scholarly journals Development and characterization of bioglass incorporated plasma electrolytic oxidation layer on titanium substrate for biomedical application

2021 ◽  
Vol 60 (1) ◽  
pp. 678-690
Author(s):  
Nur Athirah Sukrey ◽  
Muhammad Rizwan ◽  
Abd Razak Bushroa ◽  
Siti Zuliana Salleh ◽  
Wan Jefrey Basirun
Keyword(s):  
Plasma Electrolytic Oxidation ◽  
Electrolyte Concentration ◽  
Biomedical Application ◽  
Pure Titanium ◽  
Titanium Substrate ◽  
Deposition Process ◽  
Voltage Response ◽  
Functional Coating ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

Abstract In this research, the growth of bioglass (BG) (45S5) incorporated oxide layer via plasma electrolytic oxidation (PEO) method was studied with respect to different sodium hydroxide (NaOH) concentrations (0.1, 0.3, 0.5, and 0.7 M). The voltage response during the deposition process was highly dependent on the electrolyte concentration. Large sparks were recorded at the lowest electrolyte concentration. The result also showed that the increment of electrolyte concentration improved the thickness and mechanical properties of BG-coated pure titanium (TI) surfaces via the PEO process. However, the morphological investigation showed that the coating formation and the uniformity of coating distribution are dependent on the optimum concentration of the electrolyte. This study demonstrates the feasibility of the PEO method in producing a uniform bio-functional coating for biomedical applications.

scholarly journals Fabrication of a Protective Hybrid Coating Composed of TiO2, MoO2, and SiO2 by Plasma Electrolytic Oxidation of Titanium

Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1182
Author(s):  
Tehseen Zehra ◽  
Mosab Kaseem ◽  
Shakhawat Hossain ◽  
Young-Gun Ko
Keyword(s):  
Plasma Electrolytic Oxidation ◽  
Pure Titanium ◽  
Titanium Substrate ◽  
Sio2 Nanoparticles ◽  
Hybrid Coating ◽  
Structural Defects ◽  
Nacl Solution ◽  
Microstructural Observation ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

This work examined the influence of dual incorporation of MoO2 and SiO2 on the corrosion behavior of pure titanium treated via plasma electrolytic oxidation (PEO). To achieve this purpose, pure titanium substrate was treated via PEO in an alkaline-molybdate electrolyte without and with SiO2 nanoparticles. The microstructural observation revealed that the addition of SiO2 nanoparticles into the electrolyte during PEO helped to seal the structural defects in the PEO coating so that a rougher, thicker, and denser coating rich in SiO2 was successfully obtained. From the electrochemical measurements in a 3.5 wt.% NaCl solution, the TiO2-MoO2-SiO2 hybrid coating exhibited a higher corrosion resistance than the TiO2-MoO2 coating which was attributed to the sealing effect by stable SiO2 nanoparticles.

scholarly journals Comparison of Biocompatible Coatings Produced by Plasma Electrolytic Oxidation on cp-Ti and Ti-Zr-Nb Superelastic Alloy

Coatings ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 401
Author(s):  
Ruzil Farrakhov ◽  
Olga Melnichuk ◽  
Evgeny Parfenov ◽  
Veta Mukaeva ◽  
Arseniy Raab ◽  
...  
Keyword(s):  
Plasma Electrolytic Oxidation ◽  
Electrochemical Impedance ◽  
Pure Titanium ◽  
Commercially Pure Titanium ◽  
X Ray ◽  
Kinetic Coefficients ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic ◽  
Cp Ti ◽  
Peo Coatings

The paper compares the coatings produced by plasma electrolytic oxidation (PEO) on commercially pure titanium and a novel superelastic alloy Ti-18Zr-15Nb (at. %) for implant applications. The PEO coatings were produced on both alloys in the identical pulsed bipolar regime. The properties of the coatings were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDX), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS). The PEO process kinetics was modeled based on the Avrami theorem and Cottrell equation using a relaxation method. The resultant coatings contain TiO2, for both alloys, and NbO2, Nb2O5, ZrO2 for Ti-18Zr-15Nb alloy. The coating on the Ti-18Zr-15Nb alloy has a higher thickness, porosity, and roughness compared to that on cp-Ti. The values of the kinetic coefficients of the PEO process—higher diffusion coefficient and lower time constant for the processing of Ti-18Zr-15Nb—explain this effect. According to the electrochemical studies, PEO coatings on Ti-18Zr-15Nb alloy provide better corrosion protection. Higher corrosion resistance, porosity, and roughness contribute to better biocompatibility of the PEO coating on Ti-18Zr-15Nb alloy compared to cp-Ti.

