storage systems rely on large dual-purpose (storage and transportation) canisters that are not optimized for disposal. Various options exist in the US for improving integration of management practices across the entire back end of the nuclear fuel cycle.

Burnup Credit in the Criticality Safety Analysis of Spent Fuel in Storage Systems

2014 ◽  
Author(s):  
Vladyslav Soloviov
Keyword(s):  
Isotopic Composition ◽  
Nuclear Fuel ◽  
Beta Decay ◽  
Spent Nuclear Fuel ◽  
Storage Systems ◽  
Multiplication Factor ◽  
Spent Fuel ◽  
Neutron Multiplication ◽  
Initial Fuel ◽  
Effective Neutron

In this paper accounting of spent nuclear fuel (SNF) burnup of RBMK-1000 with actinides and full isotopic composition has been performed. The following characteristics were analyzed: initial fuel enrichment, burnup fraction, axial burnup profile in the fuel assembly (FA) and fuel weight. As the results show, in the first 400 hours after stopping the reactor, there is an increase in the effective neutron multiplication factor (keff) due to beta decay of 239Np into 239Pu. Further, from 5 to 50 years, there is a decrease in keff due to beta decay of 241Pu into 241Am. Beyond 50 years there is a slight change in the criticality of the system. Accounting for nuclear fuel burnup in the justification of nuclear safety of SNF systems will provide an opportunity to increase the volume of loaded fuel and thus significantly reduce technology costs of handling of SNF.

Developing a Concept for a National Used Fuel Interim Storage Facility in the United States

2013 ◽  
Author(s):  
Donald Wayne Lewis
Keyword(s):  
United States ◽  
Nuclear Fuel ◽  
Nuclear Waste ◽  
Spent Nuclear Fuel ◽  
The United States ◽  
Yucca Mountain ◽  
Storage Facility ◽  
Spent Fuel ◽  
Geological Repository ◽  
Interim Storage

In the United States (U.S.) the nuclear waste issue has plagued the nuclear industry for decades. Originally, spent fuel was to be reprocessed but with the threat of nuclear proliferation, spent fuel reprocessing has been eliminated, at least for now. In 1983, the Nuclear Waste Policy Act of 1982 [1] was established, authorizing development of one or more spent fuel and high-level nuclear waste geological repositories and a consolidated national storage facility, called a “Monitored Retrievable Storage” facility, that could store the spent nuclear fuel until it could be placed into the geological repository. Plans were under way to build a geological repository, Yucca Mountain, but with the decision by President Obama to terminate the development of Yucca Mountain, a consolidated national storage facility that can store spent fuel for an interim period until a new repository is established has become very important. Since reactor sites have not been able to wait for the government to come up with a storage or disposal location, spent fuel remains in wet or dry storage at each nuclear plant. The purpose of this paper is to present a concept developed to address the DOE’s goals stated above. This concept was developed over the past few months by collaboration between the DOE and industry experts that have experience in designing spent nuclear fuel facilities. The paper examines the current spent fuel storage conditions at shutdown reactor sites, operating reactor sites, and the type of storage systems (transportable versus non-transportable, welded or bolted). The concept lays out the basis for a pilot storage facility to house spent fuel from shutdown reactor sites and then how the pilot facility can be enlarged to a larger full scale consolidated interim storage facility.

Centralization of Canada’s Spent Nuclear Fuel

2013 ◽  
Author(s):  
Krista Nicholson ◽  
John McDonald ◽  
Shona Draper ◽  
Brian M. Ikeda ◽  
Igor Pioro
Keyword(s):  
Nuclear Fuel ◽  
Site Selection ◽  
Nuclear Power ◽  
Power Plants ◽  
Spent Nuclear Fuel ◽  
Selection Process ◽  
Spent Fuel ◽  
Geologic Repository ◽  
Candu Reactors ◽  
High Level

Currently in Canada, spent fuel produced from Nuclear Power Plants (NPPs) is in the interim storage all across the country. It is Canada’s long-term strategy to have a national geologic repository for the disposal of spent nuclear fuel for CANada Deuterium Uranium (CANDU) reactors. The initial problem is to identify a means to centralize Canada’s spent nuclear fuel. The objective of this paper is to present a solution for the transportation issues that surround centralizing the waste. This paper reviews three major components of managing and the transporting of high-level nuclear waste: 1) site selection, 2) containment and 3) the proposed transportation method. The site has been selected based upon several factors including proximity to railways and highways. These factors play an important role in the site-selection process since the location must be accessible and ideally to be far from communities. For the containment of the spent fuel during transportation, a copper-shell container with a steel structural infrastructure was selected based on good thermal, structural, and corrosion resistance properties has been designed. Rail has been selected as the method of transporting the container due to both the potential to accommodate several containers at once and the extensive railway system in Canada.

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