scholarly journals SEM and EDS Characterization of Porous Coatings Obtained On Titaniumby Plasma Electrolytic Oxidation in Electrolyte Containing Concentrated Phosphoric Acid with Zinc Nitrate

2017 ◽  
Vol 17 (2) ◽  
pp. 41-54 ◽  
Author(s):  
K. Rokosz ◽  
T. Hryniewicz ◽  
K. Pietrzak ◽  
W. Malorny
Keyword(s):  
Phosphoric Acid ◽  
Plasma Electrolytic Oxidation ◽  
Pure Titanium ◽  
Zinc Nitrate ◽  
Porous Coatings ◽  
Electrolytic Oxidation ◽  
Micro Arc Oxidation ◽  
Plasma Electrolytic ◽  
Peo Coatings

AbstractThe SEM and EDS results of porous coatings formed on pure titanium by Plasma Electrolytic Oxidation (Micro Arc Oxidation) under DC regime of voltage in the electrolytes containing of 500 g zinc nitrate Zn(NO3)2·6H2O in 1000 mL of concentrated phosphoric acid H3PO4at three voltages, i.e. 450 V, 550 V, 650 V for 3 minutes, are presented. The PEO coatings with pores, which have different shapes and the diameters, consist mainly of phosphorus, titanium and zinc. The maximum of zinc-to-phosphorus (Zn/P) ratio was found for treatment at 650 V and it equals 0.43 (wt%) | 0.20 (at%), while the minimum of that coefficient was recorded for the voltage of 450 V and equaling 0.26 (wt%) | 0.12 (at%). Performed studies have shown a possible way to form the porous coatings enriched with zinc by Plasma Electrolytic Oxidation in electrolyte containing concentrated phosphoric acid H3PO4with zinc nitrate Zn(NO3)2·6H2O.

scholarly journals TiO2Deposition on AZ31 Magnesium Alloy Using Plasma Electrolytic Oxidation

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Leon White ◽  
Youngmi Koo ◽  
Yeoheung Yun ◽  
Jagannathan Sankar
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Plasma Electrolytic Oxidation ◽  
Electrochemical Impedance ◽  
Protective Layer ◽  
Az31 Magnesium Alloy ◽  
Treatment Technique ◽  
Functional Coating ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

Plasma electrolytic oxidation (PEO) has been used in the past as a useful surface treatment technique to improve the anticorrosion properties of Mg alloys by forming protective layer. Coatings were prepared on AZ31 magnesium alloy in phosphate electrolyte with the addition of TiO2nanoparticles using plasma electrolytic oxidation (PEO). This present work focuses on developing a TiO2functional coating to create a novel electrophotocatalyst while observing the surface morphology, structure, composition, and corrosion resistance of the PEO coating. Microstructural characterization of the coating was investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM) followed by image analysis and energy dispersive spectroscopy (EDX). The corrosion resistance of the PEO treated samples was evaluated with electrochemical impedance spectroscopy (EIS) and DC polarization tests in 3.5 wt.% NaCl. The XRD pattern shows that the components of the oxide film include Mg from the substrate as well as MgO and Mg2TiO4due to the TiO2nanoparticle addition. The results show that the PEO coating with TiO2nanoparticles did improve the corrosion resistance when compared to the AZ31 substrate alloy.

scholarly journals Improvement of Mechanical and Corrosion Properties of Commercially Pure Titanium Using Alumina PEO Coatings

Coatings ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 29
Author(s):  
Viorel Malinovschi ◽  
Alexandru Horia Marin ◽  
Catalin Ducu ◽  
Sorin Moga ◽  
Victor Andrei ◽  
...  
Keyword(s):  
Plasma Electrolytic Oxidation ◽  
Pure Titanium ◽  
Commercially Pure Titanium ◽  
Corrosion Properties ◽  
Commercially Pure ◽  
Electrolytic Oxidation ◽  
Aluminum Oxide Layer ◽  
Plasma Electrolytic ◽  
Cp Ti ◽  
Peo Coatings

In this study, the surface of commercially pure titanium (Cp-Ti) was covered by a 21–95 µm-thick aluminum oxide layer using plasma electrolytic oxidation. Coating characterization revealed the formation of nodular and granular α- and γ-Al2O3 phases with minor amounts of TiAl2O5 and Na2Ti4O9 which yielded a maximum 49.0 GPa hardness and 50 N adhesive critical load. The corrosion resistance behavior in 3.5 wt.% NaCl solution of all plasma electrolytic oxidation (PEO) coatings was found to be two orders of magnitude higher compared to bare Ti substrate.

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